Precursors of active Ni species in Ni/Al2O3 catalysts for oxidative dehydrogenation of ethane

doi:10.1016/S1872-2067(12)60672-X

催化学报 ›› 2013, Vol. 34 ›› Issue (10): 1905-1913.DOI: 10.1016/S1872-2067(12)60672-X

Precursors of active Ni species in Ni/Al₂O₃ catalysts for oxidative dehydrogenation of ethane

Lucie Smoláková^a, Šárka Botková^a, Libor Čapek^a, Peter Priecel^a, Agnieszka Sołtysek^a, Martin Kout^a, Lenka Matějová^b

a Department of Physical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic;
b Nanotechnology Centre, VŠB-Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava-Poruba, Czech Republic

收稿日期:2013-06-12 修回日期:2013-07-24 出版日期:2013-09-29 发布日期:2013-09-29

Precursors of active Ni species in Ni/Al₂O₃ catalysts for oxidative dehydrogenation of ethane

Lucie Smoláková^a, Šárka Botková^a, Libor Čapek^a, Peter Priecel^a, Agnieszka Sołtysek^a, Martin Kout^a, Lenka Matějová^b

a Department of Physical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic;
b Nanotechnology Centre, VŠB-Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava-Poruba, Czech Republic

Received:2013-06-12 Revised:2013-07-24 Online:2013-09-29 Published:2013-09-29
Contact: Libor Čapek

摘要/Abstract

摘要：

Ni/Al₂O₃ catalysts for oxidative dehydrogenation (ODH) of ethane were prepared by impregnation of Al₂O₃ with nickel acetate or nickel nitrate, and by mechanical mixing of NiO and Al₂O₃. The Ni-based catalysts were characterized by N₂ adsorption-desorption, X-ray diffraction, diffuse reflectance UV-visible diffuse reflectance spectroscopy, and temperature-programmed reduction of hydrogen. The results showed that formation of crystalline NiO particles with a size of < 8 nm and/or non-stoichiometric NiO species in the Ni/Al₂O₃ catalysts led to more active species in ODH of ethane under the investigated reaction conditions. In contrast, tetrahedral Ni species present in the catalysts led to higher selectivity for ethene. Formation of large crystalline NiO particles (22-32 nm) over Ni/Al₂O₃ catalysts decreased the selectivity for ethene.

关键词: Nickel, Alumina, Ethane, Oxidative dehydrogenation, Nickel species

Abstract:

Key words: Nickel, Alumina, Ethane, Oxidative dehydrogenation, Nickel species

Lucie Smoláková, Šárka Botková, Libor Čapek, Peter Priecel, Agnieszka Sołtysek, Martin Kout, Lenka Matějová. Precursors of active Ni species in Ni/Al₂O₃ catalysts for oxidative dehydrogenation of ethane[J]. 催化学报, 2013, 34(10): 1905-1913.

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Precursors of active Ni species in Ni/Al₂O₃ catalysts for oxidative dehydrogenation of ethane

Precursors of active Ni species in Ni/Al₂O₃ catalysts for oxidative dehydrogenation of ethane

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