Microwave Assisted Sol-Gel Synthesis of MgO Nanoparticles and Their Catalytic Activity in the Synthesis of Hantzsch 1,4-Dihydropyridines

doi:10.1016/S1872-2067(11)60431-2

Abstract

Abstract: A microwave-assisted sol-gel method was employed for the preparetion of nano-sized MgO particles using Mg(NO₃)₂·6H₂O as precursor and deionized water as solvent. The sample calcined at 500 °C had a high specific surface area of 243.2 m²/g and particles sizes from 9.5 to 10.5 nm. For comparison, MgO nanoparticles were also synthesized without microwave irradiation. X-ray diffraction (XRD) characterization showed the formation of smaller particles after microwave irradiation. The structure and morphology of the MgO particles were analyzed by N₂ adsorption-desorption, XRD, scanning electron microscopy, and transmission electron microscopy. Their catalytic behavior was studied with the one-pot synthesis of Hantzsch 1,4-dihydropyridines from the reaction of aromatic aldehydes, ethyl acetoacetate, and ammonium acetate. The MgO nanoparticles have high catalytic activity and gave the desired products in good to high yields. The catalyst can be easily recovered by filtration and was used at least three times with only a slight reduction in its catalytic activity.

Key words: magnesium oxide, microwave-assisted sol-gel method, nanoparticle, Hantzsch 1,4-dihydropyridine

Hakimeh MIRZAEI, Abolghasem DAVOODNIA. Microwave Assisted Sol-Gel Synthesis of MgO Nanoparticles and Their Catalytic Activity in the Synthesis of Hantzsch 1,4-Dihydropyridines[J]. Chinese Journal of Catalysis, 2012, 33(9): 1502-1507.

