Hydrothermal synthesis of nanosized ZSM-22 and their use in the catalytic conversion of methanol

doi:10.1016/S1872-2067(15)61099-3

Abstract

Abstract:

ZSM-22 zeolite with different crystal lengths was prepared using a modified hydrothermal method. Rotation speed, Si/Al molar ratio and co-solvent have important effects on the crystal size of ZSM-22. The nanosized zeolite samples were characterized by X-ray diffraction, X-ray fluorescence, nitrogen adsorption, scanning electron microscopy, temperature-programmed desorption of ammonia and solid state nuclear magnetic resonance. The catalytic performance of nanosized ZSM-22 was tested using the conversion of methanol. Compared to conventional ZSM-22, the nanosized ZSM-22 zeolite exhibited superior selectivity to ethylene and aromatics and lower selectivity to propylene. Stability against deactivation was clearly shown by the nanosized ZSM-22 zeolite. A higher external surface area and smaller particle size make this nanosized ZSM-22 zeolite attractive for catalytic applications.

Key words: Nanosized ZSM-22 zeolite, Hydrothermal synthesis, Conversion of methanol

Lei Chen, Peng Lu, Yangyang Yuan, Li Xu, Xiaomin Zhang, Lei Xu. Hydrothermal synthesis of nanosized ZSM-22 and their use in the catalytic conversion of methanol[J]. Chinese Journal of Catalysis, 2016, 37(8): 1381-1388.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61099-3

