催化学报

催化学报 ›› 2014, Vol. 35 ›› Issue (8): 1299-1304.DOI: 10.1016/S1872-2067(14)60173-X

• 论文 • 上一篇    下一篇

(La0.8A0.2)MnO3 (A = Sr, K) perovskite catalysts for NO and C10H22 oxidation and selective reduction of NO by C10H22

Anne Giroir-Fendler, Sonia Gil, Alexandre Baylet   

  1. Lyon University, Lyon, F-69003, Lyon 1 University, CNRS UMR 5256 IRCELYON, Albert Einstein Avenue, 2 Villeurbanne, F-69622, France
  • 收稿日期:2014-05-15 修回日期:2014-06-20 出版日期:2014-08-01 发布日期:2014-08-05
  • 通讯作者: Anne Giroir-Fendler

(La0.8A0.2)MnO3 (A = Sr, K) perovskite catalysts for NO and C10H22 oxidation and selective reduction of NO by C10H22

Anne Giroir-Fendler, Sonia Gil, Alexandre Baylet   

  1. Lyon University, Lyon, F-69003, Lyon 1 University, CNRS UMR 5256 IRCELYON, Albert Einstein Avenue, 2 Villeurbanne, F-69622, France
  • Received:2014-05-15 Revised:2014-06-20 Online:2014-08-01 Published:2014-08-05

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摘要：

In this work, we studied the catalytic activity of LaMnO3 and (La0.8A0.2)MnO3 (A = Sr, K) perovskite catalysts for oxidation of NO and C10H22 and selective reduction of NO by C10H22. The catalytic performances of these perovskites were compared with that of a 2 wt% Pt/SiO2 catalyst. The La site substitution increased the catalytic properties for NO or C10H22 oxidation compared with the non-substituted LaMnO3 sample. For the most efficient perovskite catalyst, (La0.8Sr0.2)MnO3, the results showed the presence of two temperature domains for NO adsorption: (1) a domain corresponding to weakly adsorbed NO, desorbing at temperatures lower than 270 ℃ and (2) a second domain corresponding to NO adsorbed on the surface as nitrate species, desorbing at temperatures higher than 330 ℃. For the Sr-substituted perovskite, the maximum NO2 yield of 80% was observed in the intermediate temperature domain (around 285 ℃). In the reactant mixture of NO/C10H22/O2/H2O/He, (La0.8Sr0.2)MnO3 perovskite showed better performance than the 2 wt% Pt/SiO2 catalyst： NO2 yields reaching 50% and 36% at 290 and 370 ℃, respectively. This activity improvement was found to be because of atomic scale interactions between the A and B active sites, Sr2+ cation and Mn4+/Mn3+ redox couple. Thus, (La0.8Sr0.2)MnO3 perovskite could be an alternative free noble metal catalyst for exhaust gas after treatment.

关键词: LaMnO3 substituted perovskite, Nitrogen oxide oxidation, Decane oxidation, Hydrocarbons-selective catalytic reduction

Abstract:

In this work, we studied the catalytic activity of LaMnO3 and (La0.8A0.2)MnO3 (A = Sr, K) perovskite catalysts for oxidation of NO and C10H22 and selective reduction of NO by C10H22. The catalytic performances of these perovskites were compared with that of a 2 wt% Pt/SiO2 catalyst. The La site substitution increased the catalytic properties for NO or C10H22 oxidation compared with the non-substituted LaMnO3 sample. For the most efficient perovskite catalyst, (La0.8Sr0.2)MnO3, the results showed the presence of two temperature domains for NO adsorption: (1) a domain corresponding to weakly adsorbed NO, desorbing at temperatures lower than 270 ℃ and (2) a second domain corresponding to NO adsorbed on the surface as nitrate species, desorbing at temperatures higher than 330 ℃. For the Sr-substituted perovskite, the maximum NO2 yield of 80% was observed in the intermediate temperature domain (around 285 ℃). In the reactant mixture of NO/C10H22/O2/H2O/He, (La0.8Sr0.2)MnO3 perovskite showed better performance than the 2 wt% Pt/SiO2 catalyst: NO2 yields reaching 50% and 36% at 290 and 370 ℃, respectively. This activity improvement was found to be because of atomic scale interactions between the A and B active sites, Sr2+ cation and Mn4+/Mn3+ redox couple. Thus, (La0.8Sr0.2)MnO3 perovskite could be an alternative free noble metal catalyst for exhaust gas after treatment.

Key words: LaMnO3 substituted perovskite, Nitrogen oxide oxidation, Decane oxidation, Hydrocarbons-selective catalytic reduction