双子型Brönsted酸性离子液体催化高级脂肪酸与醇反应合成生物柴油

doi:10.1016/S1872-2067(15)60852-X

催化学报 ›› 2015, Vol. 36 ›› Issue (7): 982-986.DOI: 10.1016/S1872-2067(15)60852-X

双子型Brönsted酸性离子液体催化高级脂肪酸与醇反应合成生物柴油

常涛^a, 何乐芹^a,b, 张晓婧^a, 袁明霞^a, 秦身钧^a, 赵继全^b

a 河北工程大学理学院, 河北省资源勘测研究重点实验室, 河北邯郸056038;
b 河北工业大学化工学院, 天津300310

收稿日期:2015-01-29 修回日期:2015-03-27 出版日期:2015-06-12 发布日期:2015-07-30
通讯作者: 秦身钧, 电话/传真: (0310) 8577750; 电子信箱: qinsj528@hebeu.edu.cn;赵继全, 电话/传真: (022) 60202926; 电子信箱: zhaojq@hebut.edu.cn
基金资助:
河北省自然科学基金(B2012402001, D2014402046); 河北省高校百名优秀创新人才支持计划(BR2-204); 河北省高校科学技术基金(Q2012030).

Brönsted acid surfactant-combined dicationic ionic liquids as green catalysts for biodiesel synthesis from free fatty acids and alcohols

Tao Chang^a, Leqin He^a,b, Xiaojing Zhang^a, Mingxia Yuan^a, Shenjun Qin^a, Jiquan Zhao^b

a Key Laboratory for Resource Exploration Research of Hebei Province, Hebei University of Engineering, Handan 056038, Hebei, China;
b School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China

Received:2015-01-29 Revised:2015-03-27 Online:2015-06-12 Published:2015-07-30
Supported by:
This work was supported by the Science Foundation of Hebei Province (B2012402001, D2014402046), Program for One Hundred Innovative Talents in Universities of Hebei Province (BR2-204), and the Science and Technology Foundation of Universities of Hebei Province (Q2012030).

摘要/Abstract

摘要：

合成了一系列双子型酸性离子液体, 该类型离子液体以乙二铵为连接链, 由碳链长度可调的双子型阳离子与不同的阴离子组成. 因此, 具有相分离催化剂的性质, 并应用于高级脂肪酸与醇的酯化反应, 以合成生物柴油. 详细考察了各参数的影响. 结果表明, [C₁₂Sb][p-CH₃C₆H₄SO₃]表现出高催化活性及可重复使用性能.

关键词: 生物柴油, 酯化反应, Brönsted酸性, 双子型离子液体, 相分离催化剂

Abstract:

Quaternary ammonium Brönsted acid surfactant-combined dicationic ionic liquids (BASDILs) based on zwitterionic 1,2-bis[N-methyl-N-(3-sulfopropyl)-alkylammonium]ethane betaines and various anions were prepared and characterized. BASDILs possess properties similar to those of phase-separated catalysts and were applied to the catalytic synthesis of biodiesel from free fatty acids and alcohols. Several factors were investigated and the results indicated that [C₁₂Sb][p-CH₃C₆H₄SO₃] was the optimal catalyst, with good catalytic performance and reusability under mild conditions.

Key words: Biodiesel, Esterification, Brönsted acidity, Surfactant-combined dicationic ionic, liquid, Phase separated catalyst

常涛, 何乐芹, 张晓婧, 袁明霞, 秦身钧, 赵继全. 双子型Brönsted酸性离子液体催化高级脂肪酸与醇反应合成生物柴油[J]. 催化学报, 2015, 36(7): 982-986.

Tao Chang, Leqin He, Xiaojing Zhang, Mingxia Yuan, Shenjun Qin, Jiquan Zhao . Brönsted acid surfactant-combined dicationic ionic liquids as green catalysts for biodiesel synthesis from free fatty acids and alcohols[J]. Chinese Journal of Catalysis, 2015, 36(7): 982-986.

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双子型Brönsted酸性离子液体催化高级脂肪酸与醇反应合成生物柴油

Brönsted acid surfactant-combined dicationic ionic liquids as green catalysts for biodiesel synthesis from free fatty acids and alcohols

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