https://www.cjcatal.com/EN/Y2016/V37/I8/1381

References

[1] M. G. Clerici, Top. Catal., 2000, 13, 373-386.
[2] A. Corma, J. Catal., 2003, 216, 298-312.
[3] J. F. Denayer, A. R. Ocakoglu, W. Huybrechts, J. A. Martens, J. W. Thybaut, G. B. Marin, G. V. Baron, Chem. Commun., 2003, 1880-1881.
[4] C. Marcilly, J. Catal., 2003, 216, 47-62.
[5] S. Mintova, J. P. Gilson, V. Valtchev, Nanoscale, 2013, 5, 6693-6703.
[6] S. Mintova, M. Jaber, V. Valtchev, Chem. Soc. Rev., 2015, 44, 7207-7233.
[7] A. G. Machoke, A. M. Beltran, A. Inayat, B. Winter, T. Weissenberger, N. Kruse, R. Guettel, E. Spiecker, W. Schwieger, Adv. Mater., 2015, 27, 1066-1070.
[8] K. Na, C. Jo, J. Kim, K. Cho, J. Jung, Y. Seo, R. J. Messinger, B. F. Chmelka, R. Ryoo, Science, 2011, 333, 328-332.
[9] J. Gu, Z. Y. Zhang, P. Hu, L. P. Ding, N. H. Xue, L. M. Peng, X. F. Guo, M. Lin, W. P. Ding, ACS Catal., 2015, 5, 6893-6901.
[10] A. Ghorbanpour, A. Gumidyala, L. C. Grabow, S. P. Crossley, J. D. Rimer, ACS Nano, 2015, 9, 4006-4016.
[11] C. Covarrubias, R. Quijada, R. Rojas, Microporous Mesoporous Mater, 2009, 117, 118-125.
[12] V. Valtchev, L. Tosheva, Chem. Rev., 2013, 113, 6734-6760.
[13] L. Tosheva, V. P. Valtchev, Chem. Mater., 2005, 17, 2494-2513.
[14] R. Ravishankar, C. E. A. Kirschhock, P. P. Knops-Gerrits, E. J. P. Feijen, P. J. Grobet, P. Vanoppen, F. C. De Schryver, G. Miehe, H. Fuess, B. J. Schoeman, P. A. Jacobs, J. A. Martens, J. Phys. Chem. B, 1999, 103, 4960-4964.
[15] C. Madsen, C. J. H. Jacobsen, Chem. Commun., 1999, 673-674.
[16] I. Schmidt, C. Madsen, C. J. H. Jacobsen, Inorg. Chem., 2000, 39, 2279-2283.
[17] J. A. Martens, W. Souverijns, W. Verrelst, R. Parton, G. F. Froment, P. A. Jacobs, Angew. Chem. Int. Ed., 1995, 34, 2528-2530.
[18] J. A. Martens, D. Verboekend, K. Thomas, G. Vanbutsele, J. P. Gilson, J. Perez-Ramirez, ChemSusChem, 2013, 6, 421-425.
[19] G. Majano, A. Darwiche, S. Mintova, V. Valtchev, Ind. Eng. Chem. Res., 2009, 48, 7084-7091.
[20] Y. Y. Hu, C. Liu, Y. H. Zhang, N. Ren, Y. Tang, Microporous Mesoporous Mater, 2009, 119, 306-314.
[21] J. H. Zhou, H. Jiang, J. Xu, J. Hu, H. L. Liu, Y. Hu, J. Nanosci. Nanotechnol., 2013, 13, 5736-5743.
[22] K. Moeller, B. Yilmaz, R. M. Jacubinas, U. Mueller, T. Bein, J. Am. Chem. Soc., 2011, 133, 5284-5295.
[23] A. A. Ismail, R. M. Mohamed, O. A. Fouad, I. A. Ibrahim, Cryst. Res. Technol., 2006, 41, 145-149.
[24] H. van Heyden, S. Mintova, T. Bein, Chem. Mater., 2008, 20, 2956-2963.
[25] O. Larlus, S. Mintova, T. Bein, Microporous Mesoporous Mater., 2006, 96, 405-412.
[26] G. T. Kokotailo, J. L. Schlenker, F. G. Dwyer, E. W. Valyocsik, Zeolites, 1985, 5, 349-351.
[27] S. Parmar, K. K. Pant, M. John, K. Kumar, S. M. Pai, B. L. Newalkar, Energy Fuels, 2015, 29, 1066-1075.
[28] M. A. Asensi, A. Corma, A. Martinez, M. Derewinski, J. Krysciak, S. S. Tamhankar, Appl. Catal. A, 1998, 174, 163-175.
[29] R. Kumar, P. Ratnasamy, J. Catal., 1989, 116, 440-448.
[30] N. Kumar, L. E. Lindfors, R. Byggningsbacka, Appl. Catal. A, 1996, 139, 189-199.
[31] D. Masih, T. Kobayashi, T. Baba, Appl. Catal. A, 2007, 3303-3305.
[32] J. B. Wang, S. T. Xu, J. Z. Li, Y. C. Zhi, M. Z. Zhang, Y. L. He, Y. X. Wei, X. W. Guo, Z. M. Liu, RSC Adv., 2015, 5, 88928-88935.
[33] H. M. Wen, Y. Zhou, J. Y. Xie, Z. Y. Long, W. Zhang, J. Wang, RSC Adv., 2014, 4, 49647-49654.
[34] O. Muraza, A. Abdul-lateef, T. Tago, A. B. D. Nandiyanto, H. Konno, Y. Nakasaka, Z. H. Yamani, T. Masuda, Microporous Mesoporous Mater., 2015, 206, 136-143.
[35] L. Shirazi, E. Jamshidi, M. R. Ghasemi, Cryst. Res. Technol., 2008, 12, 1300-1306.
[36] Y. Liu, Z. D. Wang, Y. Ling, X. B. Li, Y. M. Liu, P. Wu, Chin. J. Catal., 2009, 30, 525-530.
[37] A. K. Jamil, O. Muraza, A. M. Al-Amer, J. Ind. Eng. Chem., 2015, 29, 112-119.
[38] J. Z. Li, Y. X. Wei, Y. Qi, P. Tian, B. Li, Y. L. He, F. X. Chang, X. D. Sun, Z. M. Liu, Catal. Today, 2011, 164, 288-292.
[39] S. Teketel, U. Olsbye, K. P. Lillerud, P. Beato, S. Svelle, Appl. Catal. A, 2015, 494, 68-76.
[40] F. F. Wei, Z. M. Cui, X. J. Meng, C. Y. Cao, F. S. Xiao, W. G. Song, ACS Catal., 2014, 4, 529-534.