同晶取代Co3O4纳米复合材料流水线式协同催化分解N2O

doi:10.1016/S1872-2067(26)65175-3

催化学报 ›› 2026, Vol. 89: 430-443.DOI: 10.1016/S1872-2067(26)65175-3

同晶取代Co₃O₄纳米复合材料流水线式协同催化分解N₂O

刘玲技^a^,¹, 蔚晓盛^a^,¹, 陈洲^a, 海雪清^a, 王永钊^a, 王长真^a^,^b^,^*(), 肖天存^c^,^*()

^a山西大学精细化学品教育部工程研究中心,山西太原 030006,中国
^b山西大学化学化工学院,山西太原 030006,中国
^c牛津大学无机化学实验室,牛津,英国

收稿日期:2026-01-07 接受日期:2026-04-02 出版日期:2026-10-18 发布日期:2026-09-01
通讯作者: *电子信箱: czwang@sxu.edu.cn (王长真),
xiao.tiancun@chem.ox.ac.uk (肖天存).
作者简介:
¹共同第一作者.
基金资助:
国家自然科学基金(22578255);国家自然科学基金(22178202);中央引导地方科技发展资金项目(YDZJSX2024D004);山西省重点研发计划(202402090301006)

Assembly-line synergistic catalysis in isomorphic substituted Co₃O₄ nanocomposite for enhanced N₂O decomposition

Lingji Liu^a^,¹, Xiaosheng Yu^a^,¹, Zhou Chen^a, Xueqing Hai^a, Yongzhao Wang^a, Changzhen Wang^a^,^b^,^*(), Tiancun Xiao^c^,^*()

^aEngineering Research Center of Ministry of Education for Fine Chemicals, Shanxi University, Taiyuan 030006, Shanxi, China
^bSchool of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, Shanxi, China
^cInorganic Chemistry Laboratory, University of Oxford, Oxford, OX1 3QR, UK

Received:2026-01-07 Accepted:2026-04-02 Online:2026-10-18 Published:2026-09-01
Contact: *E-mail:czwang@sxu.edu.cn(C. Wang),xiao.tiancun@chem.ox.ac.uk(T. Xiao).
About author:
¹Contributed equally to this work.
Supported by:
National Natural Science Foundation of China(22578255);National Natural Science Foundation of China(22178202);Central Government Guidance Fund for Local Science and Technology Development(YDZJSX2024D004);Key Research and Development Special Program of Shanxi Province(202402090301006)

摘要/Abstract

摘要：

纳米流水线协同催化是针对多步速率控制反应提出的新型设计思路, 通过在同一纳米复合材料中构建空间有序、功能协同的多活性位点, 可实现对多步反应的时空接力催化. 一氧化二氮(N₂O)作为硝酸与己二酸工业废气的主要成分, 其绿色高效催化分解对减少温室气体排放和缓解臭氧层损耗问题具有重要意义. 然而, N₂O催化分解存在两个关键挑战: (1) 低温下N-O键活化能垒高; (2) N-O断裂生成的吸附氧中间体脱附缓慢, 持续毒化活性位点. 因此, 构建具有时空有序的N-O吸附位点和氧脱附微观结构, 可实现反应步骤时空有序推进的催化体系, 成为突破N₂O催化分解瓶颈的关键, 对实现N₂O高效分解及推动流水线催化在多步骤催化反应中的应用具有重要意义.

