Characterization and Catalytic Activity of CeO2-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane

doi:10.1016/S1872-2067(11)60347-1

Abstract

Abstract: A Ni/Mo/SBA-15 catalyst was modified with CeO₂ and compared with the unmodified catalyst. The catalysts were characterized by N₂ adsorption, CO₂ temperature-programmed desorption, H₂ temperature-programmed reduction, Fourier transform infrared spectrometer, X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy. Both the Ni/Mo/SBA-15 and CeO₂/Ni/Mo/SBA-15 catalysts gave good catalytic activities at atmospheric pressure. The CeO₂ impregnated Ni/Mo/SBA-15 catalyst exhibited excellent stability at 800 ºC for 100 h on stream, and after the reaction, carbon deposits were not formed on the catalyst. The Ni/Mo/SBA-15 and CeO₂/Ni/Mo/SBA-15catalysts had a regular hexagonal mesoporous structure. The nickel species and the Ce-Mo oxide components were all in the SBA-15 mesopores. This prevented carbon deposition and sintering of the nickel species in the CeO₂/Ni/Mo/SBA-15 catalyst.

Key words: carbon dioxide reforming, methane, nickel, molybdenum, mesoporous molecular sieve SBA-15, cerium-promoted

HUANG Jian, MA Ren-Xiong, GAO Zhi-Hua, SHEN Chao-Feng, HUANG Wei. Characterization and Catalytic Activity of CeO₂-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane[J]. Chinese Journal of Catalysis, 2012, 33(4): 637-644.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60347-1

https://www.cjcatal.com/EN/Y2012/V33/I4/637

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Characterization and Catalytic Activity of CeO₂-Ni/Mo/SBA-15 Catalysts for Carbon Dioxide Reforming of Methane

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