Application of 3,4-dihydroxycinnamic acid as a suitable mediator and multiwall carbon nanotubes as a sensor for the electrocatalytic determination of L-cysteine

doi:10.1016/S1872-2067(14)60065-6

催化学报 ›› 2014, Vol. 35 ›› Issue (7): 1166-1172.DOI: 10.1016/S1872-2067(14)60065-6

Application of 3,4-dihydroxycinnamic acid as a suitable mediator and multiwall carbon nanotubes as a sensor for the electrocatalytic determination of L-cysteine

Mohsen Keyvanfard^a, Rasoul Salmani-mobarakeh^b, Hassan Karimi-Maleh^c, Khadijeh Alizad^a

a. Department of Chemsitry, Majlesi Branch, Islamic Azad University, Isfahan, Iran;
b. Department of Chemistry, Shahreza Branch, Islamic Azad University, Isfahan, Iran;
c. Department of Chemistry, Graduate University of Advanced Technology, Kerman, Iran

收稿日期:2013-11-09 修回日期:2014-02-28 出版日期:2014-06-28 发布日期:2014-06-28
通讯作者: Mohsen Keyvanfard, Hassan Karimi-Maleh

Application of 3,4-dihydroxycinnamic acid as a suitable mediator and multiwall carbon nanotubes as a sensor for the electrocatalytic determination of L-cysteine

Mohsen Keyvanfard^a, Rasoul Salmani-mobarakeh^b, Hassan Karimi-Maleh^c, Khadijeh Alizad^a

a. Department of Chemsitry, Majlesi Branch, Islamic Azad University, Isfahan, Iran;
b. Department of Chemistry, Shahreza Branch, Islamic Azad University, Isfahan, Iran;
c. Department of Chemistry, Graduate University of Advanced Technology, Kerman, Iran

Received:2013-11-09 Revised:2014-02-28 Online:2014-06-28 Published:2014-06-28

摘要/Abstract

摘要：

A highly sensitive electrochemical sensor was prepared for the determination of L-cysteine using a modified multiwall carbon nanotubes paste electrode in the presence of 3,4-dihydroxycinnamic acid (3,4-DHCA) as a mediator, based on an electrocatalytic process. The results indicate that the electrode is electrocatalytically efficient for the oxidation of L-cysteine in the presence of 3,4-DHCA. The interaction between the mediator and L-cysteine can be used for its sensitive and selective determination. Using chronoamperometry, the catalytic reaction rate constant was calculated to be 2.37×10² mol^-1 L s^-1. The catalytic peak current was linearly dependent on the L-cysteine concentration in the range of 0.4-115 μmol/L. The detection limit obtained by linear sweep voltammetry was 0.25 μmol/L. Finally, the modified electrode was examined as a selective, simple, and precise new electrochemical sensor for the determination of L-cysteine in real samples.

关键词: L-Cysteine, Multiwall carbon nanotube, Voltammetry, 3,4-Dihydroxycinnamic acid

Abstract:

Key words: L-Cysteine, Multiwall carbon nanotube, Voltammetry, 3,4-Dihydroxycinnamic acid

Mohsen Keyvanfard, Rasoul Salmani-mobarakeh, Hassan Karimi-Maleh, Khadijeh Alizad. Application of 3,4-dihydroxycinnamic acid as a suitable mediator and multiwall carbon nanotubes as a sensor for the electrocatalytic determination of L-cysteine[J]. 催化学报, 2014, 35(7): 1166-1172.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(14)60065-6

