Effects of Bi and Ni on the properties of a vanadium phosphorus oxide catalyst

doi:10.1016/S1872-2067(12)60749-9

催化学报 ›› 2014, Vol. 35 ›› Issue (2): 270-276.DOI: 10.1016/S1872-2067(12)60749-9

• 研究论文 • 上一篇

Effects of Bi and Ni on the properties of a vanadium phosphorus oxide catalyst

Yun Hin Taufiq-Yap^a,b, Choon Seon Yuen^a,b, Nawi @ Mohamed Nurul Suziana^a,b, Ramli Irmawati^a,b

a Catalysis Science and Technology Research Centre, Faculty of Science, University Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;
b Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia

收稿日期:2013-08-05 修回日期:2013-11-14 出版日期:2014-01-16 发布日期:2014-01-17
通讯作者: Yun Hin Taufiq-Yap
基金资助:
This work was supported by the Ministry of Science, Technology and Innovation of Malaysia.

Effects of Bi and Ni on the properties of a vanadium phosphorus oxide catalyst

Yun Hin Taufiq-Yap^a,b, Choon Seon Yuen^a,b, Nawi @ Mohamed Nurul Suziana^a,b, Ramli Irmawati^a,b

a Catalysis Science and Technology Research Centre, Faculty of Science, University Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;
b Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia

Received:2013-08-05 Revised:2013-11-14 Online:2014-01-16 Published:2014-01-17
Contact: Yun Hin Taufiq-Yap
Supported by:
This work was supported by the Ministry of Science, Technology and Innovation of Malaysia.

摘要/Abstract

摘要：

Vanadium phosphorus oxide (VPO) catalysts were synthesized by the dihydrate method which involved the two steps for the preparation of the dihydrate (VOPO₄×2H₂O) and the precursor hemihydrate (VOHPO₄×0.5H₂O). Bi and Ni salt were added into the mixture of VOPO₄×2H₂O and isobutanol, and the obtained precursors were calcined in a flow of a n-butane/air mixture to produce the promoted VPO catalysts. The catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, inductively coupled plasma-atomic emission spectroscopy, scanning electron microscopy (SEM), and H₂ temperature-programmed reduction (H₂-TPR). Their catalytic properties were tested using a fixed-bed microreactor. All the catalysts gave main XRD peaks at 2θ = 22.9°, 28.5°, and 30.0°, attributing to the (020), (204), and (221) planes of the pyrophosphate phase (VO)₂P₂O₇, respectively. The promoted catalysts have smaller crystallite size and higher specific surface areas. SEM micrographs revealed the formation of more prominent plate-like crystallites that were arranged as rosette clusters. H₂-TPR results showed that the promoted catalysts had lower reduction peak temperatures and possessed higher amounts of V⁵⁺-O^2- and V⁴⁺-O^- pairs, which gave higher selectivity and activity in the selective oxidation of n-butane to maleic anhydride.

关键词: Vanadium phosphorus oxide catalyst, Promoter, n-Butane oxidation, Maleic anhydride selectivity

Abstract:

Key words: Vanadium phosphorus oxide catalyst, Promoter, n-Butane oxidation, Maleic anhydride selectivity

Yun Hin Taufiq-Yap, Choon Seon Yuen, Nawi @ Mohamed Nurul Suziana, Ramli Irmawati. Effects of Bi and Ni on the properties of a vanadium phosphorus oxide catalyst[J]. 催化学报, 2014, 35(2): 270-276.

Yun Hin Taufiq-Yap, Choon Seon Yuen, Nawi @ Mohamed Nurul Suziana, Ramli Irmawati. Effects of Bi and Ni on the properties of a vanadium phosphorus oxide catalyst[J]. Chinese Journal of Catalysis, 2014, 35(2): 270-276.

