Electrocatalytic measurement of methionine concentration with a carbon nanotube paste electrode modified with benzoylferrocene

doi:10.1016/S1872-2067(12)60582-8

Electrocatalytic measurement of methionine concentration with a carbon nanotube paste electrode modified with benzoylferrocene

Hadi BEITOLLAHI^a, Alireza MOHADESI^b, Farzaneh GHORBANI^b, Hassan KARIMI MALEH^c, Mehdi BAGHAYERI^d, Rahman HOSSEINZADEH^e

a Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran;
b Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran;
c Department of Chemistry, Graduated University of Advanced Technology, Kerman, Iran;
d Department of Chemistry, Faculty of Science, Hakim Sabzevari University, PO Box 397, Sabzevar, Iran;
e Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran

收稿日期:2013-02-07 修回日期:2013-03-15 出版日期:2013-07-16 发布日期:2013-07-16
通讯作者: Hadi BEITOLLAHI

Electrocatalytic measurement of methionine concentration with a carbon nanotube paste electrode modified with benzoylferrocene

Hadi BEITOLLAHI^a, Alireza MOHADESI^b, Farzaneh GHORBANI^b, Hassan KARIMI MALEH^c, Mehdi BAGHAYERI^d, Rahman HOSSEINZADEH^e

a Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran;
b Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran;
c Department of Chemistry, Graduated University of Advanced Technology, Kerman, Iran;
d Department of Chemistry, Faculty of Science, Hakim Sabzevari University, PO Box 397, Sabzevar, Iran;
e Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran

Received:2013-02-07 Revised:2013-03-15 Online:2013-07-16 Published:2013-07-16

摘要/Abstract

摘要： A benzoylferrocene modified multi-wall carbon nanotube paste electrode for the measurement of methionine (MET) concentration is described. MET electrochemical response characteristics of the modified electrode in a phosphate buffer solution of pH 7.0 were investigated by cyclic voltammetry, square wave voltammetry, and chronoamperometry. Under optimized conditions, the square wave voltammetric peak current of MET increased linearly with MET concentration in the range of 1.0 × 10^-7 to 2.0 ×10^-4 mol/L. The detection limit was 58.0 nmol/L MET. The diffusion coefficient (D = 5.62 × 10^-6 cm²/s) and electron transfer coefficient (α = 0.4) for MET oxidation were also determined. The sensor was successfully applied for the measurement of MET concentration in human urine.

关键词: Methionine, Electrocatalysis, Carbon nanotube, Chemically modified electrode, Voltammetry, Benzoylferrocene

Abstract: A benzoylferrocene modified multi-wall carbon nanotube paste electrode for the measurement of methionine (MET) concentration is described. MET electrochemical response characteristics of the modified electrode in a phosphate buffer solution of pH 7.0 were investigated by cyclic voltammetry, square wave voltammetry, and chronoamperometry. Under optimized conditions, the square wave voltammetric peak current of MET increased linearly with MET concentration in the range of 1.0 × 10^-7 to 2.0 ×10^-4 mol/L. The detection limit was 58.0 nmol/L MET. The diffusion coefficient (D = 5.62 × 10^-6 cm²/s) and electron transfer coefficient (α = 0.4) for MET oxidation were also determined. The sensor was successfully applied for the measurement of MET concentration in human urine.

Key words: Methionine, Electrocatalysis, Carbon nanotube, Chemically modified electrode, Voltammetry, Benzoylferrocene

Hadi BEITOLLAHI, Alireza MOHADESI, Farzaneh GHORBANI, Hassan KARIMI MALEH, Mehdi BAGHAYERI, Rahman HOSSEINZADEH. Electrocatalytic measurement of methionine concentration with a carbon nanotube paste electrode modified with benzoylferrocene[J]. 催化学报, DOI: 10.1016/S1872-2067(12)60582-8.

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Electrocatalytic measurement of methionine concentration with a carbon nanotube paste electrode modified with benzoylferrocene

Electrocatalytic measurement of methionine concentration with a carbon nanotube paste electrode modified with benzoylferrocene

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