Fundamental aspects in CO2 electroreduction reaction and solutions from in situ vibrational spectroscopies

doi:10.1016/S1872-2067(22)64095-6

Chinese Journal of Catalysis ›› 2022, Vol. 43 ›› Issue (11): 2772-2791.DOI: 10.1016/S1872-2067(22)64095-6

• Reviews • Previous Articles Next Articles

Fundamental aspects in CO₂ electroreduction reaction and solutions from in situ vibrational spectroscopies

Hong Li^a, Kun Jiang^b, Shou-Zhong Zou^c^,^#(), Wen-Bin Cai^a^,^*()

^aShanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai 200438, China
^bSchool of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
^cDepartment of Chemistry, American University, Washington, District of Columbia 20016, United States

Received:2022-04-30 Accepted:2022-07-27 Online:2022-11-18 Published:2022-10-20
Contact: Shou-Zhong Zou, Wen-Bin Cai
About author:Shouzhong Zou (Department of Chemistry, American University) earned his B.S. in Chemistry in 1991 and completed his MS studies in 1994 from Xiamen University under the guidance of Prof. Zhong-Qun Tian. He received his Ph.D. in Chemistry from Purdue University in 1999 under the direction of Prof. Michael J. Weaver. He then did postdoctoral work at Caltech with Profs. Fred C Anson and Ahmed H. Zewail. He started his independent research as an assistant professor in 2002 at Miami University (Oxford, Ohio), and was promoted to associate professor in 2008. He joined American University in the summer of 2015 as a full professor and chair. His research interests include developing catalysts for low temperature fuel cells, CO₂ reduction and gas sensing, and advancing spectroscopic and microscopic techniques for the characterization of surfaces and interfaces.
Wen-Bin Cai (Department of Chemistry, Fudan University) received his B.A. degree and M.S. degree from Shanghai University of Science and Technology in 1989 and 1992, respectively, under the guidance of Prof. Xun-Nan Deng and Ph.D. degree from Fudan University in 1995 under the guidance of Prof. Wei-Fang Zhou. From 1995 to 2002, he did postdoctoral research work consecutively at Xiamen University (with Prof. Zhong-Qun Tian), Hokkaido University (with Prof. Masatoshi Osawa), and Case Western Reserve University (with Profs. Daniel Scherson and James Burgess). Since July 2002, he has been a professor at Fudan University. His research interests cover interfacial spectroelectrochemistry and electrocatalysis, including but not limited to methodological development and application of electrochemical ATR-SEIRAS, mechanistic understanding and catalyst development towards electrocatalysis of small organic molecule oxidation, oxygen reduction and carbon dioxide reduction.
Supported by:
National Natural Science Foundation of China(21733004);National Natural Science Foundation of China(22002088);International Cooperation Program of Shanghai Science and Technology Committee(17520711200);Shanghai Sailing Program(20YF1420500)

Abstract

Abstract:

Using renewable energy to drive carbon dioxide reduction reaction (CO₂RR) electrochemically into chemicals with high energy density is an efficient way to achieve carbon neutrality, where the effective utilization of CO₂and the storage of renewable energy are realized. The reactivity and selectivity of CO₂RR depend on the structure and composition of the catalyst, applied potential, electrolyte, and pH of the solution. Besides, multiple electron and proton transfer steps are involved in CO₂RR, making the reaction pathways even more complicated. In pursuit of molecular-level insights into the CO₂RR processes, in situ vibrational methods including infrared, Raman and sum frequency generation spectroscopies have been deployed to monitor the dynamic evolution of catalyst structure, to identify reactive intermediates as well as to investigate the effect of local reaction environment on CO₂RR performance. This review summarizes key findings from recent electrochemical vibrational spectrosopic studies of CO₂RR in addressing the following issues: the CO₂RR mechanisms of different pathways, the role of surface-bound CO species, the compositional and structural effects of catalysts and electrolytes on CO₂RR activity and selectivity. Our perspectives on developing high sensitivity wide-frequency infrared spectroscopy, coupling different spectroelectrochemical methods and implementing operando vibrational spectroscopies to tackle the CO₂RR process in pilot reactors are offered at the end.

Key words: Carbon dioxide electroreduction reaction, Electrocatalytic mechanism, Vibrational spectroscopy, Intermediate, Structure-performance relation, Electrolyte effect

Hong Li, Kun Jiang, Shou-Zhong Zou, Wen-Bin Cai. Fundamental aspects in CO₂ electroreduction reaction and solutions from in situ vibrational spectroscopies[J]. Chinese Journal of Catalysis, 2022, 43(11): 2772-2791.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(22)64095-6

https://www.cjcatal.com/EN/Y2022/V43/I11/2772

Figures/Tables 11

Fig. 1. Fundamental issues for the electrochemical reduction of CO2.

Fig. 2. The schematic setup of electrochemical attenuated total reflection (ATR) infrared spectroscopy (a) and Raman spectrocopy (b). Reprinted with permission from Ref. [32]. Copyright 2020, Proceedings of the National Academy of Sciences. (c) Sum-frequency generation spectroscopy. Reprinted with permission from Ref. [33]. Copyright 2019, American Chemical Society. Note: WE refers to working electrode, RE to reference electrode and CE to counter electrode.

Fig. 3. Simplified flowchart of CO2RR mechanisms leading to C1 and C2+ product generation. * Corresponds to adsorbed species, > 2e- reduction products of CH4 and C2+ that go through the reduction of *CO intermediate (*COR) are marked in light blue. Reprinted with permission from Ref. [52]. Copyright 2020, American Chemical Society.

Fig. 4. (a) In situ time-dependent ATR-IR spectra of CO2RR on Sn electrodes at -1.4 V vs. Ag/AgCl in 0.1 mol/L K2SO4 solution saturated with CO2. The black arrow shows the direction of evolution with time and the red frame shows the carbonate species. Reprinted with permission from Ref. [53]. Copyright 2015, American Chemical Society. (b) ATR-IR spectra of thin films of indium, tin, lead, and bismuth on exposure to CO2 under reducing conditions. Reprinted with permission from Ref. [54]. Copyright 2016, American Chemical Society. In situ ATR-SEIRAS collected under different applied potentials in CO2 saturated (c) and Ar-saturated (d) 0.5 mol/L KHCO3. Reprinted with permission from Ref. [55]. Copyright 2020, John Wiley and Sons.

