Selective oxidation of alcohols over nickel zirconium phosphate

doi:10.1016/S1872-2067(14)60315-6

Abstract

Abstract:

Nickel zirconium phosphate nanoparticles were found to function as efficient catalysts for the selective oxidation of a wide range of alcohols to their corresponding ketones and aldehydes using H₂O₂ as an oxidizing agent and without any organic solvents, phase transfer catalysts, or additives. The steric and electronic properties of various substrates had significant influence on the reaction conditions required to achieve acetylation. The results showed that this method can be applied for the chemoselective oxidation of benzyl alcohols in the presence of aliphatic alcohols. The catalyst used in the current study was characterized by ICP-OES, XRD, NH₃-TPD, Py-FTIR, N₂ adsorption-desorption, SEM and TEM. These analyses revealed that the interlayer distance in the catalyst increased from 0.75 to 0.98 nm when Ni²⁺ was intercalated between the layers, whereas the crystallinity of the material was reduced. The nanocatalyst could also be recovered and reused at least seven times without any discernible decrease in its catalytic activity. This new method for the oxidation of alcohols has several key advantages, including mild and environmentally friendly reaction conditions, short reaction time, excellent yields and a facile work-up.

Key words: Nickel zirconium phosphate, Nanoparticle, Alcohol oxidation, Solvent-free, Solid catalyst

Abdol R. Hajipour, Hirbod Karimi, Afshin Koohi. Selective oxidation of alcohols over nickel zirconium phosphate[J]. Chinese Journal of Catalysis, 2015, 36(7): 1109-1116.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60315-6

https://www.cjcatal.com/EN/Y2015/V36/I7/1109

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