Sorbitol hydrogenolysis to glycols by supported ruthenium catalysts

doi:10.1016/S1872-2067(14)60086-3

催化学报 ›› 2014, Vol. 35 ›› Issue (5): 614-621.DOI: 10.1016/S1872-2067(14)60086-3

Sorbitol hydrogenolysis to glycols by supported ruthenium catalysts

Inmaculada Murillo Leo, Manuel Lopez Granados, Jose Luis Garcia Fierro, Rafael Mariscal

Group of Sustainable Energy and Chemistry, Institute of Catalysis and Petrochemistry (CSIC), C/Marie Curie 2, Cantoblanco, 28049 Madrid, Spain

收稿日期:2014-03-17 修回日期:2014-03-20 出版日期:2014-04-18 发布日期:2014-04-24
通讯作者: Rafael Mariscal

Sorbitol hydrogenolysis to glycols by supported ruthenium catalysts

Inmaculada Murillo Leo, Manuel Lopez Granados, Jose Luis Garcia Fierro, Rafael Mariscal

Group of Sustainable Energy and Chemistry, Institute of Catalysis and Petrochemistry (CSIC), C/Marie Curie 2, Cantoblanco, 28049 Madrid, Spain

Received:2014-03-17 Revised:2014-03-20 Online:2014-04-18 Published:2014-04-24
Contact: Rafael Mariscal

摘要/Abstract

摘要：

Supported Ru catalysts were prepared by wet impregnation to evaluate the role of different oxide supports (Al₂O₃, SiO₂, TiO₂, ZrO₂) in sorbitol hydrogenolysis to glycols. X-ray diffraction, transmission electron microscopy, hydrogen chemisorption, X-ray photoelectron spectroscopy, and NH₃temperature-programmed desorption were used to characterize the catalysts, which were active in the hydrogenolysis of sorbitol. The support affected both the physicochemical properties and catalytic behavior of the supported Ru particles. The characterization results revealed that the Ru/Al₂O₃ catalyst has a high surface acidity, partially oxidized Ru species on the surface, and a higher surface Ru/Al atomic ratio, which gave it the highest selectivity and yield to glycols.

关键词: Sorbitol, Glycols, Hydrogenolysis, Ruthenium, Oxide supports

Abstract:

Key words: Sorbitol, Glycols, Hydrogenolysis, Ruthenium, Oxide supports

Inmaculada Murillo Leo, Manuel Lopez Granados, Jose Luis Garcia Fierro, Rafael Mariscal. Sorbitol hydrogenolysis to glycols by supported ruthenium catalysts[J]. 催化学报, 2014, 35(5): 614-621.

Inmaculada Murillo Leo, Manuel Lopez Granados, Jose Luis Garcia Fierro, Rafael Mariscal. Sorbitol hydrogenolysis to glycols by supported ruthenium catalysts[J]. Chinese Journal of Catalysis, 2014, 35(5): 614-621.

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Sorbitol hydrogenolysis to glycols by supported ruthenium catalysts

Sorbitol hydrogenolysis to glycols by supported ruthenium catalysts

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