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参考文献

[1] Centi G, Gleaves J T, Golinelli G, Trifiro F. Stud Surf Sci Catal, 1992, 72: 231
[2] Trivedi B C, Culbertson B M. Maleic Anhydride. New York: Plenum Press, 1982. 871
[3] Hutchings G J. Catal Today, 1993, 16: 139
[4] Bartley J K, Lopez-Sanchez J A, Hutchings G J. Catal Today, 2003, 81: 197
[5] Hutchings G J. Appl Catal, 1991, 72: 1
[6] Hutchings G J, Higgins R. J Catal, 1996, 162: 153
[7] Centi G, Cavani F, Trifiro F. Selective Oxidation by Heterogeneous Catalysis. New York: Kluwer Academic Plenum Publisher, 2001. 158
[8] Edwards R C. US Patent 4 515 904 A. 1985
[9] Bortinger A. US Patent 5 885 919 A. 1999
[10] Sookraj S H, Engelbrecht D. Catal Today, 1999, 49: 161
[11] Taufiq-Yap Y H, Tan K P, Waugh K C, Hussein M Z, Ramli I, Abdul Rahman M B. Catal Lett, 2003, 89: 87
[12] Taufiq-Yap Y H, Kamiya Y, Tan K P. J Nat Gas Chem, 2006, 15: 297
[13] Taufiq-Yap Y H, Abdul Ghani A A. Chin J Catal (催化学报), 2007, 28: 1037
[14] Taufiq-Yap Y H, Nurul Suziana N M, Hussein M Z. Catal Lett, 2011, 141: 136
[15] Haber J, Zazhigalov V A, Stoch J, Bogutskaya L V, Batcherikova I V. Catal Today, 1997, 33: 39
[16] Klug H P, Alexander L E. X-Ray Diffraction Procedures for Polycrystalline and Amorphous. New York: John Wiley & Sons, 1974. 618
[17] Kesteman E, Merzouki M, Taouk B, Bordes E, Contractor R. Stud Surf Sci Catal, 1995, 91: 707
[18] Igarashi H, Tsuji K, Okuhara T, Misono M. J Phys Chem, 1993, 97: 7065
[19] de Farias A M D, Gonzalez W d A, de Oliveira P G P, Eon J G, Herrmann J M, Aouine M, Loridant S, Volta J C. J Catal, 2002, 208: 238
[20] Ye D, Satsuma A, Hattori A, Hattori T, Murakami T. Catal Today, 1993, 16: 113
[21] Hutchings G J. J Matter Chem, 2004, 14: 3385
[22] Centi G. Catal Today, 1993, 16: 5
[23] Centi G, Manenti I, Riva A, Trifiro F. Appl Catal, 1984, 9: 177
[24] Poli G, Resta I, Ruggeri O, Trifiro F. Appl Catal, 1981, 1: 395
[25] Centi G, Trifiro F, Ebner J R, Franchetti V M. Chem Rev, 1988, 88: 55
[26] Kiely C J, Sajip S, Ellison I J, Sananes M T, Hutchings, G J, Volta J C. Catal Lett, 1995, 33: 357
[27] Taufiq-Yap Y H, Goh C K, Hutchings G J, Dummer N, Bartley J K. Catal Lett, 2009, 130: 327
[28] Abon M, Herrmann J M, Volta J C. Catal Today, 2001, 71: 121
[29] Taufiq-Yap Y H, Goh C K, Hutchings G J, Dummer N, Bartley J K. J Mol Catal A, 2006, 260: 24
[30] Takita Y, Tanaka K, Ichimaru S, Mizihara Y, Abe Y, Ishihara T. Appl Catal A, 1993, 103: 281
[31] Mars P, van Krevelen D W. Chem Eng Sci, 1954, 3: 41
[32] Witko M, Tokarz R, Haber J, Hermann K. J Mol Catal A, 2001, 166: 59
[33] Volta J C. Top Catal, 2001, 15: 121
[34] Lin M M. Appl Catal A, 2003, 250: 287
[35] Joly J P, Mehier C, Bere K E, Abon M. Appl Catal A, 1998, 169: 55
[36] Wang D X, Kung H H, Barteau M A. Appl Catal A, 2000, 201: 203

Effects of Bi and Ni on the properties of a vanadium phosphorus oxide catalyst

Effects of Bi and Ni on the properties of a vanadium phosphorus oxide catalyst

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