Fig. 5. (a) In situ SERS spectra of CO2RR at nanoporous Ag surfaces in 0.1 mol/L KHCO3 solution saturated with CO2. The arrow on the right shows the potential scanning direction. Peaks marked with black and red dashed lines are attributed to the reported and new SERS signals, respectively. Reprinted with permission from Ref. [64]. Copyright 2020, American Chemical Society. (b) Vibrational sum-frequency generation study of CO2RR at Pt/EMIM-BF4 interfaces. Reprinted with permission from Ref. [65]. Copyright 2016, Elsevier.

Fig. 6. (a) Simulated structures of possible adsorbates on Cu(100) for CO2RR and their calculated infrared-active vibrational frequencies. Cu, Li, C, O, and H atoms are depicted as orange, yellow, gray, red and white spheres. Reprinted with permission from Ref. [60]. Copyright 2017, John Wiley and Sons. (b) The vibrational density of states (v-DoSs) of *OC-CO, *OC-COH, *HOC-COH, *C-COH, *CH-COH, *C-CH, *C-CH2, and *C=C=O intermediate. In A2-G2, v-DoS from quantum mechanics molecular dynamics (QM-MD) is shown as a solid black line, the experimental frequencies are shown as a red dashed line, and the vibrational frequencies from v-QM optimization are shown as solid blue lines for comparison. Reprinted with permission from Ref. [51]. Copyright 2019, Proceedings of the National Academy of Sciences. (c) In situ Raman spectra in CO2-saturated 0.2 mol/L NaHCO3 for iodide-derived copper (ID-Cu) and oxide-derived copper (OD-Cu) samples shown the enlarged region between 850-1150 cm-1 at -1.0 V vs. Ag/AgCl. (d) The -CHx stretching region between 2700-3000 cm-1 at -0.8 V vs. Ag/AgCl. Reprinted with permission from Ref. [72]. Copyright 2020, John Wiley and Sons.

Fig. 7. The adsorption configuration of CO on metal electrodes and the corresponding positions in the vibrational spectrum.

Fig. 8. The schematic diagrams showing the roles of COtop and CObrigde on different electrodes. (a) Au electrode. Reprinted with permission from Ref. [84]. Copyright 2016, Proceedings of the National Academy of Sciences. (b) Pd electrode. Reprinted with permission from Ref. [85]. Copyright 2021, American Chemical Society. (c) Polycrystalline Cu electrode. Reprinted with permission from Ref. [82]. Copyright 2018, American Chemical Society. (d) Cu electrode with Cu(0) and Cu(I). Reprinted with permission from Ref. [86]. Copyright 2020, American Chemical Society.

Fig. 9. Schematic diagrams for the observed processes on anodic treatment of mechanically polished polycrystalline Cu electrode during CO2RR using in situ time-resolved surface-enhanced Raman spectroscopy. Reprinted with permission from Ref. [98]. Copyright 2021, John Wiley and Sons.

Fig. 10. Controversial views on OD-Cu catalysts during CO2RR. (a) Partially positive-charged copper (Cuδ+) is to boost the formation of highly valued multicarbon C2+ products during CO2RR. Reprinted with permission from Ref. [111]. Copyright 2020, American Chemical Society. (b) The electrochemical prereduction process, during which Cu2O nanocubes were converted into metallic Cu phase under a negative potential of -0.34 V vs. RHE. Reprinted with permission from Ref. [32]. Copyright 2020, Proceedings of the National Academy of Sciences of the United States of American. (c) Cu(100)/Cu(111) interfaces as superior active sites for CO dimerization during CO2RR. Reprinted with permission from Ref. [109]. Copyright 2021, American Chemical Society. (d) Role of a hydroxide layer on Cu electrodes in electrochemical CO2 Reduction. Reprinted with permission from Ref. [95]. Copyright 2019, American Chemical Society.

Fig. 11. (a) Schematic illustration of the effect of alkali metal cations on the local interfacial electric field on Cu electrodes. (b) Peak frequencies of the C≡O stretch band of linearly-bonded CO as a function of applied potential in CO-saturated 0.1 mol/L alkali metal bicarbonates as indicated. Reprinted with permission from Ref. [149]. Copyright 2017, The Royal Society of Chemistry. (c) Schematic illustration of the effect of alkali metal cations on local pH on Cu electrodes. (d) Steady-state pH at the metal-electrolyte interface during the electroreduction of CO2 at -1.0 V vs. RHE in CO2-saturated 0.05 mol/L M2CO3 solutions (M = Li+, Na+, K+, Cs+). Reprinted with permission from Ref. [154]. Copyright 2017, American Chemical Society.

