Nanocasting, Template Synthesis, and Structural Studies on Cesium Salt of Phosphotungstic Acid for the Synthesis of Novel 1,3,5-Triaryl-pyrazoline Derivatives

doi:10.1016/S1872-2067(11)60330-6

催化学报 ›› 2012, Vol. 33 ›› Issue (2): 237-246.DOI: 10.1016/S1872-2067(11)60330-6

Nanocasting, Template Synthesis, and Structural Studies on Cesium Salt of Phosphotungstic Acid for the Synthesis of Novel 1,3,5-Triaryl-pyrazoline Derivatives

Razieh FAZAELI1,*, Hamid ALIYAN2, Shahram TANGESTANINEJAD1, Esmaeel MOHAMMADI1, Maryam BORDBAR3

1Department of Chemistry, Shahreza Branch, Islamic Azad University, 86145-311, Iran; 2Department of Chemistry, Mobarakeh Branch, Islamic Azad University, 84815-119, Iran; 3Department of chemistry, Faculty of Science, The University of Qom, 37185-359, Qom, Iran

收稿日期:2011-05-25 修回日期:2011-06-17 出版日期:2012-02-20 发布日期:2015-07-27

Nanocasting, Template Synthesis, and Structural Studies on Cesium Salt of Phosphotungstic Acid for the Synthesis of Novel 1,3,5-Triaryl-pyrazoline Derivatives

Razieh FAZAELI1,*, Hamid ALIYAN2, Shahram TANGESTANINEJAD1, Esmaeel MOHAMMADI1, Maryam BORDBAR3

1Department of Chemistry, Shahreza Branch, Islamic Azad University, 86145-311, Iran; 2Department of Chemistry, Mobarakeh Branch, Islamic Azad University, 84815-119, Iran; 3Department of chemistry, Faculty of Science, The University of Qom, 37185-359, Qom, Iran

Received:2011-05-25 Revised:2011-06-17 Online:2012-02-20 Published:2015-07-27

摘要/Abstract

摘要： The elimination of the silica matrix of composites by HF occurred by a two-step reaction deposition of a Cs_2.5H_0.5PW₁₂O₄₀ (CsHPW) salt nanocrystal. We used 2D hexagonal SBA-15 silica as a template for the nanofabrication of CsHPW nanoparticles. Nanocast CsHPW materials are stable against leaching and colloidization in polar solvents. The catalytic performance of the nanocast CsHPW materials exceeded that of bulk Cs_2.5H_0.5PW₁₂O₄₀, which is the most active among the acidic HPW salts. A series of novel 1,3,5-triaryl-pyrazoline derivatives were synthesized by the reaction between chalcone and phenylhydrazine in high yield in the presence of CsHPW salt nanocrystals.

关键词: nanocasting, nanoparticle, green chemistry, 1,3,5-triaryl-2-pyrazoline, polyoxometalate

Abstract: The elimination of the silica matrix of composites by HF occurred by a two-step reaction deposition of a Cs_2.5H_0.5PW₁₂O₄₀ (CsHPW) salt nanocrystal. We used 2D hexagonal SBA-15 silica as a template for the nanofabrication of CsHPW nanoparticles. Nanocast CsHPW materials are stable against leaching and colloidization in polar solvents. The catalytic performance of the nanocast CsHPW materials exceeded that of bulk Cs_2.5H_0.5PW₁₂O₄₀, which is the most active among the acidic HPW salts. A series of novel 1,3,5-triaryl-pyrazoline derivatives were synthesized by the reaction between chalcone and phenylhydrazine in high yield in the presence of CsHPW salt nanocrystals.

Key words: nanocasting, nanoparticle, green chemistry, 1,3,5-triaryl-2-pyrazoline, polyoxometalate

Razieh FAZAELI, Hamid ALIYAN, Shahram TANGESTANINEJAD, Esmaeel MOHAMMADI, Maryam BORDBAR. Nanocasting, Template Synthesis, and Structural Studies on Cesium Salt of Phosphotungstic Acid for the Synthesis of Novel 1,3,5-Triaryl-pyrazoline Derivatives[J]. 催化学报, 2012, 33(2): 237-246.

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Nanocasting, Template Synthesis, and Structural Studies on Cesium Salt of Phosphotungstic Acid for the Synthesis of Novel 1,3,5-Triaryl-pyrazoline Derivatives

Nanocasting, Template Synthesis, and Structural Studies on Cesium Salt of Phosphotungstic Acid for the Synthesis of Novel 1,3,5-Triaryl-pyrazoline Derivatives

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