Precursors of active Ni species in Ni/Al2O3 catalysts for oxidative dehydrogenation of ethane

doi:10.1016/S1872-2067(12)60672-X

Abstract

Abstract:

Ni/Al₂O₃ catalysts for oxidative dehydrogenation (ODH) of ethane were prepared by impregnation of Al₂O₃ with nickel acetate or nickel nitrate, and by mechanical mixing of NiO and Al₂O₃. The Ni-based catalysts were characterized by N₂ adsorption-desorption, X-ray diffraction, diffuse reflectance UV-visible diffuse reflectance spectroscopy, and temperature-programmed reduction of hydrogen. The results showed that formation of crystalline NiO particles with a size of < 8 nm and/or non-stoichiometric NiO species in the Ni/Al₂O₃ catalysts led to more active species in ODH of ethane under the investigated reaction conditions. In contrast, tetrahedral Ni species present in the catalysts led to higher selectivity for ethene. Formation of large crystalline NiO particles (22-32 nm) over Ni/Al₂O₃ catalysts decreased the selectivity for ethene.

Key words: Nickel, Alumina, Ethane, Oxidative dehydrogenation, Nickel species

Lucie Smoláková, Šárka Botková, Libor Čapek, Peter Priecel, Agnieszka Sołtysek, Martin Kout, Lenka Matějová. Precursors of active Ni species in Ni/Al₂O₃ catalysts for oxidative dehydrogenation of ethane[J]. Chinese Journal of Catalysis, 2013, 34(10): 1905-1913.

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Precursors of active Ni species in Ni/Al₂O₃ catalysts for oxidative dehydrogenation of ethane

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