本文基于原子级Ca和Zr物种对Co₃O₄的同晶取代策略, 精准构建了一种由Ca-O-Co位点与Co-Oᵥ-Zr位点串联耦合而成的“流水线式”反应模块, 即富含Ca-O-Co-O_v-Zr亚结构“微集成工作站”的新型纳米复合催化剂, 并揭示了其对N-O吸附与氧脱附动力学的协同调控机制. 最优CoCaZr样品N₂O分解T₉₀温度温度可低至355 °C, 且能耐受各种杂质气氛并稳定运行超过100 h. 实验机理与密度泛函理论计算研究表明, 该优异性能主要源于Ca-O-Co-O_v-Zr亚结构的原子尺度双向促进机制: 一方面, Ca通过给电子效应构建“Ca-e^--Co”电子传输链(车间1), 提高Co位点电子云密度, 促进Co²⁺对N₂O分子的吸附与N-O键的断裂(步骤i); 另一方面, Co-O_v-Zr(车间2)作为“氧输送带”, 在N-O键断裂后驱动随后的氧脱附过程(步骤ii), 促进活性氧物种的快速脱附与位点再生. 在空间维度上, Ca-e^--Co与Co-O_v-Zr位点通过微集成工作站亚结构实现空间毗邻与功能接力, 使得N-O键断裂生成的活性氧物种被迅速转移至氧空位区域并高效脱附, 避免活性位点被氧毒化; 在时间维度上, 相比传统的块体催化剂因缺乏足够的协同界面, 无法高效地将多个基元步骤串联起来的结构缺陷, 原子级相邻的多集成协同中心Ca-O-Co-O_v-Zr亚结构, 可以同时全局性地活化N₂O分子一站式催化分解而无需排队等待, 保障流水线式催化循环的高效进行.

综上, 本研究为合理设计流水线式亚结构中的协同活性位点提供了有效思路, 成功解决了N₂O分解反应中的多步骤动力学限制问题, 丰富了纳米级流水线式协同催化的应用场景, 对推进复杂催化反应中多步骤协同机制的研究以及开发高效稳定的多步骤催化材料奠定了理论与实验基础.

关键词: 流水线式协同催化, 同晶取代亚结构, 纳米复合材料, 双向促进机制, N₂O催化分解

Abstract:

Nanoscale assembly-line catalysis is a novel avenue for reactions with multiple rate-determining steps. The regional coexistence of different elements in nanocomposites with adjacent heterometallic coordination can construct substructures compatible with multifunctional sites, resulting in synergistic catalysis. Herein, a novel nanocomposite with affluent Ca-O-Co-O_v-Zr micro-integrated stations (MIS) is developed through an isomorphic substitution strategy to promote the spatiotemporally ordered N-O adsorption and mitigate kinetic limitation of O transportation/desorption through an assembly-line catalytic perspective during N₂O decomposition. The optimized CoCa₆Zr₉ can achieve T₉₀ of N₂O decomposition at 355 °C and stably run for more than 100 h. This superior performance is mainly attributed to a bidirectional promotion mechanism via both “Ca-e^--Co” electronic chain in Ca-O-Co (workshop 1) and O vacancy electronic pump in “Co-O_v-Zr” (workshop 2), which promotes the formation of electron-rich Co²⁺-O_v cooperative sites (namly, the MIS), accelerating cleavage of N-O bond (Primary Step i). Meanwhile, the cooperative of atomic-regulated electronic and redox inducers can adjust the Co-O polarity to maintain the Co²⁺ valence state, weaken the Co-O bond and enhance active oxygen mobility, thus refreshing its active sites for assembly-line catalytic cycles instantly and persistently (Primary Step ii). This work establishes an effective insight for rationally assembling cooperative active sites in assembly-line inspired substructures, which is essential for advancing the research on the coordination of multiple reaction steps in complex catalytic reactions.

Key words: Assembly-line catalysis, Isomorphic substituted substructure, Nanocomposite, Bidirectional promotion, N₂O decomposition

刘玲技, 蔚晓盛, 陈洲, 海雪清, 王永钊, 王长真, 肖天存. 同晶取代Co₃O₄纳米复合材料流水线式协同催化分解N₂O[J]. 催化学报, 2026, 89: 430-443.

Lingji Liu, Xiaosheng Yu, Zhou Chen, Xueqing Hai, Yongzhao Wang, Changzhen Wang, Tiancun Xiao. Assembly-line synergistic catalysis in isomorphic substituted Co₃O₄ nanocomposite for enhanced N₂O decomposition[J]. Chinese Journal of Catalysis, 2026, 89: 430-443.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(26)65175-3

