Aqueous-Phase Reforming of Ethylene Glycol to H2 on Sn-Modified Rapidly Quenched Skeletal Ni-Mo Catalyst

Chinese Journal of Catalysis ›› 2009, Vol. 30 ›› Issue (7): 595-600.

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Aqueous-Phase Reforming of Ethylene Glycol to H2 on Sn-Modified Rapidly Quenched Skeletal Ni-Mo Catalyst

CHU Xianwen1, LIU Jun1, QIAO Minghua1,*, ZHUANG Jihua1,*, FAN Kangnian1, ZHANG Xiaoxin2, ZONG Baoning2

1 Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, China 2 Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China

Received:2009-07-25 Online:2009-07-25 Published:2013-04-24

Abstract

Abstract: Addition of Sn to rapidly quenched skeletal Ni-Mo remarkably improved the H2 production rate and selectivity in aqueous-phase reforming (APR) of ethylene glycol. The H2 selectivity reached 98.7% at high conversion of ethylene glycol while the formation of alkanes was substantially suppressed.

Key words: rapidly quenched alloy, nickel, molybdenum, stannum, ethylene glycol, aqueous-phase reforming, hydrogen production

CHU Xianwen;LIU Jun;QIAO Minghua;*;ZHUANG Jihua;*;FAN Kangnian;ZHANG Xiaoxin;ZONG Baoning. Aqueous-Phase Reforming of Ethylene Glycol to H2 on Sn-Modified Rapidly Quenched Skeletal Ni-Mo Catalyst[J]. Chinese Journal of Catalysis, 2009, 30(7): 595-600.

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Aqueous-Phase Reforming of Ethylene Glycol to H2 on Sn-Modified Rapidly Quenched Skeletal Ni-Mo Catalyst

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