Rapid nonenzymatic monitoring of glucose and fructose using a CuO/multiwalled carbon nanotube nanocomposite-modified glassy carbon electrode

doi:10.1016/S1872-2067(12)60586-5

催化学报 ›› 2013, Vol. 34 ›› Issue (6): 1208-1215.DOI: 10.1016/S1872-2067(12)60586-5

Rapid nonenzymatic monitoring of glucose and fructose using a CuO/multiwalled carbon nanotube nanocomposite-modified glassy carbon electrode

Hajar SHEKARCHIZADEH^a, Mahdi KADIVAR^a, Ali A. ENSAFI^b

a Department of Food Science and Technology, College of Agriculture, Isfahan University of Technology, Isfahan 84156-83111, Iran;
b Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Iran

收稿日期:2012-12-30 修回日期:2013-03-15 出版日期:2013-06-07 发布日期:2013-06-09
通讯作者: Ali A. ENSAFI
基金资助:
The Iranian Nanotechnology Initiative, Research Council of Isfahan University of Technology, and Centre of Excellence in Sensor and Green Chemistry are thanked for supporting this work.

Rapid nonenzymatic monitoring of glucose and fructose using a CuO/multiwalled carbon nanotube nanocomposite-modified glassy carbon electrode

Hajar SHEKARCHIZADEH^a, Mahdi KADIVAR^a, Ali A. ENSAFI^b

a Department of Food Science and Technology, College of Agriculture, Isfahan University of Technology, Isfahan 84156-83111, Iran;
b Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Iran

Received:2012-12-30 Revised:2013-03-15 Online:2013-06-07 Published:2013-06-09
Supported by:
The Iranian Nanotechnology Initiative, Research Council of Isfahan University of Technology, and Centre of Excellence in Sensor and Green Chemistry are thanked for supporting this work.

摘要/Abstract

摘要：

A nonenzymatic electrochemical sensor for glucose and fructose was fabricated that contained a glassy carbon electrode modified with a copper oxide (CuO)/multiwalled carbon nanotube (MWCNT) nanocomposite. The electrochemical properties of the CuO/MWCNT-modified glassy carbon electrode were investigated. Two distinguishable anodic peaks were observed around 0.30 and 0.44 V corresponding to the oxidation of glucose and fructose, respectively, at the surface of the modified electrode. The detection limits for glucose and fructose were both 0.04 mmol/L. The sensor was used to simultaneously determine the concentrations of glucose and fructose in hydrolyzed sucrose samples, and to measure glucose in blood serum samples, demonstrating its potential as a nonenzymatic carbohydrate sensor.

关键词: Nonenzymatic detection, Copper oxide, Multiwalled carbon nanotube, Modified glassy carbon electrode, Glucose, Fructose, Simultaneous determination

Abstract:

Key words: Nonenzymatic detection, Copper oxide, Multiwalled carbon nanotube, Modified glassy carbon electrode, Glucose, Fructose, Simultaneous determination

Hajar SHEKARCHIZADEH, Mahdi KADIVAR, Ali A. ENSAFI. Rapid nonenzymatic monitoring of glucose and fructose using a CuO/multiwalled carbon nanotube nanocomposite-modified glassy carbon electrode[J]. 催化学报, 2013, 34(6): 1208-1215.

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Rapid nonenzymatic monitoring of glucose and fructose using a CuO/multiwalled carbon nanotube nanocomposite-modified glassy carbon electrode

Rapid nonenzymatic monitoring of glucose and fructose using a CuO/multiwalled carbon nanotube nanocomposite-modified glassy carbon electrode

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