https://www.cjcatal.com/CN/Y2026/V89/I10/430

图/表 5

Fig. 1. Schematic synthetic procedures and structural characterizations of the nanocomposites. (a) Schematic illustration for the preparation of the CoCaZr nanocomposites. HR-TEM (b), HAADF-STEM images and EDX element mappings (c), high-resolution atomic contrast imaging (d) of the CoCa6Zr9 from position I in (b). HR-TEM and corresponding GPA images of CoCa6Zr9 from position II (e) and reference Co3O4 with strain tensor maps (f) in xy direction (εxy). (e1) Schematic representation of the regional balance of tensile and compressive lattice strains. (g) XRD patterns in rietveld refinement of Co3O4 and CoCa6Zr9. The Fourier transform spectra of k2-Co K-edge EXAFS (h), Zr 3d XPS (i) and Ca 2p XPS (j) spectra for Co3O4, CoCa6Zr9 and Co/Ca6Zr9.

Fig. 2. Catalytic performance evaluation. N2O decomposition activity (a) and Arrhenius plots (b) for the decomposition of N2O over Co3O4, CoCa6Zr9 and Co/Ca6Zr9. N2O decomposition activity (c), Arrhenius plots (d) for the decomposition of N2O and reaction rates (e) at 300 and 350 °C over CoCaxZry nanocomposites. Reaction conditions: 1000 ppm N2O balanced with Ar, GHSV = 10000 h-1. (f) The schematic of structural properties of the Ca-O-Co-Ov-Zr substructure. (g) Stability test at 400 °C over CoCa6Zr9, Co3O4, Co/Ca6Zr9 catalysts and 355 °C over CoCa6Zr9 nanocomposite. (h) T90 and stability performance of CoCa6Zr9 and their comparison with the reported Co-based catalysts (refer to Table S4 for details), and (i) Test of impurities resistance over CoCa6Zr9 nanocomposite.

Fig. 3. Promotion factors analysis. The Co K-edge XANES spectra (a), H2-TPR profiles (b), CO2-TPD profiles (c), EPR spectra (d), O 1s XPS spectra (e), and O2-TPD profiles (f) of CoCaxZry nanocomposites. (g) The linear fitting relationship between the reaction rate at 300 °C and Co2+/Co3+ from Co XPS spectra, Oads/(Oads+Olat) from O XPS spectra, the Co2+ maintenance ability (reduction temperature of peak-2 in H2-TPR), the basic ability (desorption temperature of peak-I in CO2-TPD). (h) Possible bidirectional promotion mechanism on the surface of CoCaxZry nanocomposites.

Fig. 4. Theoretical calculation. N2O adsorption configurations of Co-O-Co (311) (a), Ca-O-Co-O-Zr (311) (b), and Ca-O-Co-Ov-Zr (311) (c). (d) The PDOS of the Co atoms on the Co-O-Co, Ca-O-Co-O-Zr, and Ca-O-Co-Ov-Zr; the black dashed line implies the Ef energy. The differential charge density diagram of Co-O-Co (e), Ca-O-Co-O-Zr (f), and Ca-O-Co-Ov-Zr (g), in which the cyan and yellow regions stand for the depletion and accumulation of charges, respectively. (h) Schematic illustration of electron transfer between Ca-O-Co-Ov-Zr and N2O. (i) The PDOS of the N2O molecule is adsorbed on the Co-O-Co, Ca-O-Co-O-Zr, and Ca-O-Co-Ov-Zr. (j) Schematic illustration of the orbital interactions between Co 3d and N2O 3π*. (k) Optimized structures and calculated transition state (TS) of N2O decomposition over the Co-O-Co (311) and Ca-O-Co-Ov-Zr (311) surface.

Fig. 5. N2O decomposition mechanism. O XPS spectra (a) and Co XPS (b) spectra of results of the fresh (dash line)/spent (solid line) CoCa6Zr9, Co3O4, and Co/Ca6Zr9 catalysts. (c) Concentration variation ratio of Oads/(Oads+Olat), and Co2+/(Co2+ + Co3+) before and after the reaction of the CoCa6Zr9, Co3O4, and Co/Ca6Zr9. (d) In situ FT-IR spectra of the CoCa6Zr9 catalyst recorded at 50 °C upon passing 1000 ppm of N2O. In-situ FT-IR spectra obtained during catalytic decomposition of N2O (1000 ppm) over CoCa6Zr9 (e) and Co3O4 (f) at varied temperatures. (g) Reaction stability mechanism in N2O decomposition over CoCa6Zr9 nanocomposite. (h) Schematic illustration of the assembly-line catalysis mechanism vs traditional catalysis.

