Effects of Br substituent on catalytic performance of Ru-bda (H2bda = 2,2'-bipyridine-6,6'-dicarboxylic acid) catalysts for water oxidation

doi:10.1016/S1872-2067(15)60895-6

Abstract

Abstract:

A series of new Ru-bda catalysts with Br modification on the equatorial ligand, [Ru(Ln)(picoline)₂] (H₂L1 = 4-Br-2,2'-bipyridine-6,6'-dicarboxylic acid (4-Br-bda), 2; H₂L2 = 4,4'-diBr-bda, 3) and [Ru(L1)(isoquinoline)₂] 5, were synthesized for catalytic water oxidation. Compared with the un-substituted catalysts, the catalysts modified with Br displayed a marked change in the catalytic activities and reaction orders. The results confirm that the electronic effect of Br has a large effect on the kinetics and leads to the change in reaction orders.

Key words: Water oxidation, Ruthenium-bda catalyst, Bromine modification, Electronic effect, Kinetic studies

Zhao Liu, Yan Gao, Ze Yu, Min Zhang, Jianhui Liu. Effects of Br substituent on catalytic performance of Ru-bda (H2bda = 2,2'-bipyridine-6,6'-dicarboxylic acid) catalysts for water oxidation[J]. Chinese Journal of Catalysis, 2015, 36(10): 1742-1749.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60895-6

https://www.cjcatal.com/EN/Y2015/V36/I10/1742

References

[1] Blankenship R E, Tiede D M, Baber J, Bradvig G M, Fleming G, Ghiraedi M, Gunner M R, Junge W, Kramer D M, Melic A, Moore T A, Moser C C, Nocera D G, Nozik A J, Ort D R, Parson W W, Prince R C, Sayre R T. Science, 2011, 332: 805
[2] Cox N, Retegan M, Neese F, Pantazis D A, Boussac A, Lubitz W. Science, 2014, 345: 804
[3] Barnett S M, Goldberg K I, Mayer M J. Nat Chem, 2014, 4: 498
[4] Alstrum-Acevedo J H, Brennaman M K, Meyer T J. Inorg Chem, 2005, 44: 6802
[5] Sun L, Hammarstrom L, Åkermark B, Styring S. Chem Soc Rev, 2001, 30: 36
[6] Lewis N S, Nocera D G. Proc Natl Acad Sci, 2006, 103: 15729
[7] Ruttinger W, Dismukes G C. Chem Rev, 1997, 97: 1
[8] Huynh M H, Meyer T J. Chem Rev, 2007, 107: 5004
[9] Dau H, Zaharieva I. Acc Chem Res, 2009, 42: 1861
[10] Wada T, Tsuge K, Tanaka K. Angew Chem Int Ed, 2000, 39: 1479
[11] Concepcion J, Jurss J W, Templeton J L, Meyer T J. Proceed Nat Acad Sci, 2008, 105: 17632
[12] Geletii Y V, Bogdan B, Kogerler P, Hillesheim D A, Musaev D G, Hill C L. Angew Chem Int Ed, 2008, 47: 3896
[13] Robinson D M, Go Y B, Mu M M, Gardner G, Zhang Z J, Mastrogiovanni D, Garfunkel E, Li J, Greenblatt M, Dismukes G C. J Am Chem Soc, 2013,135: 3494
[14] Mucherman J L, Polyansky D E, Wada T, Tanka K, Fujita E. Inorg Chem, 2008, 47: 1787
[15] Sala X, Maji S, Bofil R, Garcla-Anton J, Escriche L, Llobet A. Acc Chem Res, 2014, 47: 504
[16] Brimblecombe R, Dismukes G C, Swiegers G F, Spiccia L. Dalton Trans, 2009, 9374
[17] Hull J H, Balcells D, Blakemore J D, Incarvito C D, Eisenstein O, Brudvig G W, Carbtree R H. J Am Chem Soc, 2009, 131: 8730
[18] McDaniel N D, Coughlin F J, Tinker L L, Bernhard S. J Am Chem Soc, 2008, 130: 210
[19] Wasylenko D J, Ganesamoorthy G, Borau-Garcia J, Berlinguette C P. Chem Commun, 2011, 47: 4249
[20] Gao Y, Åkermark T, Liu J, Sun L, Åkermark B. J Am Chem Soc, 2009, 131: 8726
[21] Hurst J K. Coord Chem Rev, 2005, 249: 313
[22] Brimblecombe R, Swiegers G F, Dismukes G C, Spiccia L. Angew Chem Int Ed, 2008, 47: 7335
[23] Yano J, Yachandra V. Chem Rev, 2014, 114: 4175
[24] Yagi M, Kaneko M. Chem Rev, 2001, 101: 21
[25] Concepcion J J, Jurss J W, Templeton J L, Meyer T J. J Am Chem Soc, 2008, 130: 16462
[26] Zong R, Thummel R P. J Am Chem Soc, 2013, 127: 12802
[27] Duan L, Fisher A, Xu Y, Sun L. J Am Chem Soc, 2009, 131: 10397
[28] Duan L, Bozoglian F, Mandal S, Stewart B, Privalov T, Llobet A, Sun L. Nat Chem, 2012, 4: 418
[29] Jiang Y, Li F, Huang F, Zhang B B, Sun L C. Chin J Catal (姜毅, 李斐, 黄芳, 张彪彪, 孙立成. 催化学报), 2013, 34: 1489
[30] Dulière E, Deviller M, Marchand-Brynaert J. Organometallics, 2003, 22: 804
[31] Donnici C L, Maxinio Filho D H, Moreira L L C, Teixeira dox Reis G, Cordeiro E, Ferreira de Oliveira I M, Carvalho S, Paniago E B. J Braz Chem Soc, 1998, 9: 455
[32] Regnouf de J B, Papet A L, Marsura A J. J Heterocyclic Chem, 1994, 31: 1069
[33] Mukkala V M, Kankare J J. Helv Chim Acta, 1992, 75: 1578
[34] Duan L, Wang L, Inge A K, Fisher A, Zou X, Sun L. Inorg Chem, 2013, 52: 7844
[35] Duan L, Fisher A, Xue Y H, Sun L. J Am Chem Soc, 2009, 131: 10397
[36] Dovletoglou A, Adeyemi S A, Meyer T J. Inorg Chem, 1996, 35: 4120
[37] Duan L, Xu Y, Zhang P, Wang M, Sun L. Inorg Chem, 2010, 49: 209