离子热法合成沸石咪唑骨架材料及其溶解-结晶机理研究

doi:10.1016/S1872-2067(14)60278-3

催化学报 ›› 2015, Vol. 36 ›› Issue (6): 855-865.DOI: 10.1016/S1872-2067(14)60278-3

离子热法合成沸石咪唑骨架材料及其溶解-结晶机理研究

王亚松^a,c, 徐云鹏^a, 李大伟^a,c, 刘浩^a,c, 厉晓蕾^a,c, 陶硕^a,c, 田志坚^a,b

a 中国科学院大连化学物理研究所洁净能源国家实验室, 辽宁大连116023;
b 中国科学院大连化学物理研究所催化基础国家重点实验室, 辽宁大连116023;
c 中国科学院大学, 北京100049

收稿日期:2014-11-14 修回日期:2014-12-14 出版日期:2015-05-21 发布日期:2015-05-21
通讯作者: 田志坚,电话/传真: (0411)84379151; 电子信箱: tianz@dicp.ac.cn
基金资助:
国家自然科学基金(21001102, 21373214).

Ionothermal synthesis of zeolitic imidazolate frameworks and the synthesis dissolution-crystallization mechanism

Yasong Wang^a,c, Yunpeng Xu^a, Dawei Li^a,c, Hao Liu^a,c, Xiaolei Li^a,c, Shuo Tao^a,c, Zhijian Tian^a,b

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
c University of Chinese Academy of Sciences, Beijing 100049, China

Received:2014-11-14 Revised:2014-12-14 Online:2015-05-21 Published:2015-05-21
Supported by:
This work was supported by the National Natural Science Foundation of China (21001102, 21373214).

摘要/Abstract

摘要：

基于沸石咪唑骨架材料在离子液体和低共熔溶剂中冷却结晶的析出方式, 开发了一种离子热法合成沸石咪唑骨架材料的新途径, 采用X射线衍射、扫描电镜、核磁共振光谱、红外光谱以及热重分析等方法对制备的产物进行了表征, 研究了合成条件对产物结晶度、尺寸和形貌的影响, 探讨了沸石咪唑骨架材料在离子热合成体系中的溶解-结晶析出机理. 研究发现, 冷却速率能够影响产物形貌, 急速冷却时, sod (RCSR代码)型产物的形貌为球形, zni (RCSR代码)型产物为棒状或平板状; 程序控制冷却时, sod型产物的形貌为多面体, zni型产物呈团簇状.

关键词: 离子热合成, 沸石咪唑骨架材料, 溶解-结晶机理, 溶解度, 冷却析出

Abstract:

A cooling-induced crystallization process was used to synthesize sod (RCSR symbol)- and zni (RCSR symbol)-type zeolitic imidazolate frameworks (ZIFs) ionothermally in 1-ethyl-3-methylimidazolium bromide ionic liquid and a urea-choline chloride deep eutectic solvent. The products were characterized by X-ray diffraction, scanning electron microscopy, nuclear magnetic resonance spectroscopy, infrared spectroscopy and thermal gravimetric analysis. The effect of the synthesis conditions on the crystallinity, size and morphology of the product was studied. The dissolution-crystallization mechanism of ZIFs was discussed. The cooling rate affected the product morphology. When the synthesis solution was cooled by rapid cooling, the shape of the sod-type product was spherical and the morphology of the zni-type product was rod-like or plate-like. With a programmed cooling, the sod-type product was polyhedron in shape and the zni-type product was in the form of clusters.

Key words: Ionothermal synthesis, Zeolitic imidazolate frameworks, Dissolution-crystallization mechanism, Solubility, Precipitation

王亚松, 徐云鹏, 李大伟, 刘浩, 厉晓蕾, 陶硕, 田志坚. 离子热法合成沸石咪唑骨架材料及其溶解-结晶机理研究[J]. 催化学报, 2015, 36(6): 855-865.

Yasong Wang, Yunpeng Xu, Dawei Li, Hao Liu, Xiaolei Li, Shuo Tao, Zhijian Tian. Ionothermal synthesis of zeolitic imidazolate frameworks and the synthesis dissolution-crystallization mechanism[J]. Chinese Journal of Catalysis, 2015, 36(6): 855-865.