参考文献

[1]	X. Wu, J. Du, Y. Gao, H. Wang, C. Zhang, R. Zhang, H. He, G. M. Lu, Z. Wu, Chem. Soc. Rev., 2024, 53, 8379-8423.
[2]	G. Zhu, H. Shi, L. Zhong, G. He, B. Wang, J. Shan, P. Han, T. Liu, S. Wang, C. Liu, N. Zhang, L. Jiang, L. Yu, C. Zhan, Z. Tang, T. Wen, B. Ma, X. Su, S. Zhang, J. Zhang, H. Di, L. Hou, A. H. Krichels, M. Trimmer, M. S. M. Jetten, Y. Peng, F. E. Löffler, H. Tian, Y.-G. Zhu, Nat. Rev. Earth Environ., 2025, 6, 574-592.
[3]	M. L. Bols, B. E. R. Snyder, H. M. Rhoda, P. Cnudde, G. Fayad, R. A. Schoonheydt, V. Van Speybroeck, E. I. Solomon, B. F. Sels, Nat. Catal., 2021, 4, 332-340.
[4]	H. Jiang, H. Wang, F. Liang, S. Werth, T. Schiestel, J. Caro, Angew. Chem. Int. Ed., 2009, 48, 2983-2986.
[5]	Y. Jing, C. He, N. Zhang, Y. Murano, R. Toyoshima, H. Kondoh, Y. Kageyama, H. Inomata, T. Toyao, K.-I. Shimizu, ACS Catal., 2023, 13, 12983-12993.
[6]	F. Buttignol, J. W. A. Fischer, A. H. Clark, M. Elsener, A. Garbujo, P. Biasi, I. Czekaj, M. Nachtegaal, G. Jeschke, O. Kröcher, D. Ferri, Nat. Catal., 2024, 7, 1305-1315.
[7]	D. Zhao, S. Lyu, Q. Cheng, Y. Liu, P. Zhao, Q. Zhang, Y. Zhang, Y. Pan, X. Li, S. Xiong, Z. Wang, X. Li, J. Am. Chem. Soc., 2025, 147, 20493-20503.
[8]	L. Nowakowski, C. Hudy, F. Zasada, J. Gryboś, W. Piskorz, A. Wach, Y. Kayser, J. Szlachetko, Z. Sojka, J. Am. Chem. Soc., 2024, 146, 24450-24466.
[9]	Y. Gong, Z. Liu, Z. Li, C. Liu, N. Yan, L. Ma, Environ. Sci. Technol., 2024, 58, 906-914.
[10]	H. Wang, J. Zhu, X. Ren, Y. Tong, P. Chen, Adv. Funct. Mater., 2024, 34, 2312552.
[11]	L. Xue, C. Zhang, H. He, Y. Teraoka, Appl. Catal. B, 2007, 75, 167-174.
[12]	P. Stelmachowski, G. Maniak, J. Kaczmarczyk, F. Zasada, W. Piskorz, A. Kotarba, Z. Sojka, Appl. Catal. B, 2014, 146, 105-111.
[13]	W. Li, T. Wang, X. Cao, Y. Li, G. Miao, N. Sun, J. Li, W. Han, W. Wei, X. Chen, Adv. Funct. Mater., 2025, 35, 2414231.
[14]	Y. Sun, M. Xiao, F. Liu, J. Gan, S. Gao, J. Liu, Adv. Mater., 2024, 36, 2414579.
[15]	Q. Hu, S. Qi, Q. Huo, Y. Zhao, J. Sun, X. Chen, M. Lv, W. Zhou, C. Feng, X. Chai, H. Yang, C. He, J. Am. Chem. Soc., 2024, 146, 2967-2976.
[16]	J. Kim, W. Ko, J. M. Yoo, V. K. Paidi, H. Y. Jang, M. Shepit, J. Lee, H. Chang, H. S. Lee, J. Jo, B. H. Kim, S.-P. Cho, J. van Lierop, D. Kim, K.-S. Lee, S. Back, Y.-E. Sung, T. Hyeon, Adv. Mater., 2022, 34, 2270065.
[17]	B. Zhang, W. Liu, Z. Liu, Y. Pei, D. Li, H. Yang, C. Qiu, Y. Fan, Y. Xu, J. Ding, L. Yu, B. Liu, C. Su, Nat. Commun., 2025, 16, 3052.
[18]	X. Wang, R. Duan, Z. Li, M. Gao, Y. Fu, Y. Han, G. He, H. He, Environ. Sci. Technol., 2025, 59, 5839-5847.