References

[1]	O. S. Bushuyev, P. De Luna, C. T. Dinh, L. Tao, G. Saur, J. Van De Lagemaat, S. O. Kelley, E. H. Sargent, Joule, 2018, 2, 825-832.
[2]	J. Resasco, A. T. Bell, Trends Chem., 2020, 2, 825-836.
[3]	X. Zhao, L. Du, B. You, Y. Sun, Catal. Sci. Technol., 2020, 10, 2711-2720.
[4]	Y. Y. Birdja, E. Pérez-Gallent, M. C. Figueiredo, A. J. Göttle, F. Calle-Vallejo, M. T. M. Koper, Nat. Energy, 2019, 4, 732-745.
[5]	G. Wang, J. Chen, Y. Ding, P. Cai, L. Yi, Y. Li, C. Tu, Y. Hou, Z. Wen, L. Dai, Chem. Soc. Rev., 2021, 50, 4993-5061.
[6]	F. Liang, K. Zhang, L. Zhang, Y. Zhang, Y. Lei, X. Sun, Small, 2021, 17, 2100323.
[7]	M. G. Kibria, J. P. Edwards, C. M. Gabardo, C. T. Dinh, A. Seifitokaldani, D. Sinton, E. H. Sargent, Adv. Mater., 2019, 31, 1807166.
[8]	D. Gao, R. M. Arán-Ais, H. S. Jeon, B. Roldan Cuenya, Nat. Catal., 2019, 2, 198-210.
[9]	F. Franco, C. Rettenmaier, H. S. Jeon, B. Roldan Cuenya, Chem. Soc. Rev., 2020, 49, 6884-6946.
[10]	Y. Wang, J. Liu, G. Zheng, Adv. Mater., 2021, 33, 2005798.
[11]	L. Zhang, Z. J. Zhao, J. Gong, Angew. Chem. Int. Ed., 2017, 56, 11326-11353.
[12]	S. Zhu, M. Shao, J. Solid. State. Electrochem., 2015, 20, 861-873.
[13]	S. Nitopi, E. Bertheussen, S. B. Scott, X. Liu, A. K. Engstfeld, S. Horch, B. Seger, I. E. L. Stephens, K. Chan, C. Hahn, J. K. Norskov, T. F. Jaramillo, I. Chorkendorff, Chem. Rev., 2019, 119, 7610-7672.
[14]	C. Liu, J. Gong, Z. Gao, L. Xiao, G. Wang, J. Lu, L. Zhuang, Sci. China Chem., 2021, 64, 1660-1678.
[15]	B. Deng, M. Huang, X. Zhao, S. Mou, F. Dong, ACS Catal., 2021, 12, 331-362.
[16]	S. Sharifi Golru, E. J. Biddinger, Chem. Eng. J., 2022, 428, 131303.
[17]	A. J. Garza, A. T. Bell, M. Head-Gordon, ACS Catal., 2018, 8, 1490-1499.
[18]	L. R. L. Ting, B. S. Yeo, Curr. Opin. Electrochem., 2018, 8, 126-134.
[19]	W. Ma, X. He, W. Wang, S. Xie, Q. Zhang, Y. Wang, Chem. Soc. Rev., 2021, 50, 12897-12914.
[20]	P. Zhu, H. Wang, Nat. Catal., 2021, 4, 943-951.
[21]	E. W. Lees, B. A. W. Mowbray, F. G. L. Parlane, C. P. Berlinguette, Nat. Rev. Mater., 2022, 7, 55-64.
[22]	C. T. Dinh, T. Burdyny, M. G. Kibria, A. Seifitokaldani, C. M. Gabardo, F. P. G. De Arquer, A. Kiani, J. P. Edwards, P. De Luna, O. S. Bushuyev, C. Q. Zou, R. Quintero-Bermudez, Y. J. Pang, D. Sinton, E. H. Sargent, Science, 2018, 360, 783-787.
[23]	J. Wang, F. Zhang, X. Kang, S. Chen, Curr. Opin. Electrochem., 2019, 13, 40-46.
[24]	J. Timoshenko, B. Roldan Cuenya, Chem. Rev., 2021, 121, 882-961.
[25]	X. Li, S. Wang, L. Li, Y. Sun, Y. Xie, J. Am. Chem. Soc., 2020, 142, 9567-9581.
[26]	A. D. Handoko, F. Wei, Jenndy, B. S. Yeo, Z. W. Seh, Nat. Catal., 2018, 1, 922-934.
[27]	S. Ye, T. Kondo, N. Hoshi, J. Inukai, S. Yoshimoto, M. Osawa, K. Itaya, Electrochemistry, 2009, 77, 2-20.
[28]	X. Cao, D. Tan, B. Wulan, K. S. Hui, K. N. Hui, J. Zhang, Small Methods, 2021, 5, 2100700.
[29]	N. Heidary, K. H. Ly, N. Kornienko, Nano Lett., 2019, 19, 4817-4826.
[30]	H. Wang, Y.-W. Zhou, W.-B. Cai, Curr. Opin. Electrochem., 2017, 1, 73-79.
[31]	L. Jin, A. Seifitokaldani, Catalysts, 2020, 10, 481.
[32]	P. Zhu, C. Xia, C. Y. Liu, K. Jiang, G. Gao, X. Zhang, Y. Xia, Y. Lei, H. N. Alshareef, T. P. Senftle, H. Wang, Proc. Natl. Acad. Sci. U. S. A., 2021, 118, e2010868118.
[33]	A. Kemna, N. García Rey, B. Braunschweig, ACS Catal., 2019, 9, 6284-6292.
[34]	S. Zhu, T. Li, W.-B. Cai, M. Shao, ACS Energy Lett., 2019, 4, 682-689.
[35]	M. Osawa, K. Yoshii, Appl. Spectrosc., 1997, 51, 512-518.
[36]	M. Osawa, Surface-Enhanced Infrared Absorption Spectroscopy. Springer, Singapore, 2018, 697-706.
[37]	Y.-Y. Yang, H.-X. Zhang, W.-B. Cai, J. Electrochem., 2013, 19, 6-16.
[38]	H. Miyake, S. Ye, M. Osawa, Electrochem. Commun., 2002, 4, 973-977.
[39]	S.-J. Huo, X.-K. Xue, Q.-X. Li, S.-F. Xu, W.-B. Cai, J. Phys. Chem. B, 2006, 110, 25721-25728.
