Silica-functionalized N-propylpiperazine for immobilization of palladium nanoparticles as efficient heterogeneous catalyst for cyanation reactions

doi:10.1016/S1872-2067(12)60532-4

催化学报 ›› 2013, Vol. 34 ›› Issue (4): 718-722.DOI: 10.1016/S1872-2067(12)60532-4

Silica-functionalized N-propylpiperazine for immobilization of palladium nanoparticles as efficient heterogeneous catalyst for cyanation reactions

Khodabakhsh NIKNAM, Abdollah DERIS, Farhad PANAHI

Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran

出版日期:2013-04-23 发布日期:2013-04-24
通讯作者: Khodabakhsh NIKNAM

Silica-functionalized N-propylpiperazine for immobilization of palladium nanoparticles as efficient heterogeneous catalyst for cyanation reactions

Khodabakhsh NIKNAM, Abdollah DERIS, Farhad PANAHI

Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran

Online:2013-04-23 Published:2013-04-24
Supported by:
This work was supported by Persian Gulf University.

摘要/Abstract

摘要：

An efficient heterogeneous Pd catalytic system has been developed, based on immobilization of Pd nanoparticles (PNPs) on a silica-bonded N-propylpiperazine (SBNPP) substrate. The SBNPP substrate effectively stabilizes the PNPs and improves their stability against aggregation. The catalytic activity of this catalyst was investigated in the cyanation of aryl halides with K₄[Fe(CN)₆] as the cyanide source. The catalyst could be recycled several times without appreciable loss of catalytic activity.

Abstract:

Key words: Palladium nanoparticle, Silica-bonded N-propylpiperazine, Cyanation reaction, Aryl halide

Khodabakhsh NIKNAM, Abdollah DERIS, Farhad PANAHI. Silica-functionalized N-propylpiperazine for immobilization of palladium nanoparticles as efficient heterogeneous catalyst for cyanation reactions[J]. 催化学报, 2013, 34(4): 718-722.

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Silica-functionalized N-propylpiperazine for immobilization of palladium nanoparticles as efficient heterogeneous catalyst for cyanation reactions

Silica-functionalized N-propylpiperazine for immobilization of palladium nanoparticles as efficient heterogeneous catalyst for cyanation reactions

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