[19]	Q. Ji, B. Tang, X. Zhang, C. Wang, H. Tan, J. Zhao, R. Liu, M. Sun, H. Liu, C. Jiang, J. Zeng, X. Cai, W. Yan, Nat. Commun., 2024, 15, 8089.
[20]	Y. Li, T. Chen, S. Zhao, P. Wu, Y. Chong, A. Li, Y. Zhao, G. Chen, X. Jin, Y. Qiu, D. Ye, ACS Catal., 2022, 12, 4906-4917.
[21]	W. Yang, F. Qi, W. An, H. Yu, S. Liu, P. Ma, R. Chen, S. Liu, L.-L. Lou, K. Yu, ACS Catal., 2024, 14, 5936-5948.
[22]	B. Li, X. Duan, T. Zhao, B. Niu, G. Li, Z. Zhao, Z. Yang, D. Liu, F. Zhang, J. Cheng, Z. Hao, Environ. Sci. Technol., 2024, 58, 2153-2161.
[23]	C. Wang, X. Jie, Y. Qiu, Y. Zhao, H. A. Al-Megren, S. Alshihri, P. P. Edwards, T. Xiao, Appl. Catal. B, 2019, 259, 118019.
[24]	C. Cheng, Z. Zhuo, X. Xia, T. Liu, Y. Shen, C. Yuan, P. Zeng, D. Cao, Y. Zou, J. Guo, L. Zhang, ACS Nano, 2024, 18, 35052-35065.
[25]	S. Liu, W. Xue, Y. Ji, W. Xu, W. Chen, L. Jia, T. Zhu, Z. Zhong, G. Xu, D. Mei, F. Su, Appl. Catal. B, 2023, 323, 122151.
[26]	L. Li, G. Chen, H. Zheng, W. Meng, S. Jia, L. Zhao, P. Zhao, Y. Zhang, S. Huang, T. Huang, J. Wang, Nat. Commun., 2021, 12, 3863.
[27]	J. Mao, W. Chen, W. Sun, Z. Chen, J. Pei, D. He, C. Lv, D. Wang, Y. Li, Angew. Chem. Int. Ed., 2017, 56, 11971-11975.
[28]	N. Sun, X. Wen, F. Wang, W. Wei, Y. Sun, Energy Environ. Sci., 2010, 3, 366.
[29]	G. Chai, W. Zhang, L. F. Liotta, M. Li, Y. Guo, A. Giroir-Fendler, Appl. Catal. B, 2021, 298, 120606.
[30]	Y. Long, X. Zhu, C. Gao, W. Si, J. Li, Y. Peng, Nat. Commun., 2025, 16, 1048.
[31]	Z. Wang, J. Zhu, X. Zu, Y. Wu, S. Shang, P. Ling, P. Qiao, C. Liu, J. Hu, Y. Pan, J. Zhu, Y. Sun, Y. Xie, Angew. Chem. Int. Ed., 2022, 61, e202203249.
[32]	Z. Wei, J. Ding, X. Duan, G.-L. Chen, F.-Y. Wu, L. Zhang, X. Yang, Q. Zhang, Q. He, Z. Chen, J. Huang, S.-F. Hung, X. Yang, Y. Zhai, ACS Catal., 2023, 13, 4711-4718.
[33]	H. Wang, G. Cui, H. Lu, Z. Li, L. Wang, H. Meng, J. Li, H. Yan, Y. Yang, M. Wei, Nat. Commun., 2024, 15, 3765.
[34]	B. Liu, Y. Wang, Y. Huang, L. Liu, Y. Wei, Y. Sun, X. Wei, W. Han, Appl. Catal. B, 2023, 328, 122477.
[35]	Y. Wu, H. Wang, F.-S. Xiao, Z. Wu, J. Am. Chem. Soc., 2025, 147, 25787-25798.
[36]	H. Liu, S. Yang, G. Wang, H. Liu, Y. Peng, C. Sun, J. Li, J. Chen, Environ. Sci. Technol., 2022, 56, 16325-16335.
[37]	L. Xue, H. He, C. Liu, C. Zhang, B. Zhang, Environ. Sci. Technol., 2009, 43, 890-895.
[38]	Y. Shen, J. Deng, S. Impeng, S. Li, T. Yan, J. Zhang, L. Shi, D. Zhang, Environ. Sci. Technol., 2020, 54, 10342-10350.
[39]	P. Hong, C. Xu, H. Zhao, Y. Lei, Adv. Funct. Mater., 2026, 36, 2502833.