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References

1 Wagner G W, Bartram P W, Koper O, Klabunde K J. J Phys Chem B, 1999, 103: 3225
2 Davini P, Tartarelli R. Fuel, 1985, 64: 380
3 Duyar O, Durusoy H Z. Turk J Phys, 2004, 28: 139
4 Phillips J M. Appl Phys, 1996, 79: 1829
5 Hamet J F, Mercey B, Hervieu M, Raveau B. Physica C, 1992, 193: 465
6 Liu S W, Weaver J, Yuan Z, Donner W, Chen C L, Jiang J C, Meletis E I, Chang W, Kirchoefer S W, Horwitz J, Bhalla A. Appl Phys Lett, 2005, 87: 142905/1
7 Hattori H. Chem Rev, 1995, 95: 537
8 Mishakov I V, Bedilo A F, Richards R M, Chesnokov V V, Volodin A M, Zaikovskii V I, Buyanov R A, Klabunde K J. J Catal, 2002, 206: 40
9 Chesnokov V V, Bedilo A F, Heroux D S, Mishakov I V, Klabunde K J. J Catal, 2003, 218: 438
10 Kumar D, Reddy V B, Mishra B G, Rana R K, Nadagoudac M N, Varmac R S. Tetrahedron, 2007, 63: 3093
11 Climent M J, Corma A, Iborra S, Mifsud M. J Catal, 2007, 247: 223
12 Zelmanov G, Semiat R. Water Res, 2008, 42: 492
13 Pucher P, Benmami M, Azouani R, Krammer G, Chhor K, Bocquet J F, Kanaev A V. Appl Catal A, 2007, 332: 297
14 Mirjafary Z, Saeidian H, Sadeghi A, Matloubi Moghaddam F. Catal Commun, 2008, 9: 299
15 Xue C H, Palaniappan K, Arumugam G, Hackney S A, Liu J, Liua H Y. Catal Lett, 2007, 116: 94
16 Jiu J T, Kurumada K I, Tanigaki M, Adachi M, Yoshikawa S. Mater Lett, 2004, 58: 44
17 Chadwick A V, Poplett I J F, Maitland D T S, Smith M E. Chem Mater, 1998, 10: 864
18 Bokhimi X, Morales A, Portilla M, Garc?a-Ruiz A. Nanostruct Mater, 1999, 12: 589
19 Subramania A, Kumar G V, Priya A R S, Vasudevan T. Nanotechnology, 2007, 18: 225601/1
20 Lopez T, Gomez R, Navarrete J, Lopez-Salinas E. J Sol-Gel Sci Technol, 1998, 13: 1043
21 Utamapanya S, Klabunde K J, Schlup J R. Chem Mater, 1991, 3: 175
22 Liang S H, Gay I D. Langmuir, 1985, 1: 593
23 Klabunde K J, Stark J, Koper O, Mohs C, Park D G, Decker S, Jiang Y, Lagadic I, Zhang D J. J Phys Chem, 1996, 100: 12142
24 Bokhimi X, Morales A, Lopez T, Gomez R. J Solid State Chem, 1995, 115: 411
25 Xu B Q, Wei J M, Wang H Y, Sun K Q, Zhu Q M. Catal Today, 2001, 68: 217
26 Matthews J S, Just O, Obi-Johnson B, Rees W S. Chem Vapor Depos, 2000, 6: 129
27 El-Shall M S, Slack W, Vann W, Kane D, Hanley D. J Phys Chem, 1994, 98: 3067
28 Ding Y, Zhang G T, Wu H, Hai B, Wang L B, Qian Y T. Chem Mater, 2001, 13: 435
29 Helble J J. J Aerosol Sci, 1998, 29: 721
30 Krishnakumar T, Jayaprakash R, Parthibavarman M, Phani A R, Singh V N, Mehta B R. Mater Lett, 2009, 63: 896
31 Davoodnia A, Rahimizadeh M, Atapour-Mashhad H, Tavakoli-Hoseini N. Heteroat Chem, 2009, 20: 346
32 Parida K M, Parija S. Sol Energy, 2006, 80: 1048
33 Moghaddam F M, Saeisian H. Mater Sci Engin B, 2007, 139: 265
34 Davoodnia A, Heravi M M, Rezaei-Daghigh L, Tavakoli- Hoseini N. Chin J Chem, 2010, 28: 429
35 Davoodnia A, Khojastehnezhad A, Tavakoli-Hoseini N. Bull Korean Chem Soc, 2011, 32: 2243
36 Zeinali-Dastmalbaf M, Davoodnia A, Heravi M M, Tavakoli- Hoseini N, Khojastehnezhad A, Zamani H A. Bull Korean Chem Soc, 2011, 32: 656
37 Khojastehnezhad A, Davoodnia A, Bakavoli M, Tavakoli- Hoseini N, Zeinali-Dastmalbaf M. Chin J Chem, 2011, 29: 297
38 Davoodnia A, Tavakoli-Nishaburi A, Tavakoli-Hoseini N. Bull Korean Chem Soc, 2011, 32: 635
39 Jenkins R, Snyder R L. Chemical Analysis: Introduction to X-Ray Powder Diffractometry. New York: Wiley, 1996. 90
40 Klug H P, Alexander L E. X-Ray Diffraction Procedures. 2nd Ed. New York: Wiley, 1974. 656
41 Antonyraj C A, Kannan S. Appl Catal A, 2008, 338: 121
42 Debache A, Ghalem W, Boulcina R, Belfaitah A, Rhouati S, Carboni B. Tetrahedron Lett, 2009, 50: 5248
43 Heydari A, Khaksar S, Tajbakhsh M, Bijanzadeh H R. J Fluo-rine Chem, 2009, 130: 609
44 Murthy Y L N, Rajack A, Taraka Ramji M, Jeson Babu J, Praveen Ch, Aruna Lakshmi K. Bioorg Med Chem Lett, 2012, in press
45 Adharvana Chari M, Syamasundar K. Catal Commun, 2005, 6: 624
46 Sridhar R, Perumal P T. Tetrahedron, 2005, 61: 2465
47 Bamoharram F F. Synth React Inorg Met-Org Nano-Met Chem, 2011, 41: 571
48 Diez V K, Apesteguia C R, Di Cosimo J I. Catal Today, 2000, 63: 53

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