The application of incorporation model in γ-Al2O3-supported single and dual metal oxide catalysts：A review

doi:10.1016/S1872-2067(12)60708-6

Chinese Journal of Catalysis ›› 2013, Vol. 34 ›› Issue (11): 1975-1985.DOI: 10.1016/S1872-2067(12)60708-6

• Reviews • Previous Articles Next Articles

The application of incorporation model in γ-Al₂O₃-supported single and dual metal oxide catalysts：A review

Xiaojiang Yao^a, Fei Gao^b, Lin Dong^a,b

a School of Chemistry and Chemical Engineering, Key Laboratory of Mesoscopic Chemistry of MOE, Nanjing University, Nanjing 210093, Jiangsu, China;
b Center of Modern Analysis, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing 210093, Jiangsu, China

Received:2013-08-31 Revised:2013-09-10 Online:2013-10-18 Published:2013-10-18
Contact: Lin Dong
Supported by:
This work was supported by the National Natural Science Foundation of China (20873060, 20973091), the National Basic Research Program of China (973 Program, 2010CB732300), and Jiangsu Science and Technology Support Program (SBE201100389).

Abstract

Abstract:

The investigation of the interaction between the surface dispersed components and the supports is the key to understand the nature of catalytic reactions. A single metal oxide (CuO) and dual metal oxides (CuO-Mn₂O₃, CuO-CoO, etc.) were supported on γ-Al₂O₃ to produce model catalysts. The dispersion behavior of these metal oxides on the surface of γ-Al₂O₃ and some physicochemical properties were explained using the Incorporation Model. These properties were considered together with their catalytic performances in CO+O₂ and NO+CO model reactions to explore "composition-structure-property" relationships. A possible reaction mechanism involving surface synergetic oxygen vacancy on the supported dual metal oxide catalysts was proposed to approach the nature of NO reduction by CO.

Key words: γ-Alumina support, Supported metal oxide catalyst, Surface interaction, Incorporation Model, Surface synergetic oxygen vacancy

Xiaojiang Yao, Fei Gao, Lin Dong. The application of incorporation model in γ-Al₂O₃-supported single and dual metal oxide catalysts：A review[J]. Chinese Journal of Catalysis, 2013, 34(11): 1975-1985.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60708-6