[40]	H.-F. Wang, Y.-G. Yan, S.-J. Huo, W.-B. Cai, Q.-J. Xu, M. Osawa, Electrochim. Acta, 2007, 52, 5950-5957.
[41]	H.-L. Wang, E.-M. You, R. Panneerselvam, S.-Y. Ding, Z.-Q. Tian, Light-Sci. Appl., 2021, 10, 161.
[42]	H.-Q. Chen, L. Zou, D.-Y. Wei, L.-L. Zheng, Y.-F. Wu, H. Zhang, J.-F. Li, Chin. J. Catal., 2022, 43, 33-46.
[43]	J. F. Li, Y. J. Zhang, S. Y. Ding, R. Panneerselvam, Z. Q. Tian, Chem. Rev., 2017, 117, 5002-5069.
[44]	C. Zhan, X. J. Chen, Y. F. Huang, D. Y. Wu, Z. Q. Tian, Acc. Chem. Res., 2019, 52, 2784-2792.
[45]	S. Ye, M. Osawa, K. Uosaki, J. Vac. Soc. Jpn,. 2004, 47, 439-445.
[46]	Y. Tong, Y. Zhao, N. Li, M. Osawa, P. B. Davies, S. Ye, J. Chem. Phys., 2010, 133, 034705.
[47]	S. Wallentine, S. Bandaranayake, S. Biswas, L. R. Baker, J. Phys. Chem. A, 2020, 124, 8057-8064.
[48]	Y. Hori, in: Modern Aspects of Electrochemistry, C. G. Vayenas, R. E. White, M. E. Gamboa-Aldeco, Ed, Springer, New York, 2008, 89-189.
[49]	A. Bagger, W. Ju, A. S. Varela, P. Strasser, J. Rossmeisl, ChemPhysChem, 2017, 18, 3266-3273.
[50]	Y. Katayama, F. Nattino, L. Giordano, J. Hwang, R. R. Rao, O. Andreussi, N. Marzari, Y. Shao-Horn, J. Phys. Chem. C, 2018, 123, 5951-5963.
[51]	T. Cheng, A. Fortunelli, W. A. Goddard, III, Proc. Natl. Acad. Sci. U. S. A., 2019, 116, 7718-7722.
[52]	K. Jiang, Y. Huang, G. Zeng, F. M. Toma, W. A. Goddard, III, A. T. Bell, ACS Energy Lett., 2020, 5, 1206-1214.
[53]	M. F. Baruch, J. E. Pander, J. L. White, A. B. Bocarsly, ACS Catal., 2015, 5, 3148-3156.
[54]	J. E. Pander, M. F. Baruch, A. B. Bocarsly, ACS Catal., 2016, 6, 7824-7833.
[55]	C. Cao, D. D. Ma, J. F. Gu, X. Xie, G. Zeng, X. Li, S. G. Han, Q. L. Zhu, X. T. Wu, Q. Xu, Angew. Chem. Int. Ed., 2020, 59, 15014-15020.
[56]	A. Dutta, A. Kuzume, M. Rahaman, S. Vesztergom, P. Broekmann, ACS Catal., 2015, 5, 7498-7502.
[57]	K. R. Phillips, Y. Katayama, J. Hwang, Y. Shao-Horn, J. Phys. Chem. Lett., 2018, 9, 4407-4412.
[58]	A. Dutta, I. Zelocualtecatl Montiel, K. Kiran, A. Rieder, V. Grozovski, L. Gut, P. Broekmann, ACS Catal., 2021, 11, 4988-5003.
[59]	S. Zhu, B. Jiang, W. B. Cai, M. Shao, J. Am. Chem. Soc., 2017, 139, 15664-15667.
[60]	E. Pérez-Gallent, M. C. Figueiredo, F. Calle-Vallejo, M. T. Koper, Angew. Chem. Int. Ed., 2017, 56, 3621-3624.
[61]	K. P. Kuhl, T. Hatsukade, E. R. Cave, D. N. Abram, J. Kibsgaard, T. F. Jaramillo, J. Am. Chem. Soc., 2014, 136, 14107-14113.
[62]	S. Jin, Z. Hao, K. Zhang, Z. Yan, J. Chen, Angew. Chem. Int. Ed., 2021, 60, 20627-20648.
[63]	N. J. Firet, W. A. Smith, ACS Catal., 2017, 7, 606-612.
[64]	W. Shan, R. Liu, H. Zhao, Z. He, Y. Lai, S. Li, G. He, J. Liu, ACS Nano, 2020, 14, 11363-11372.
[65]	B. Braunschweig, P. Mukherjee, J. L. Haan, D. D. Dlott, J. Electroanal. Chem., 2017, 800, 144-150.
[66]	M. Dunwell, W. Luc, Y. Yan, F. Jiao, B. Xu, ACS Catal., 2018, 8, 8121-8129.
[67]	S. Wallentine, S. Bandaranayake, S. Biswas, L. R. Baker, J. Phys. Chem. Lett., 2020, 11, 8307-8313.
[68]	B. A. Rosen, A. Salehi-Khojin, M. R. Thorson, W. Zhu, D. T. Whipple, P. J. A. Kenis, R. I. Masel, Science, 2011, 334, 643-644.
[69]	N. García Rey, D. D. Dlott, J. Phys. Chem. C, 2015, 119, 20892-20899.
[70]	B. A. Rosen, J. L. Haan, P. Mukherjee, B. Braunschweig, W. Zhu, A. Salehi-Khojin, D. D. Dlott, R. I. Masel, J. Phys. Chem. C, 2012, 116, 15307-15312.
[71]	R. Kortlever, J. Shen, K. J. Schouten, F. Calle-Vallejo, M. T. M. Koper, J. Phys. Chem. Lett., 2015, 6, 4073-4082.
[72]	A. Vasileff, Y. Zhu, X. Zhi, Y. Zhao, L. Ge, H. M. Chen, Y. Zheng, S. Z. Qiao, Angew. Chem. Int. Ed., 2020, 59, 19649-19653.
[73]	Y. Kim, S. Park, S.-J. Shin, W. Choi, B. K. Min, H. Kim, W. Kim, Y. J. Hwang, Energy Environ. Sci., 2020, 13, 4301-4311.
