聚合物稳定的金纳米簇催化:理论计算与实验的相互影响

doi:10.1016/S1872-2067(16)62463-4

催化学报 ›› 2016, Vol. 37 ›› Issue (10): 1588-1593.DOI: 10.1016/S1872-2067(16)62463-4

聚合物稳定的金纳米簇催化:理论计算与实验的相互影响

Hiroaki Koga^a, Kohei Sakata^b, Yoshinori Ato^b, Akihide Hayashi^b, Kohei Tada^b, Mitsutaka Okumur^a,b

a 京都大学催化剂与电池元素战略研究基地, 京都, 日本;
b 大阪大学科学研究院化学系, 大阪, 日本

收稿日期:2016-04-24 修回日期:2016-05-20 出版日期:2016-10-21 发布日期:2016-10-22
通讯作者: Mitsutaka Okumur

Advances in polymer-stabilized Au nano-cluster catalysis: Interplay of theoretical calculations and experiments

Hiroaki Koga^a, Kohei Sakata^b, Yoshinori Ato^b, Akihide Hayashi^b, Kohei Tada^b, Mitsutaka Okumur^a,b

a Elements Strategy Initiative for Catalysts and Batteries(ESICB) Kyoto University, 1-30 Goryoohara, Kyoto 615-8245, Japan;
b Department of Chemistry, Graduate School of Science Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan

Received:2016-04-24 Revised:2016-05-20 Online:2016-10-21 Published:2016-10-22
Contact: Mitsutaka Okumur

摘要/Abstract

摘要：

平均粒径为2-10 nm的聚合物稳定的Au纳米簇（NCs）表现出独特的催化性能.多个研究表明，影响聚合物稳定的Au NCs催化活性的主要因素为：Au NC尺寸的控制、聚合物的选择以及反应条件的优化.这是由于聚合物稳定的Au NCs在多个催化反应中表现出明显的尺寸效应，其催化活性也因所采用的聚合物和反应条件的不同而不同.为了阐明影响聚合物稳定的Au NCs催化活性的内在原因，众多研究者关注于聚合物稳定的Au NCs催化中的理论计算与实验的相互影响.本文主要总结了聚合物稳定的Au NCs中这种相互影响的研究进展.

关键词: 聚合物稳定的金纳米簇, 醇的有氧氧化, 理论计算和实验的相互影响, 金纳米簇的尺寸效应, 聚合物的作用

Abstract:

Polymer-stabilized Au nano clusters (NCs) with mean diameters of 2-10 nm exhibit unique catalytic properties. Several studies have shown that the key factors affecting the catalytic activity of polymer-stabilized Au NCs are control of the Au NC size, appropriate selection of polymers and optimization of the reaction conditions. This is because polymer-stabilized Au NCs exhibit a clear size effect in several catalytic reactions, and the catalytic activity differs with the type of polymer used and the reaction conditions. In order to elucidate the reason underlying the catalytic activity of the polymer-stabilized Au NCs, much attention is being devoted to the interplay of theoretical calculations and experiments in catalysis by polymer stabilized Au NCs. The present article mainly summarizes our progress in understanding this interplay in polymer-stabilized Au NC catalysis.

Key words: Polymer-stabilized Au nano-cluster, Aerobic oxidation of alcohols, Interplay of theoretical calculations and experiments, Size effect of Au nano-cluster, Role of the polymers

Hiroaki Koga, Kohei Sakata, Yoshinori Ato, Akihide Hayashi, Kohei Tada, Mitsutaka Okumur. 聚合物稳定的金纳米簇催化:理论计算与实验的相互影响[J]. 催化学报, 2016, 37(10): 1588-1593.

Hiroaki Koga, Kohei Sakata, Yoshinori Ato, Akihide Hayashi, Kohei Tada, Mitsutaka Okumur. Advances in polymer-stabilized Au nano-cluster catalysis: Interplay of theoretical calculations and experiments[J]. Chinese Journal of Catalysis, 2016, 37(10): 1588-1593.

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https://www.cjcatal.com/CN/Y2016/V37/I10/1588

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聚合物稳定的金纳米簇催化:理论计算与实验的相互影响

Advances in polymer-stabilized Au nano-cluster catalysis: Interplay of theoretical calculations and experiments

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