物相到性能: 碳化钼在逆水煤气变换反应中的先进作用

doi:10.1016/S1872-2067(26)65036-X

摘要/Abstract

摘要： 碳化钼(MoC_x)具有独特的类贵金属反应活性、较好的热稳定性及可放大性, 使其性能超越传统过渡金属, 成为逆水煤气变换(RWGS)反应的高效催化剂. 2024‒2025年的最新研究进展显示, 以前未被充分探索的α-MoC相表现出巨大的应用潜力, 具有高活性和高CO选择性, 且碳化物动态参与到二氧化碳活化过程中. 原位机理研究和物相-活性的构性关系等些研究进展表明, MoC_x可用作RWGS和下游二氧化碳稳定化利用的转换平台. 然而, 目前还存在一些关键问题有待解决, 如表面碳空位的确切作用、MoC_x在动态RWGS条件下的长期稳定性、合成方法的可放大性, 以及在工业应用中的耐久性等. 本文集中综述了最近进展, 同时概述了将MoC_x催化剂用于循环碳技术和工业二氧化碳利用所面临的当前挑战和未来研究机会.

关键词: 碳化钼, 逆水汽变化反应, CO₂利用, 催化, CO₂加氢

Abstract: Molybdenum carbides (MoC_x) are rapidly emerging as efficient catalysts for the reverse water-gas shift (RWGS) reaction, outperforming conventional transition metals with their unique blend of noble-metal-like reactivity, exceptional thermal stability, and scalability. Recent advances in 2024‒2025 have unlocked the excellent potential of the previously underexplored α-MoC phase, revealing unprecedented activity, robust CO selectivity, and dynamic carbidic carbon participation in CO₂ activation. These advances, alongside in situ mechanistic insights and phase-activity correlations, make a compelling case for MoC_x as a transformative platform for RWGS and downstream CO₂ valorization. Despite these advances, critical questions remain regarding the precise role of surface carbon vacancies, the long-term stability of MoC_x under dynamic RWGS conditions, the scalability of synthesis methods, and the durability for industrial deployment. This perspective provides the first focused synthesis of recent developments, while outlining current challenges and future research opportunities needed to position MoC_x catalysts at the forefront of circular carbon technologies and industrial CO₂ utilization.

Key words: Molybdenum carbide, Reverse water-gas shift, CO₂ utilization, Catalysis, CO₂ hydrogenation

Fleur A. E. Bruekers, Tess I. van Benthem, Rajamohanan Sobhana Anju, N. Raveendran Shiju. 物相到性能: 碳化钼在逆水煤气变换反应中的先进作用[J]. 催化学报, DOI: 10.1016/S1872-2067(26)65036-X.

Fleur A. E. Bruekers, Tess I. van Benthem, Rajamohanan Sobhana Anju, N. Raveendran Shiju. Phase to performance: The advancing role of molybdenum carbides in reverse water-gas shift reaction[J]. Chinese Journal of Catalysis, DOI: 10.1016/S1872-2067(26)65036-X.

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