[74]	W. Ma, S. Xie, T. Liu, Q. Fan, J. Ye, F. Sun, Z. Jiang, Q. Zhang, J. Cheng, Y. Wang, Nat. Catal., 2020, 3, 478-487.
[75]	J. Li, X. Chang, H. Zhang, A. S. Malkani, M. J. Cheng, B. Xu, Q. Lu, Nat. Commun., 2021, 12, 3264.
[76]	A. D. Handoko, K. W. Chan, B. S. Yeo, ACS Energy Lett., 2017, 2, 2103-2109.
[77]	M. Ma, K. Djanashvili, W. A. Smith, Angew. Chem. Int. Ed., 2016, 55, 6680-6684.
[78]	K. D. Yang, W. R. Ko, J. H. Lee, S. J. Kim, H. Lee, M. H. Lee, K. T. Nam, Angew. Chem. Int. Ed., 2017, 56, 796-800.
[79]	A. Dutta, M. Rahaman, N. C. Luedi, M. Mohos, P. Broekmann, ACS Catal., 2016, 6, 3804-3814.
[80]	Z. C. Huang-Fu, Q. T. Song, Y. H. He, J. J. Wang, J. Y. Ye, Z. Y. Zhou, S. G. Sun, Z. H. Wang, Phys. Chem. Chem. Phys., 2019, 21, 25047-25053.
[81]	C. M. Gunathunge, J. Li, X. Li, M. M. Waegele, ACS Catal., 2020, 10, 11700-11711.
[82]	C. M. Gunathunge, V. J. Ovalle, Y. Li, M. J. Janik, M. M. Waegele, ACS Catal., 2018, 8, 7507-7516.
[83]	F. Li, A. Thevenon, A. Rosas-Hernandez, Z. Wang, Y. Li, C. M. Gabardo, A. Ozden, C. T. Dinh, J. Li, Y. Wang, J. P. Edwards, Y. Xu, C. Mccallum, L. Tao, Z. Q. Liang, M. Luo, X. Wang, H. Li, C. P. O'brien, C. S. Tan, D. H. Nam, R. Quintero-Bermudez, T. T. Zhuang, Y. C. Li, Z. Han, R. D. Britt, D. Sinton, T. Agapie, J. C. Peters, E. H. Sargent, Nature, 2020, 577, 509-513.
[84]	A. Wuttig, M. Yaguchi, K. Motobayashi, M. Osawa, Y. Surendranath, Proc. Natl. Acad. Sci. U. S. A., 2016, 113, E4585-E4593.
[85]	T.-W. Jiang, Y.-W. Zhou, X.-Y. Ma, X. Qin, H. Li, C. Ding, B. Jiang, K. Jiang, W.-B. Cai, ACS Catal., 2021, 11, 840-848.
[86]	T. C. Chou, C. C. Chang, H. L. Yu, W. Y. Yu, C. L. Dong, J. J. Velasco-Velez, C. H. Chuang, L. C. Chen, J. F. Lee, J. M. Chen, H. L. Wu, J. Am. Chem. Soc., 2020, 142, 2857-2867.
[87]	X. Chang, Y. Zhao, B. Xu, ACS Catal., 2020, 10, 13737-13747.
[88]	C. Zhan, F. Dattila, C. Rettenmaier, A. Bergmann, S. Kühl, R. García-Muelas, N. López, B. R. Cuenya, ACS Catal., 2021, 11, 7694-7701.
[89]	A. Wuttig, C. Liu, Q. Peng, M. Yaguchi, C. H. Hendon, K. Motobayashi, S. Ye, M. Osawa, Y. Surendranath, ACS Cent. Sci., 2016, 2, 522-528.
[90]	C. M. Gunathunge, X. Li, J. Li, R. P. Hicks, V. J. Ovalle, M. M. Waegele, J. Phys. Chem. C, 2017, 121, 12337-12344.
[91]	Z. Li, Y. Yang, Z. Yin, X. Wei, H. Peng, K. Lyu, F. Wei, L. Xiao, G. Wang, H. D. Abruña, J. Lu, L. Zhuang, ACS Catal., 2021, 11, 2473-2482.
[92]	A. Wuttig, J. Ryu, Y. Surendranath, J. Phys. Chem. C, 2021, 125, 17042-17050.
[93]	A. S. Malkani, J. Li, J. Anibal, Q. Lu, B. Xu, ACS Catal., 2019, 10, 941-946.
[94]	C. M. Gunathunge, J. Li, X. Li, J. J. Hong, M. M. Waegele, ACS Catal., 2020, 10, 6908-6923.
[95]	G. Iijima, T. Inomata, H. Yamaguchi, M. Ito, H. Masuda, ACS Catal., 2019, 9, 6305-6319.
[96]	G. Iijima, H. Yamaguchi, T. Inomata, H. Yoto, M. Ito, H. Masuda, ACS Catal., 2020, 10, 15238-15249.
[97]	A. S. Malkani, M. Dunwell, B. Xu, ACS Catal., 2019, 9, 474-478.
[98]	H. An, L. Wu, L. D. B. Mandemaker, S. Yang, J. De Ruiter, J. H. J. Wijten, J. C. L. Janssens, T. Hartman, W. Van Der Stam, B. M. Weckhuysen, Angew. Chem. Int. Ed., 2021, 60, 16576-16584.
[99]	C. W. Li, M. W. Kanan, J. Am. Chem. Soc., 2012, 134, 7231-7234.
[100]	C. W. Li, J. Ciston, M. W. Kanan, Nature, 2014, 508, 504-507.
[101]	A. Verdaguer-Casadevall, C. W. Li, T. P. Johansson, S. B. Scott, J. T. Mckeown, M. Kumar, I. E. Stephens, M. W. Kanan, I. Chorkendorff, J. Am. Chem. Soc., 2015, 137, 9808-9811.
[102]	S. Y. Lee, H. Jung, N. K. Kim, H. S. Oh, B. K. Min, Y. J. Hwang, J. Am. Chem. Soc., 2018, 140, 8681-8689.
[103]	Y. Zhou, F. Che, M. Liu, C. Zou, Z. Liang, P. De Luna, H. Yuan, J. Li, Z. Wang, H. Xie, H. Li, P. Chen, E. Bladt, R. Quintero-Bermudez, T. K. Sham, S. Bals, J. Hofkens, D. Sinton, G. Chen, E. H. Sargent, Nat. Chem., 2018, 10, 974-980.
