Synthesis of Mesoporous Silicas with a Cationic Surfactant-Anionic Polymer Mixture as Template

doi:10.1016/S1872-2067(11)60344-6

Abstract

Abstract: Different structural mesoporous silicas have been synthesized at high temperature using the Stöber method by utilizing a mixture of cationic cetyltrimethylammonium bromide and anionic water-soluble sodium polyacrylate (NaPAA) as template. The synthetic conditions, which include the amount of ethanol, crystallization temperature, crystallization time, polymer concentration, and molecular weight, have significant influence on the structures and surface morphologies of the synthetic product. This could be attributed to a combined effect of NaPAA and ethanol.

Key words: cationic surfactant, anionic polymer, composite template, ethanol, mesoporous silica

ZHANG Li-Na, WANG Hao, FAN Wei-Bin, WANG Jian-Guo. Synthesis of Mesoporous Silicas with a Cationic Surfactant-Anionic Polymer Mixture as Template[J]. Chinese Journal of Catalysis, 2012, 33(1): 164-173.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60344-6

https://www.cjcatal.com/EN/Y2012/V33/I1/164

References

1 Beck J S, Vartuli J C, Roth W J, Leonowicz M E, Kresge C T, Schmitt K D, Chu C T W, Olson D H, Sheppard E W. J Am Chem Soc, 1992, 114: 10834
2 Kresge C T, Leonowicz M E, Roth W J, Vartuli J C, Beck J S. Nature, 1992, 359: 710
3 Selvam P, Bhatia S K, Sonwane C G. Ind Eng Chem Res, 2001, 40: 3237
4 Linssen T, Cassiers K, Cool P, Vansant E F. Adv Colloid Interface Sci, 2003, 103: 121
5 Liu X B, Li L S, Du Y, Guo Z, Ong T T, Chen Y, Ng S C, Yang Y H. J Chromatogr A, 2009, 1216: 7767
6 Li Y Y, Cheng S Y, Dai P C, Liang X M, Ke Y X. Chem Commun, 2009: 1085
7 冯雪风, 金卫根, 刘芬, 罗建勋. 无机盐工业 (Feng X F, Jin W G, Liu F, Luo J X. Inorg Chem Ind), 2008, 40(12): 12
8 Zhao D Y, Feng J L, Huo Q S, Melosh N, Fredrickson G H, Chmelka B F, Stucky G D. Science, 1998, 279: 548
9 Jin Z W, Wang X D, Cui X G. Colloids Surf A, 2008, 316: 27
10 Suzuki K, Ikari K, Imai H. J Am Chem Soc, 2004, 126: 462
11 Ye J F, Zhang H J, Yang R, Li X G, Qi L M. Small, 2010, 6: 296
12 Liu Y R. Microporous Mesoporous Mater, 2009, 124: 190
13 Braga T P, Gomes E C C, de Sousa A F, Carreño N L V, Longhinotti E, Valentini A. J Non-Crystal Solids, 2009, 355: 860
14 Lin H M, Zhu G H, Xing J J, Gao B, Qiu S L. Langmuir, 2009, 25: 10159
15 Wang Y, Song H H, Zhang H, Liao L F, Liu N, Chen X H. J Mater Chem, 2011, 21: 5576
16 Chen Q R, Han L, Gao C B, Che S A. Microporous Mesoporous Mater, 2010, 128: 203
17 Gu X, Li C L, Liu X H, Ren J W, Wang Y Q, Guo Y L, Guo Y, Lu G Z. J Phys Chem C, 2009, 113: 6472
18 Li Y, Bi L F, Wang S B, Chen Y L, Li B Z, Zhu X L, Yang Y G. Chem Commun, 2010, 46: 2680
19 Niu D C, Ma Z, Li Y S, Shi J L. J Am Chem Soc, 2010, 132: 15144
20 Guo X H, Deng Y H, Tu B, Zhao D Y. Langmuir, 2010, 26: 702
21 Chen H M, He J H, Tang H M, Yan C X. Chem Mater, 2008, 20: 5894
22 Yu S H, Cölfen H. J Mater Chem, 2004, 14: 2124
23 Pouget E, Dujardin E, Cavalier A, Moreac A, Valery C, Marchi-Artzner V, Weiss T, Renault A, Paternoster M, Artzner F. Nature Mater, 2007, 6: 434
24 Liu S Q, Cool P, Collart O, Van Der Voort P, Vansant E F, Lebedev O I, Van Tendeloo G, Jiang M H. J Phys Chem B, 2003, 107: 10405
25 Iler R K. The Chemistry of Silica. New York: Wiley-Interscience Publications, 1979

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