Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates

doi:10.1016/S1872-2067(12)60742-6

Chinese Journal of Catalysis ›› 2014, Vol. 35 ›› Issue (2): 227-231.DOI: 10.1016/S1872-2067(12)60742-6

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Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates

Zhengchao Duan^a, Lianzhi Wang^a, Xiaoyu Zuo^a, Xiangping Hu^b, Zhuo Zheng^b

a School of Chemical and Enviromental Engineering, Hubei University for Nationalities, Enshi 445000, Hubei, China;
b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2013-09-11 Revised:2013-10-23 Online:2014-01-16 Published:2014-01-17
Contact: Zhengchao Duan, Xiangping Hu
Supported by:
This work was supported by the National Natural Science Foundation of China (21262011).

Abstract

Abstract:

A series of chiral ferrocenyl diphosphine ligands (ImiFerroPhos ligands) has been applied to the hydrogenation of β-substituted α,β-unsaturated phosphonates to generate a range of optically active β-substituted alkylphosphonates in good yields with good enantioselectivity (up to 92% ee) under mild reaction conditions.

Key words: β-Substituted α,β-unsaturated phosphonate, Asymmetric catalytic hydrogenation, ImiFerroPhos ligands, Rhodium (Ⅱ) complex, Chiral β-substituted alkylphosphonate

Zhengchao Duan, Lianzhi Wang, Xiaoyu Zuo, Xiangping Hu, Zhuo Zheng. Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates[J]. Chinese Journal of Catalysis, 2014, 35(2): 227-231.

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Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates

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