[104]	C. Chen, X. Sun, L. Lu, D. Yang, J. Ma, Q. Zhu, Q. Qian, B. Han, Green Chem., 2018, 20, 4579-4583.
[105]	W. Zhang, P. He, C. Wang, T. Ding, T. Chen, X. Liu, L. Cao, T. Huang, X. Shen, O. A. Usoltsev, A. L. Bugaev, Y. Lin, T. Yao, J. Mater. Chem. A, 2020, 8, 25970-25977.
[106]	Q. Fan, X. Zhang, X. Ge, L. Bai, D. He, Y. Qu, C. Kong, J. Bi, D. Ding, Y. Cao, X. Duan, J. Wang, J. Yang, Y. Wu, Adv. Energy Mater., 2021, 11, 2101424.
[107]	Z. Chen, T. Wang, B. Liu, D. Cheng, C. Hu, G. Zhang, W. Zhu, H. Wang, Z. J. Zhao, J. Gong, J. Am. Chem. Soc., 2020, 142, 6878-6883.
[108]	D. Zhong, Z. J. Zhao, Q. Zhao, D. Cheng, B. Liu, G. Zhang, W. Deng, H. Dong, L. Zhang, J. Li, J. Li, J. Gong, Angew. Chem. Int. Ed., 2021, 60, 4879-4885.
[109]	Z. Z. Wu, X. L. Zhang, Z. Z. Niu, F. Y. Gao, P. P. Yang, L. P. Chi, L. Shi, W. S. Wei, R. Liu, Z. Chen, S. Hu, X. Zheng, M. R. Gao, J. Am. Chem. Soc., 2021, 144, 259-269.
[110]	K. Jiang, R. B. Sandberg, A. J. Akey, X. Liu, D. C. Bell, J. K. Nørskov, K. Chan, H. Wang, Nat. Catal., 2018, 1, 111-119.
[111]	K. K. Patra, S. Park, H. Song, B. Kim, W. Kim, J. Oh, ACS Appl. Energ. Mater., 2020, 3, 11343-11349.
[112]	P. De Luna, R. Quintero-Bermudez, C.-T. Dinh, M. B. Ross, O. S. Bushuyev, P. Todorović, T. Regier, S. O. Kelley, P. Yang, E. H. Sargent, Nat. Catal., 2018, 1, 103-110.
[113]	P. P. Yang, X. L. Zhang, F. Y. Gao, Y. R. Zheng, Z. Z. Niu, X. Yu, R. Liu, Z. Z. Wu, S. Qin, L. P. Chi, Y. Duan, T. Ma, X. S. Zheng, J. F. Zhu, H. J. Wang, M. R. Gao, S. H. Yu, J. Am. Chem. Soc., 2020, 142, 6400-6408.
[114]	X. Feng, K. Jiang, S. Fan, M. W. Kanan, ACS Cent. Sci., 2016, 2, 169-174.
[115]	H. Jung, S. Y. Lee, C. W. Lee, M. K. Cho, D. H. Won, C. Kim, H. S. Oh, B. K. Min, Y. J. Hwang, J. Am. Chem. Soc., 2019, 141, 4624-4633.
[116]	C. Chen, X. Sun, X. Yan, Y. Wu, M. Liu, S. Liu, Z. Zhao, B. Han, Green Chem., 2020, 22, 1572-1576.
[117]	R. Kas, R. Kortlever, A. Milbrat, M. T. Koper, G. Mul, J. Baltrusaitis, Phys. Chem. Chem. Phys., 2014, 16, 12194-12201.
[118]	L. Mandal, K. R. Yang, M. R. Motapothula, D. Ren, P. Lobaccaro, A. Patra, M. Sherburne, V. S. Batista, B. S. Yeo, J. W. Ager, J. Martin, T. Venkatesan, ACS Appl. Mater. Interfaces, 2018, 10, 8574-8584.
[119]	M. He, C. Li, H. Zhang, X. Chang, J. G. Chen, W. A. Goddard, III, M. J. Cheng, B. Xu, Q. Lu, Nat. Commun., 2020, 11, 3844.
[120]	C. Li, H. Xiong, M. He, B. Xu, Q. Lu, ACS Catal., 2021, 11, 12029-12037.
[121]	W. Deng, L. Zhang, L. Li, S. Chen, C. Hu, Z. J. Zhao, T. Wang, J. Gong, J. Am. Chem. Soc., 2019, 141, 2911-2915.
[122]	P. Iyengar, M. J. Kolb, J. R. Pankhurst, F. Calle-Vallejo, R. Buonsanti, ACS Catal., 2021, 11, 4456-4463.
[123]	L. R. L. Ting, O. Piqué, S. Y. Lim, M. Tanhaei, F. Calle-Vallejo, B. S. Yeo, ACS Catal., 2020, 10, 4059-4069.
[124]	D. Higgins, A. T. Landers, Y. Ji, S. Nitopi, C. G. Morales-Guio, L. Wang, K. Chan, C. Hahn, T. F. Jaramillo, ACS Energy Lett., 2018, 3, 2947-2955.
[125]	L. Xiong, X. Zhang, L. Chen, Z. Deng, S. Han, Y. Chen, J. Zhong, H. Sun, Y. Lian, B. Yang, X. Yuan, H. Yu, Y. Liu, X. Yang, J. Guo, M. H. Rummeli, Y. Jiao, Y. Peng, Adv. Mater., 2021, 33, 2101741.
[126]	A. Herzog, A. Bergmann, H. S. Jeon, J. Timoshenko, S. Kühl, C. Rettenmaier, M. Lopez Luna, F. T. Haase, B. Roldan Cuenya, Angew. Chem. Int. Ed., 2021, 60, 7426-7435.
[127]	E. L. Clark, C. Hahn, T. F. Jaramillo, A. T. Bell, J. Am. Chem. Soc., 2017, 139, 15848-15857.
[128]	T. T. H. Hoang, S. Verma, S. Ma, T. T. Fister, J. Timoshenko, A. I. Frenkel, P. J. A. Kenis, A. A. Gewirth, J. Am. Chem. Soc., 2018, 140, 5791-5797.
[129]	Y. C. Li, Z. Wang, T. Yuan, D. H. Nam, M. Luo, J. Wicks, B. Chen, J. Li, F. Li, F. P. G. De Arquer, Y. Wang, C. T. Dinh, O. Voznyy, D. Sinton, E. H. Sargent, J. Am. Chem. Soc., 2019, 141, 8584-8591.
[130]	D. Ren, B. S.-H. Ang, B. S. Yeo, ACS Catal., 2016, 6, 8239-8247.
