Chinese Journal of Catalysis ›› 2011, Vol. 32 ›› Issue (6): 1040-1045.DOI: 10.3724/SP.J.1088.2011.10145

• Research papers • Previous Articles     Next Articles

Ground-Level Ozone Decomposition over Pd-MnOx/Al2O3 Catalyst Prepared by Urea Hydrolysis

PAN Hao, ZHOU Lina, ZHU Yi, PENG Na, GONG Maochu, CHEN Yaoqiang*   

  1. Key Laboratory of Green Chemistry and Technology of Ministry of Education, Sichuan University, Chengdu 610064, Sichuan, China
  • Received:2011-01-24 Revised:2011-03-03 Online:2011-06-21 Published:2014-10-31

Abstract: The Pd-MnOx/Al2O3 catalyst has been prepared by the urea hydrolysis method and characterized by low temperature nitrogen adsorption-desorption and X-ray diffraction. Its catalytic activity for decomposing ground-level ozone has been studied. The catalyst showed a high activity at low temperature and high relative humidity. At gas hourly space velocity (GHSV) of 660000 h-1 and relative humidity of 85%–90%, the ozone conversion over the catalyst reached 91.7% at 20 °C and the temperature for complete decomposition of ozone was only 24 °C. Furthermore, the prepared catalyst can completely decompose ground-level ozone when it is coated on the wave shaped heat patches of automobile water tanks.

Key words: palladium, manganese oxide, urea hydrolysis method, relative humidity, ground-level ozone, catalytic decomposition, completely decompose