https://www.cjcatal.com/EN/Y2013/V34/I11/1975

References

[1] Zhang Y H, Xiong G X, Sheng S S, Yang W S. Catal Today, 2000, 63: 517
[2] Zhang Y H, Xiong G X, Yang W S, Sheng S S. J Nat Gas Chem (张玉红, 熊国兴, 杨维慎, 盛世善. 天然气化学), 2000, 9:175
[3] Ma D, Mei D J, Li X, Gong M C, Chen Y Q. J Chin Rare Earth Soc (马迪, 梅大江, 李璇, 龚茂初, 陈耀强. 中国稀土学报), 2006, 24: 293
[4] Zhao X Y, Xu B L, Fan Y N. Chin J Inorg Chem (赵小燕, 许波连, 范以宁. 无机化学学报), 2008, 24: 1489
[5] Capannelli G, Carosini E, Monticelli O, Cavani F, Trifirò F. Catal Lett, 1996, 39: 241
[6] Selwood P W. Adv Catal, 1951, 3: 27
[7] Schuman S C, Shalit H. Catal Rev, 1970, 4: 245
[8] Schuit G C A, Gates B C. AICHE J, 1973, 19: 471
[9] Grange P, Delmon B. J Gess-Common Metals, 1974, 36: 353
[10] Massoth F E. Adv Catal, 1978, 27: 265
[11] Lipsch J M J G, Schuit G C A. J Catal, 1969, 15: 179
[12] Sonnemans J, Mars P. J Catal, 1973, 31: 209
[13] Lo Jacono M, Cimino A, Schuit G C A. Gazz Chim Ital, 1973, 103: 1281
[14] de Beer V H J, Schuit G C A. Stud Surf Sci Catal, 1976, 1: 343
[15] Hagenbach G, Courty Ph, Delmon B. J Catal, 1971, 23: 295
[16] Hagenbach G, Menguy P, Delmon B. Bull Soc Chim Belg, 1974, 83: 1
[17] Xie Y C, Tang Y Q. Adv Catal, 1990, 37: 1
[18] Chen Y, Dong L, Jin Y S, Xu B, Ji W J. Stud Surf Sci Catal, 1996, 101: 1293
[19] Chen Y, Zhang L F. Catal Lett, 1992, 12: 51
[20] Gates B C, Katzer J R, Schuit G C A. Chemistry of Catalytic Processes. New York: McGraw-Hill, 1979
[21] Beaufils J P, Barbaux Y. J Chim Phys Phys-Chim Biol, 1981, 78: 347
[22] Jimenéz-Gonzaléz A, Schmeisser D. Surf Sci, 1991, 250: 59
[23] Chen Y, Zhang L F. Catal Lett, 1992, 12: 51
[24] Wang X Y, Zhao B Y, Jiang D E, Xie Y C. Appl Catal A, 1999, 188: 201
[25] Chen Y. J Fudan Univ (Nat Sci) (陈懿. 复旦大学学报(自然科学版)), 2002, 41: 251
[26] Dong L. Chin J Catal (董林. 催化学报), 2009, 30: 1150
[27] Dong L, Yao X J, Chen Y. Chin J Catal (董林, 姚小江, 陈懿. 催化学报), 2013, 34: 851
[28] Dong L, Chen Y. Chin J Inorg Chem, 2000, 16: 250
[29] Xia W S, Wan H L, Chen Y. J Mol Catal A, 1999, 138: 185
[30] Wan H Q, Wang Z, Zhu J, Li X W, Liu B, Gao F, Dong L, Chen Y. Appl Catal B, 2008, 79: 254
[31] Yang F, Graciani J, Evans J, Liu P, Hrbek J, Sanz J F, Rodriguez J A. J Am Chem Soc, 2011, 133: 3444
[32] Over H, Kim Y D, Seitsonen A P, Wendt S, Lundgren E, Schmid M, Varga P, Morgante A, Ertl G. Science, 2000, 287:1474
[33] Esch F, Fabris S, Zhou L,Montini T, Africh C, Fornasiero P, Comelli G, Rosei R. Science, 2005, 309: 752
[34] Sun C Z, Zhu J, Lv Y Y, Qi L, Liu B, Gao F, Sun K Q, Dong L, Chen Y. Appl Catal B, 2011, 103: 206
[35] Yao X J, Yu Q, Ji Z Y, Lv Y Y, Cao Y, Tang C J, Gao F, Dong L, Chen Y. Appl Catal B, 2013, 130-131: 293
[36] Yao X J, Gao F, Yu Q, Qi L, Tang C J, Dong L, Chen Y. Catal Sci Technol, 2013, 3: 1355
[37] Pan X M, Ren K W, Wang X L, Lin R, Kou S Y, Ma J X. Acta Energiae Solaris Sin (潘相敏, 任克威, 王晓蕾, 林瑞, 寇素原, 马建新. 太阳能学报), 2010, 31: 958
[38] Chmielarz L, Kuśtrowski P, Zbroja M, Gil-Knap B, Datka J, Dziembaj R. Appl Catal B, 2004, 53: 47
[39] Wan H Q, Li D, Dai Y, Hu Y H, Liu B, Dong L. J Mol Catal A, 2010, 332: 32
[40] Faungnawakij K, Shimoda N, Fukunaga T, Kikuchi R, Eguchi K. Appl Catal A, 2008, 341: 139
[41] Lv Y Y, Zhang H L, Cao Y, Dong L H, Zhang L L, Yao K A, Gao F, Dong L, Chen Y. J Colloid Interface Sci, 2012, 372: 63
[42] Arnoldy P, Moulijn J A. J Catal, 1985, 93: 38
[43] Li D, Yu Q, Li S S, Wan H Q, Liu L J, Qi L, Liu B, Gao F, Dong L, Chen Y. Chem Eur J, 2011, 17: 5668
[44] Lv Y Y, Liu L C, Zhang H L, Yao X J, Gao F, Yao K A, Dong L, Chen Y. J Colloid Interface Sci, 2013, 390: 158

The application of incorporation model in γ-Al₂O₃-supported single and dual metal oxide catalysts：A review

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 3

Recommended Articles

Metrics

[1]	DONG Lin, YAO Xiaojiang, CHEN Yi. Interactions among supported copper-based catalyst components and their effects on performance: A review [J]. Chinese Journal of Catalysis, 2013, 34(5): 851-864.
[2]	SHI Chuan, XU Li, ZHU Ai-Min, ZHANG Yu-Zhuo, QU Ze-Tang. Copper Oxide Clusters Stabilized by Ceria for CO, C₃H₆, and NO Abatement [J]. Chinese Journal of Catalysis, 2012, 33(9): 1455-1462.
[3]	DONG Lin*. Studies on the Surface Interaction of Supported Metal Oxide Catalysts and Their Applications in the Abatement of Air Pollutant Molecules NO and CO [J]. Chinese Journal of Catalysis, 2009, 30(11): 1150-1169.