Cu-Catalyzed Coupling of Aryl Iodides with Thiols Using Carbonyl-Phosphine Oxide Ligands

doi:10.1016/S1872-2067(10)60243-4

Abstract

Abstract: A series of carbonyl-phosphine oxide ligands were synthesized from 2-bromophenylaldehyde and used in Cu-catalyzed C–S coupling reactions. Aryl iodide and aryl bromide reacted with thiols efficiently upon catalysis under mild reaction conditions and a yield of up to 99% was obtained.

Key words: Cu, carbonyl-phosphine oxide, carbon-sulfur bond formation, cross-coupling reaction, iodide aryl, thiol

WANG Hao-Long, WAN Bo-Shun. Cu-Catalyzed Coupling of Aryl Iodides with Thiols Using Carbonyl-Phosphine Oxide Ligands[J]. Chinese Journal of Catalysis, 2011, 32(7): 1129-1132.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(10)60243-4

https://www.cjcatal.com/EN/Y2011/V32/I7/1129

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