[131]	S. Lee, G. Park, J. Lee, ACS Catal., 2017, 7, 8594-8604.
[132]	J. Gao, H. Zhang, X. Guo, J. Luo, S. M. Zakeeruddin, D. Ren, M. Gratzel, J. Am. Chem. Soc., 2019, 141, 18704-18714.
[133]	J. Huang, M. Mensi, E. Oveisi, V. Mantella, R. Buonsanti, J. Am. Chem. Soc., 2019, 141, 2490-2499.
[134]	Z.-J. Sun, M. M. Sartin, W. Chen, F. He, J. Cai, X.-X. Ye, J.-L. Lu, Y.-X. Chen, Chin. J. Chem. Phys., 2020, 33, 303-310.
[135]	H. Li, T.-W. Jiang, X. Qin, J. Chen, X.-Y. Ma, K. Jiang, X.-G. Zhang, W.-B. Cai, ACS Catal., 2021, 11, 6846-6856.
[136]	H. Li, X. Qin, T. Jiang, X. Y. Ma, K. Jiang, W. B. Cai, ChemCatChem, 2019, 11, 6139-6146.
[137]	J.-S. Wang, G.-C. Zhao, Y.-Q. Qiu, C.-G. Liu, J. Phys. Chem. C, 2020, 125, 572-582.
[138]	T. T. Zhuang, D. H. Nam, Z. Wang, H. H. Li, C. M. Gabardo, Y. Li, Z. Q. Liang, J. Li, X. J. Liu, B. Chen, W. R. Leow, R. Wu, X. Wang, F. Li, Y. Lum, J. Wicks, C. P. O'brien, T. Peng, A. H. Ip, T. K. Sham, S. H. Yu, D. Sinton, E. H. Sargent, Nat. Commun., 2019, 10, 4807.
[139]	Y. Deng, Y. Huang, D. Ren, A. D. Handoko, Z. W. Seh, P. Hirunsit, B. S. Yeo, ACS Appl. Mater. Interfaces, 2018, 10, 28572-28581.
[140]	Z. Pan, K. Wang, K. Ye, Y. Wang, H.-Y. Su, B. Hu, J. Xiao, T. Yu, Y. Wang, S. Song, ACS Catal., 2020, 10, 3871-3880.
[141]	D. Liu, Y. Liu, M. Li, J. Phys. Chem. C, 2020, 124, 6145-6153.
[142]	Y. Song, J. R. C. Junqueira, N. Sikdar, D. Ohl, S. Dieckhofer, T. Quast, S. Seisel, J. Masa, C. Andronescu, W. Schuhmann, Angew. Chem. Int. Ed., 2021, 60, 23427-23434.
[143]	S. Ringe, E. L. Clark, J. Resasco, A. Walton, B. Seger, A. T. Bell, K. Chan, Energy Environ. Sci., 2019, 12, 3001-3014.
[144]	L. D. Chen, M. Urushihara, K. Chan, J. K. Nørskov, ACS Catal., 2016, 6, 7133-7139.
[145]	A. S. Malkani, J. Anibal, B. Xu, ACS Catal., 2020, 10, 14871-14876.
[146]	G. Hussain, L. Pérez-Martínez, J.-B. Le, M. Papasizza, G. Cabello, J. Cheng, A. Cuesta, Electrochim. Acta, 2019, 327, 135055.
[147]	J. Resasco, L. D. Chen, E. Clark, C. Tsai, C. Hahn, T. F. Jaramillo, K. Chan, A. T. Bell, J. Am. Chem. Soc., 2017, 139, 11277-11287.
[148]	M. R. Singh, Y. Kwon, Y. Lum, J. W. Ager, III, A. T. Bell, J. Am. Chem. Soc., 2016, 138, 13006-13012.
[149]	C. M. Gunathunge, V. J. Ovalle, M. M. Waegele, Phys. Chem. Chem. Phys., 2017, 19, 30166-30172.
[150]	H. Liu, J. Liu, B. Yang, ACS Catal., 2021, 11, 12336-12343.
[151]	E. Pérez-Gallent, G. Marcandalli, M. C. Figueiredo, F. Calle-Vallejo, M. T. M. Koper, J. Am. Chem. Soc., 2017, 139, 16412-16419.
[152]	K. Ogura, J. R. Ferrell, A. V. Cugini, E. S. Smotkin, M. D. Salazar-Villalpando, Electrochim. Acta, 2010, 56, 381-386.
[153]	W. Deng, T. Yuan, S. Chen, H. Li, C. Hu, H. Dong, B. Wu, T. Wang, J. Li, G. A. Ozin, J. Gong, Fundamental Res., 2021, 1, 432-438.
[154]	O. Ayemoba, A. Cuesta, ACS Appl. Mater. Interfaces, 2017, 9, 27377-27382.
[155]	M. C. O. Monteiro, F. Dattila, B. Hagedoorn, R. García-Muelas, N. López, M. T. M. Koper, Nat. Catal., 2021, 4, 654-662.
[156]	K. Ye, G. Zhang, X.-Y. Ma, C. Deng, X. Huang, C. Yuan, G. Meng, W.-B. Cai, K. Jiang, Energy Environ. Sci., 2022, 15, 749-759.
[157]	J. Li, D. Wu, A. S. Malkani, X. Chang, M. J. Cheng, B. Xu, Q. Lu, Angew. Chem. Int. Ed., 2020, 59, 4464-4469.
[158]	J. Li, X. Li, C. M. Gunathunge, M. M. Waegele, Proc. Natl. Acad. Sci. U. S. A., 2019, 116, 9220-9229.
[159]	G. Marcandalli, A. Goyal, M. T. M. Koper, ACS Catal., 2021, 11, 4936-4945.
[160]	M. Dunwell, Q. Lu, J. M. Heyes, J. Rosen, J. G. Chen, Y. Yan, F. Jiao, B. Xu, J. Am. Chem. Soc., 2017, 139, 3774-3783.
[161]	K. Yang, R. Kas, W. A. Smith, J. Am. Chem. Soc., 2019, 141, 15891-15900.
[162]	D. Gao, F. Scholten, B. Roldan Cuenya, ACS Catal., 2017, 7, 5112-5120.
[163]	V. J. Ovalle, M. M. Waegele, J. Phys. Chem. C, 2020, 124, 14713-14721.

