催化学报 ›› 2015, Vol. 36 ›› Issue (3): 268-273.DOI: 10.1016/S1872-2067(14)60251-5

• 论文 • 上一篇    下一篇

Dimerization of norbornene on zeolite catalysts

N. G. Grigor'eva, S. V. Bubennov, L. M. Khalilov, B. I. Kutepov   

  1. Federal State Budget Institution of Science, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation
  • 收稿日期:2014-09-05 修回日期:2014-11-12 出版日期:2015-02-14 发布日期:2015-02-14
  • 通讯作者: N. G. Grigor'eva

Dimerization of norbornene on zeolite catalysts

N. G. Grigor'eva, S. V. Bubennov, L. M. Khalilov, B. I. Kutepov   

  1. Federal State Budget Institution of Science, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation
  • Received:2014-09-05 Revised:2014-11-12 Online:2015-02-14 Published:2015-02-14

摘要:

The high activity and selectivity of H-Beta and H-ZSM-12 zeolites in the dimerization of norbornene was established. The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium, with a selectivity of dimer formation of 88%-98%. Four stereo-isomers of the bis-2,2'-norbornylidene structure were identified in the dimer fraction, with the (Z)-anti-bis-2,2'- norbornylidene prevailing over the others

关键词: Zeolites, Norbornene, Dimerization, Bisnorbornylidenes

Abstract:

The high activity and selectivity of H-Beta and H-ZSM-12 zeolites in the dimerization of norbornene was established. The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium, with a selectivity of dimer formation of 88%-98%. Four stereo-isomers of the bis-2,2'-norbornylidene structure were identified in the dimer fraction, with the (Z)-anti-bis-2,2'- norbornylidene prevailing over the others

Key words: Zeolites, Norbornene, Dimerization, Bisnorbornylidenes