https://www.cjcatal.com/CN/Y2014/V35/I7/1166

参考文献

[1] The Primary Structure Of Proteins Is the Amino Acid Sequence. The Microbial World. University of Wisconsin-Madison Bacteriology Department. Retrieved 16 September 2012.
[2] Kazemi S, Karimi-Maleh H, Hosseinzadeh R, Faraji F. Ionics, 2013, 19: 933
[3] Chwatko G, Bald E. Talanta, 2000, 52: 509
[4] Friedman M, Krull L H, Cavins J F. J Biolog Chem, 1970, 245: 3868
[5] Saetre R, Rabenstein D L. Anal Biochem, 1978, 90: 684
[6] Jin W R, Wang Y. J Chromatog A, 1997, 769: 307
[7] Chrastil J. Analyst, 1990, 115: 1383
[8] Gaitonde M K. Biochem J, 1967, 104: 627
[9] Wu F Y, Liao W S, Wu Y M, Wan X F. Spect Lett, 2008, 41: 393
[10] Giljanovi? J, Brklja?a M, Prki? A. Molecules, 2011, 16: 7224
[11] Nie L H, Ma H M, Sun M, Li X H, Su M H, Liang S C. Talanta, 2003, 59: 959
[12] Ensafi A A, Dadkhah-Tehrani S, Karimi-Maleh H. Anal Sci, 2011, 27: 409
[13] Amini M K, Khorasani J H, Khaloo S S, Tangestaninejad S. Anal Biochem, 2003, 320: 32
[14] Perevezentseva D O, Gorchakov E V. J Solid State Electrochem, 2012, 16: 2405
[15] Ahmad M, Pan C F, Zhu J. J Mater Chem, 2010, 20: 7169
[16] Ensafi A A, Karimi-Maleh H. J Electroanal Chem, 2010, 640: 75
[17] Ensafi A A, Bahrami H, Karimi-Maleh H, Mallakpour S. Chin J Catal (催化学报), 2012, 33: 1919
[18] Ensafi A A, Lotfi M, Karimi-Maleh H. Chin J Catal (催化学报), 2012, 33: 487
[19] Tavana T, Khalilzadeh M A, Karimi-Maleh H, Ensafi A A, Beitollahi H, Zareyee D. J Mol Liq, 2012, 168: 69
[20] Karimi-Maleh H, Biparva P, Hatami M. Biosens Bioelect, 2013, 48: 270
[21] Elyasi M, Khalilzadeh M A, Karimi-Maleh H. Food Chem, 2013, 141: 4311
[22] Beitollah H, Goodarzian M, Khalilzadeh M A, Karimi-Maleh H, Hassanzadeh M, Tajbakhsh M. J Mol Liq, 2012, 173: 137
[23] Keyvanfard M, Khosravi V, Karimi-Maleh H, Alizad K, Rezaei B. J Mol Liq, 2013, 177: 182
[24] Keyvanfard M, Shakeri R, Karimi-Maleh H, Alizad K. Mater Sci Eng C, 2013, 33: 811
[25] Ensafi A A, Karimi-Maleh H, Keyvanfard M. Int J Environ Anal Chem, 2013, 93: 650
[26] Moradi R, Sebt S A, Karimi-Maleh H, Sadeghi R, Karimi F, Bahari A, Arabi H. Phys Chem Chem Phys, 2013, 15: 5888
[27] Keyvanfard M, Ensafi A A, Karimi-Maleh H. J Solid State Electrochem, 2012, 16: 2949
[28] Karimi-Maleh H, Keyvanfard M, Alizad K, Khosravi V, Asnaashariisfahani M. Int J Electrochem Sci, 2012, 7: 6816
[29] Mokhtari A, Karimi-Maleh H, Ensafi A A, Beitollahi H. Sens Actuators B, 2012, 169: 96
[30] Roodbari Shahmiri M, Bahari A, Karimi-Maleh H, Hosseinzadeh R, Mirnia N. Sens Actuators B, 2013, 177: 70
[31] Karimi-Maleh H, Ensafi A A, Allafchian A R. J Solid State Electrochem, 2010, 14: 9
[32] Ma X Y, Chao M Y. Anal Methods, 2013, 5: 5823
[33] Mirmomtaz E, Ensafi A A, Karimi-Maleh H. Electroanalysis, 2008, 20: 1973
[34] Rafiee B, Fakhari A R. Biosens Bioelect, 2013, 46: 130
[35] Galus Z. Fundumentals of Electrochemical Analysis. New York: Ellis Horwood, 1976
[36] Raoof J B, Ojani R, Karimi-Maleh H. Electroanalysis, 2008, 20: 1259
[37] Ensafi A A, Karimi-Maleh H, Mallakpour S, Hatami M. Sens Actuators B, 2011, 155: 464
[38] Ensafi A A, Karimi-Maleh H, Mallakpour S, Rezaei B. Colloids Surf B, 2011, 87: 480
[39] Keyvanfard M, Karimi-Maleh H, Alizad K. Chin J Catal (催化学报), 2013, 34: 1883
[40] Afzali D, Karimi-Maleh H, Khalilzadeh M A. Environ Chem Lett, 2011, 9: 375
[41] Ensafi A A, Karimi-Maleh H, Ghiaci M, Arshadi M. J Mater Chem, 2011, 21: 15022
[42] Ensafi A A, Dadkhah-Tehrani S, Karimi-Maleh H. Anal Sci, 2011, 27: 409
[43] Ensafi A A, Karimi-Maleh H, Mallakpour S. Electroanalysis, 2011, 23: 1478
[44] Taheri A R, Mohadesi A, Afzali D, Karimi-Maleh H, Moghaddam H M, Zamani H, Zad Z R. Int J Electrochem Sci, 2011, 6: 171

