Palladium-Catalyzed Suzuki Reaction Using a New N-Carbazolyl Diphosphine

doi:10.3724/SP.J.1088.2010.00614

Chinese Journal of Catalysis ›› 2010, Vol. 31 ›› Issue (12): 1478-1482.DOI: 10.3724/SP.J.1088.2010.00614

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Palladium-Catalyzed Suzuki Reaction Using a New N-Carbazolyl Diphosphine

PENG Zonghai1, FU Haiyan1, MA Menglin2, CHEN Hua1,*, LI Xianjun1

1Key Laboratory of Green Chemistry and Technology of Ministry of Education, the Institute of Homogeneous Catalysis, Faculty of Chemistry, Sichuan University. Chengdu 610064, Sichuan, China; 2Department of Chemistry, Xihua University, Chengdu 611930, Sichuan, China

Received:2010-06-09 Online:2010-12-13 Published:2014-04-26

Abstract

Abstract: A new diphospine, 6,6′-dimethoxy-2,2′-bis(di-N-carbazolylphosphino)-1,1′-biphenyl (3), has been synthesized from commercially available 3-bromoanisole in five steps and fully characterized by ¹H NMR, ³¹P NMR, ¹³C NMR, and high-resolution mass spectrometry. The palladium complex with the new ligand 3 provided excellent yields in Suzuki coupling reaction of aryl bromides and phenylo boric acid, even in the presence of hindered and functional groups.

Key words: Suzuki cross-coupling, diphosphine ligand, N-carbazolyl, palladium, aryl bromide, phenylo boric acid

PENG Zonghai1, FU Haiyan1, MA Menglin2, CHEN Hua1,*, LI Xianjun1. Palladium-Catalyzed Suzuki Reaction Using a New N-Carbazolyl Diphosphine[J]. Chinese Journal of Catalysis, 2010, 31(12): 1478-1482.

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Palladium-Catalyzed Suzuki Reaction Using a New N-Carbazolyl Diphosphine

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