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参考文献

[1] Phan A, Doonan C J, Uribe-Romo F J, Knobler C B, O'Keeffe M, Yaghi O M. Acc Chem Res, 2010, 43: 58
[2] Tranchemontagne D J, Mendoza-Cortes J L, O'Keeffe M, Yaghi O M. Chem Soc Rev, 2009, 38: 1257
[3] Chizallet C, Lazare S, Bazer-Bachi D, Bonnier F, Lecocq V, Soyer E, Quoineaud A A, Bats N. J Am Chem Soc, 2010, 132: 12365
[4] Jiang H L, Akita T, Ishida T, Haruta M, Xu Q. J Am Chem Soc, 2011, 133: 1304
[5] Farrusseng D, Aguado S, Pinel C. Angew Chem Int Ed, 2009, 48: 7502
[6] Park K S, Ni Z, Cote A P, Choi J Y, Huang R, Uribe-Romo F J, Chae H K, O'Keeffe M, Yaghi O M. Proc Natl Acad Sci USA, 2006, 103: 10186
[7] Perez-Pellitero J, Amrouche H, Siperstein F R, Pirngruber G, Nieto-Draghi C, Chaplais G, Simon-Masseron A, Bazer-Bachi D, Peralta D, Bats N. Chem Eur J, 2010, 16: 1560
[8] Jiang H L, Liu B, Akita T, Haruta M, Sakurai H, Xu Q. J Am Chem Soc, 2009, 131: 11302
[9] Venna S R, Carreon M A. J Am Chem Soc, 2010, 132: 76
[10] Bennett T D, Tan J H, Moggach S A, Galvelis R, Mellot-Draznieks C, Reisner B A, Thirumurugan A, Allan D R, Cheetham A K. Chem Eur J, 2010, 16: 10684
[11] Tan J C, Bennett T D, Cheetham A K. Proc Natl Acad Sci USA, 2010, 107: 9938
[12] Tian Y Q, Cai C X, Ren X M, Duan C Y, Xu Y, Gao S, You X Z. Chem Eur J, 2003, 9: 5673
[13] Hikov T, Schroder C A, Cravillon J, Wiebckeb M, Huber K. Phys Chem Chem Phys, 2012, 14: 511
[14] Huang X C, Lin Y Y, Zhang J P, Chen X M. Angew Chem Int Ed, 2006, 45: 1557
[15] Pan Y C, Liu Y Y, Zeng G F, Zhao L, Lai Z P. Chem Commun, 2011, 47: 2071
[16] Gross A F, Sherman E, Vajo J J. Dalton Trans, 2012, 41: 5458
[17] Venna S R, Jasinski J B, Carreon M A. J Am Chem Soc, 2010, 132: 18030
[18] Cravillon J, Schoder C A, Nayuk R, Gummel J, Huber K, Wiebcke M. Angew Chem Int Ed, 2011, 50: 8067
[19] Seoane B, Zamaro J M, Tellez C, Coronas J. CrystEngComm, 2012, 14: 3103
[20] Cho H Y, Kim J, Kim S N, Ahn W S. Microporous Mesoporous Mater, 2013, 169: 180
[21] Yang L S, Lu H M. Chin J Chem, 2012, 30: 1040
[22] Beldon P J, Fabian L, Stein R S, Thirumurugan A, Cheetham A K, Friscic T. Angew Chem Int Ed, 2010, 49: 9640
[23] Shi Q, Chen Z F, Song Z W, Li J P, Dong J X. Angew Chem Int Ed, 2011, 50: 672
[24] Zhang H, Shi Q, Kang X Z, Dong J X. J Coord Chem, 2013, 66: 2079
[25] Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O'Keeffe M, Yaghi O M. Science, 2008, 319: 939
[26] Lehnert R, Seel F Z. Anorg Allg Chem, 1980, 464: 187
[27] Cooper E R, Andrews C D, Wheatley P S, Webb P B, Wormald P, Morris R E. Nature, 2004, 430: 1012
[28] Wang Y S, Xu Y P, Tian Z J, Lin L W. Chin J Catal (王亚松, 徐云鹏, 田志坚, 林励吾. 催化学报), 2012, 33: 39
[29] Dybtsev D N, Chun H, Kim K. Chem Commun, 2004:1594
[30] Zhang J, Wu T, Chen S M, Feng P Y, Bu X H. Angew Chem Int Ed, 2009, 48: 3486
[31] Chen S M, Zhang J, Wu T, Feng P Y, Bu X H. Dalton Trans, 2010, 39: 697
[32] Wang Y S, Xu Y P, Ma H J, Xu R S, Liu H, Li D W, Tian Z J. Microporous Mesoporous Mater, 2014, 195: 50
[33] Abbott A P, Capper G, Davies D L, Rasheed R K, Tambyrajah V. Chem Commun, 2003: 70
[34] Zhang Q H, De Oliveira V, Royer S, Jerome F. Chem Soc Rev, 2012, 41: 7108
[35] Cravillon J, Munzer S, Lohmeier S J, Feldhoff A, Huber K, Wiebcke M. Chem Mater, 2009, 21: 1410
[36] Griffiths H. J Soc Chem Ind, 1925, 44: 7
[37] Sarig S, Glasner A, Epstein J A, Eidelman N. J Cryst Growth, 1977, 39: 255
[38] Xu R R, Pang W Q, Yu J H, Huo Q S, Chen J S. Chemistry—Zeolites and Porous Materials. Beijing: Science Press (徐如人, 庞文琴, 于吉红, 霍启升, 陈接胜. 分子筛与多孔材料化学. 北京: 科学出版社), 2004. 379
[39] Krivankova I, Marcisinova M, Sohnel O. J Chem Eng Data, 1992, 37: 23
[40] Mullin J W. Crystallization. 3rd Ed. London: Butterworth Heinemann, 1993. 20
[41] Jones A G, Mullin J W. Chem Eng Sci, 1974, 29: 105
[42] Dirksen J A, Ring T A. Chem Eng Sci, 1991, 46: 2389

离子热法合成沸石咪唑骨架材料及其溶解-结晶机理研究

Ionothermal synthesis of zeolitic imidazolate frameworks and the synthesis dissolution-crystallization mechanism

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