Fundamental aspects in CO₂ electroreduction reaction and solutions from in situ vibrational spectroscopies

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

Figures/Tables 11

References

Related Articles 15

Recommended Articles

Metrics

[1]	Jing Shi, Yu-Hua Guo, Fei Xie, Ming-Tian Zhang, Hong-Tao Zhang. Electronic effects of redox-active ligands on ruthenium-catalyzed water oxidation [J]. Chinese Journal of Catalysis, 2023, 52(9): 271-279.
[2]	Liyuan Gong, Ying Wang, Jie Liu, Xian Wang, Yang Li, Shuai Hou, Zhijian Wu, Zhao Jin, Changpeng Liu, Wei Xing, Junjie Ge. Reshaping the coordination and electronic structure of single atom sites on the right branch of ORR volcano plot [J]. Chinese Journal of Catalysis, 2023, 50(7): 352-360.
[3]	Si-Na Qin, Di-Ye Wei, Jie Wei, Jia-Sheng Lin, Qing-Qi Chen, Yuan-Fei Wu, Huai-Zhou Jin, Hua Zhang, Jian-Feng Li. Direct identification of the carbonate intermediate during water-gas shift reaction at Pt-NiO interfaces using surface-enhanced Raman spectroscopy [J]. Chinese Journal of Catalysis, 2022, 43(8): 2010-2016.
[4]	Chuncheng Liu, Evgeny A. Uslamin, Sophie H. van Vreeswijk, Irina Yarulina, Swapna Ganapathy, Bert M. Weckhuysen, Freek Kapteijn, Evgeny A. Pidko. An integrated approach to the key parameters in methanol-to-olefins reaction catalyzed by MFI/MEL zeolite materials [J]. Chinese Journal of Catalysis, 2022, 43(7): 1879-1893.
[5]	Mengru Wang, Yi Wang, Xiaoling Mou, Ronghe Lin, Yunjie Ding. Design strategies and structure-performance relationships of heterogeneous catalysts for selective hydrogenation of 1,3-butadiene [J]. Chinese Journal of Catalysis, 2022, 43(4): 1017-1041.
[6]	Jie Wei, Wei Chen, Da Zhou, Jun Cai, Yan-Xia Chen. Restructuring of well-defined Pt-based electrode surfaces under mild electrochemical conditions [J]. Chinese Journal of Catalysis, 2022, 43(11): 2792-2801.
[7]	Xiaoxue Zhao, Mengyang Xu, Xianghai Song, Weiqiang Zhou, Xin Liu, Pengwei Huo. 3D Fe-MOF embedded into 2D thin layer carbon nitride to construct 3D/2D S-scheme heterojunction for enhanced photoreduction of CO₂ [J]. Chinese Journal of Catalysis, 2022, 43(10): 2625-2636.
[8]	Li Zhu, Yiyang Lin, Kang Liu, Emiliano Cortés, Hongmei Li, Junhua Hu, Akira Yamaguchi, Xiaoliang Liu, Masahiro Miyauchi, Junwei Fu, Min Liu. Tuning the intermediate reaction barriers by a CuPd catalyst to improve the selectivity of CO₂ electroreduction to C2 products [J]. Chinese Journal of Catalysis, 2021, 42(9): 1500-1508.
[9]	Li Yang, Lijun Shi, Chungu Xia, Fuwei Li. Intermediate formation enabled regioselective access to amide in the Pd-catalyzed reductive aminocarbonylation of olefin with nitroarene [J]. Chinese Journal of Catalysis, 2020, 41(7): 1152-1160.
[10]	Xuemei Li, Junying Tian, Hailong Liu, Congkui Tang, Chungu Xia, Jing Chen, Zhiwei Huang. Effective synthesis of 5-amino-1-pentanol by reductive amination of biomass-derived 2-hydroxytetrahydropyran over supported Ni catalysts [J]. Chinese Journal of Catalysis, 2020, 41(4): 631-641.
[11]	HUANG Weixin, FU Qiang. Surface and Interface Chemistry of Model Catalysts [J]. Chinese Journal of Catalysis, 2019, 40(s1): 165-168.
[12]	Xu Tang, Liang Ni, Juan Han, Yun Wang. Preparation and characterization of ternary magnetic g-C₃N₄ composite photocatalysts for removal of tetracycline under visible light [J]. Chinese Journal of Catalysis, 2017, 38(3): 447-457.
[13]	Xiaobing Zhu, Xin Qu, Xiaosong Li, Jinglin Liu, Jianhao Liu, Bin Zhu, Chuan Shi. Selective reduction of carbon dioxide to carbon monoxide over Au/CeO₂ catalyst and identification of reaction intermediate [J]. Chinese Journal of Catalysis, 2016, 37(12): 2053-2058.
[14]	Weixing Liu, Zhe Zhao, Baofeng Tu, Daan Cui, Dingrong Ou, Mojie Cheng. TiO₂-modified La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ cathode for intermediate temperature solid oxide fuel cells [J]. Chinese Journal of Catalysis, 2015, 36(4): 502-508.
[15]	Zheng-Le Zhao, Qing Gu, Xin-Yan Wu, Shu-Li You. Pd(0)-catalyzed benzylation of indole through η³-benzyl palladium intermediate [J]. Chinese Journal of Catalysis, 2015, 36(1): 15-18.