Recent progress in Ag3PO4-based all-solid-state Z-scheme photocatalytic systems

doi:10.1016/S1872-2067(17)62905-X

Abstract

Abstract:

Heterogeneous semiconductor photocatalysis is a promising green technology solution to energy and environmental problems. Traditional photocatalyst TiO₂, with a wide band gap of 3.2 eV, can only be excited by UV light and utilizes less than 4% of solar energy. Silver phosphate (Ag₃PO₄) is among the most active visible-light-driven photocatalysts reported. Unfortunately, unwanted pho-tocorrosion is the main obstacle to the practical application of Ag₃PO₄. Much effort has been made in recent years to address this issue and further enhance the photocatalytic performance of Ag₃PO₄. The construction of Z-scheme photocatalytic systems that mimic natural photosynthesis is a prom-ising strategy to improve the photocatalytic activity and stability of Ag₃PO₄. This brief review con-cisely summarizes and highlights recent research progress in Ag₃PO₄-based all-solid-state Z-scheme photocatalytic systems with or without a solid-state electron mediator, focusing on their construc-tion, application, and reaction mechanism. Furthermore, the challenges and future prospects of Ag₃PO₄-based Z-scheme photocatalytic systems are discussed.

Key words: Silver phosphate, Photocatalysis, Z-scheme system, Application, Mechanism

Ming Ge, Zhenlu Li. Recent progress in Ag₃PO₄-based all-solid-state Z-scheme photocatalytic systems[J]. Chinese Journal of Catalysis, 2017, 38(11): 1794-1803.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62905-X

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Recent progress in Ag₃PO₄-based all-solid-state Z-scheme photocatalytic systems

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