[40]	Y. Yan, M. Ouyang, Y. Xing, J. Tian, L. Song, P. Chen, P. Liu, L. Yang, X. Song, M. Fu, D. Ye, Appl. Catal. B, 2025, 365, 124864.
[41]	X. Zhang, Y. Zhang, B. O. Protsenko, M. A. Soldatov, J. Zhang, C. Yang, S. Bo, H. Wang, X. Chen, C. Wang, W. Cheng, Q. Liu, Nat. Commun., 2025, 16, 6921.
[42]	W. Tolman, Angew. Chem. Int. Ed., 2010, 49, 1018-1024.
[43]	Y. Liu, F. Wang, F. Xie, J. Zheng, J. Lan, F. Guo, Y. Sun, L. Zhang, X. Liu, ACS Catal., 2023, 13, 10340-10350.
[44]	H. Zhang, L. Wu, R. Feng, S. Wang, C.-S. Hsu, Y. Ni, A. Ahmad, C. Zhang, H. Wu, H.-M. Chen, W. Zhang, Y. Li, P. Liu, F. Song, ACS Catal., 2023, 13, 6000-6012.
[45]	Y. Jing, K. Taketoshi, N. Zhang, C. He, T. Toyao, Z. Maeno, T. Ohori, N. Ishikawa, K.-I. Shimizu, ACS Catal., 2022, 12, 6325-6333.
[46]	Y. Xiong, Y. Zhao, X. Qi, J. Qi, Y. Cui, H. Yu, Y. Cao, Environ. Sci. Technol., 2021, 55, 13335-13344.
[47]	Y. Ren, X. Lei, H. Wang, J. Xiao, Z. Qu, ACS Catal., 2023, 13, 8293-8306.
[48]	S. Yang, X. Guo, X. Li, T. Wu, L. Zou, Z. He, Q. Xu, J. Zheng, L. Chen, Q. Wang, Z. J. Xu, Angew. Chem. Int. Ed., 2024, 63, e202317957.
[49]	Z. Zhao, P. Wang, C. Song, T. Zhang, S. Zhan, Y. Li, Angew. Chem. Int. Ed., 2023, 62, e202216403.
[50]	E. Pastor, M. Sachs, S. Selim, J. R. Durrant, A. A. Bakulin, A. Walsh, Nat. Rev. Mater., 2022, 7, 503-521.
[51]	D. Li, D. Xu, Y. Pei, Q. Zhang, Y. Lu, B. Zhang, J. Am. Chem. Soc., 2024, 146, 28728-28738.
[52]	K. Zhang, L. Zhang, Z. Zhao, Y. Hou, M. Zhang, S. Li, X. Wang, Z. Sun, W. Chen, Q. Tao, X. Liang, X. Zou, J. Am. Chem. Soc., 2026, 148, 8095-8106.
[53]	A. Li, S. Kong, C. Guo, H. Ooka, K. Adachi, D. Hashizume, Q. Jiang, H. Han, J. Xiao, R. Nakamura, Nat. Catal., 2022, 5, 109-118.
[54]	R.-Y. Fan, H. Liu, J.-K. Ren, Y. Li, J. Nan, Y. Zhou, C.-Y. Liu, Y.-M. Chai, B. Dong, ACS Sustainable Chem. Eng., 2024, 12, 2313-2323.
[55]	Y. Zhu, J. Wang, T. Koketsu, M. Kroschel, J.-M. Chen, S.-Y. Hsu, G. Henkelman, Z. Hu, P. Strasser, J. Ma, Nat. Commun., 2022, 13, 7754.
[56]	S. Li, X. Wang, X. Chi, Y. Xiong, Y. Sun, Z. Tang, X. Gao, H. Zhang, J. Li, K. Nie, J. Xie, Z. Yang, Y.-M. Yan, Adv. Funct. Mater., 2023, 33, 2306098.
[57]	F. Ye, S. Zhang, Q. Cheng, Y. Long, D. Liu, R. Paul, Y. Fang, Y. Su, L. Qu, L. Dai, C. Hu, Nat. Commun., 2023, 14, 2040.
[58]	Z. Yan, X. Wang, Y. Zhang, Z. Zhang, L. Qi, B. Miao, Q. Li, Appl. Catal. B, 2024, 358, 124389.
[59]	L. Wang, C. Lin, I. Boldog, J. Yang, C. Janiak, J. Li, Angew. Chem. Int. Ed., 2024, 63, e202317435.
[60]	R. Su, Y. Gao, L. Chen, Y. Chen, N. Li, W. Liu, B. Gao, Q. Li, Proc. Natl. Acad. Sci. U. S. A., 2024, 121, e2319427121.

同晶取代Co₃O₄纳米复合材料流水线式协同催化分解N₂O

Assembly-line synergistic catalysis in isomorphic substituted Co₃O₄ nanocomposite for enhanced N₂O decomposition

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 5

参考文献

相关文章 9

编辑推荐

Metrics

[1]	龙泽清, 仙光, 张光明, 张涛, 李雪梅. 超声水热法制备高可见光催化活性的BiOCl-Bi₁₂O₁₇Cl₂纳米复合材料去除染料和药物废水[J]. 催化学报, 2020, 41(3): 464-473.
[2]	周鑫, 邹菁, 张胜, 潘敏, 龚晚芸. 具有高电催化活性的g-C₃N₄-ZnS-DNA纳米复合材料的制备及应用[J]. 催化学报, 2017, 38(2): 287-295.
[3]	马亚娟, 王泽美, 徐晓峰, 王靖宇. 多孔材料的二氧化碳吸附与光催化转化研究进展[J]. 催化学报, 2017, 38(12): 1956-1969.
[4]	Shafaq Sahar, Akif Zeb, 刘亚男, Naseeb Ullah, 徐安武. Fe₃O₄/g-C₃N₄复合催化剂增强芬顿/光-芬顿和类过氧化酶反应的活性及稳定性[J]. 催化学报, 2017, 38(12): 2110-2119.
[5]	N. Thirugnanam, 宋怀兵, 吴艳. CdSe量子点/氧化石墨烯复合物对灿烂绿染料的光催化降解性能研究[J]. 催化学报, 2017, 38(12): 2150-2159.
[6]	张贺新, Jae-Hyeong Park, Young-Kwon Moon, Eun-Bin Ko, Dong-ho Lee, 胡雁鸣, 张学全, Keun-Byoung Yoon. 石墨烯/二氯化镁负载钛系齐格勒-纳塔催化剂制备及其乙烯聚合性能[J]. 催化学报, 2017, 38(1): 131-137.
[7]	施斌斌;姚国新;李国华;;郑遗凡. 碳化钨-二氧化钛纳米复合材料的制备及其电催化活性[J]. 催化学报, 2010, 31(4): 466-470.
[8]	童东绅;夏厚胜;周春晖. 蒙皂族粘土基催化材料的设计制备和催化作用[J]. 催化学报, 2009, 30(11): 1170-1187.
[9]	吴季怀;林煜;黄妙良;林建明;黄昀日方;殷澍;佐藤次雄. 层状纳米光催化复合材料HNbWO6/Pt的合成和性质[J]. 催化学报, 2001, 22(2): 209-211.