Application of 3,4-dihydroxycinnamic acid as a suitable mediator and multiwall carbon nanotubes as a sensor for the electrocatalytic determination of L-cysteine

Application of 3,4-dihydroxycinnamic acid as a suitable mediator and multiwall carbon nanotubes as a sensor for the electrocatalytic determination of L-cysteine

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 14

编辑推荐

Metrics

[1]	Behnaz Afzalian, Joel T. Mague, Maryam Mohamadi, S. Yousef Ebrahimipour, Behjat Pour amiri, Esmat Tavakolinejad Kermani. Ni(II), Co(II), and Cu(II) complexes incorporating 2-pyrazinecarboxylic acid: Synthesis, characterization, electrochemical evaluation, and catalytic activity for the synthesis of 2H-indazolo[2,1-b]phthalazine-triones[J]. 催化学报, 2015, 36(7): 1101-1108.
[2]	Javad Hosseini, Mehdi Abdolmaleki, Hamid Reza Pouretedal, Mohammad Hossein Keshavarz. Electrocatalytic activity of porous nanostructured Fe/Pt-Fe electrode for methanol electrooxidation in alkaline media[J]. 催化学报, 2015, 36(7): 1029-1034.
[3]	Mohsen Keyvanfard, Maryam Tahmasbi, Hassan Karimi-Maleh, Khadijeh Alizad. A voltammetric sensor with a multiwall carbon nanotube paste electrode and naphthol green as a mediator for the determination of N-actylcysteine in the presence of tryptophan[J]. 催化学报, 2014, 35(4): 501-508.
[4]	Seyed Naser Azizi, Shahram Ghasemi, Neda Salek Gilani. An electrode with Ni(Ⅱ) loaded analcime zeolite catalyst for the electrooxidation of methanol[J]. 催化学报, 2014, 35(3): 383-390.
[5]	Reza Ojani, Jahan-Bakhsh Raoof, Ali Asghar Maleki, Saeid Safshekan. Simultaneous and sensitive detection of dopamine and uric acid using a poly(L-methionine)/gold nanoparticle-modified glassy carbon electrode[J]. 催化学报, 2014, 35(3): 423-429.
[6]	Mohammad Mazloum-Ardakani, Mahboobe Abolhasani, Bibi-Fatemeh Mirjalili, Mohammad Ali Sheikh-Mohseni, Afsaneh Dehghani-Firouzabadi, Alireza Khoshroo. Electrocatalysis of dopamine in the presence of uric acid and folic acid on modified carbon nanotube paste electrode[J]. 催化学报, 2014, 35(2): 201-209.
[7]	Mir Ghasem Hosseini, Mehdi Abdolmaleki, Sajjad Ashrafpoor. Methanol electro-oxidation on a porous nanostructured Ni/Pd-Ni electrode in alkaline media[J]. 催化学报, 2013, 34(9): 1712-1719.
[8]	Ali A. Ensafi, E. Heydari-Bafrooei, B. Rezaei. Simultaneous detection of hydroxylamine and phenol using p-aminophenol-modified carbon nanotube paste electrode[J]. 催化学报, 2013, 34(9): 1768-1775.
[9]	Hadi BEITOLLAHI, Alireza MOHADESI, Farzaneh GHORBANI, Hassan KARIMI MALEH, Mehdi BAGHAYERI, Rahman HOSSEINZADEH. Electrocatalytic measurement of methionine concentration with a carbon nanotube paste electrode modified with benzoylferrocene[J]. 催化学报, 2013, 34(7): 1333-1338.
[10]	Mohsen Keyvanfard, Hassan Karimi-Maleh, Khadijeh Alizad. Multiwall carbon nanotube paste electrode with 3,4-dihydroxy-cinnamic acid as mediator for the determination of glutathione in pharmaceutical and urine samples[J]. 催化学报, 2013, 34(10): 1883-1889.
[11]	Ali A. ENSAFI, Mahsa LOTFI, Hassan KARIMI-MALEH. New Modified-Multiwall Carbon Nanotubes Paste Electrode for Electrocatalytic Oxidation and Determination of Hydrazine Using Square Wave Voltammetry[J]. 催化学报, 2012, 33(3): 487-493.
[12]	Ali A. ENSAFI, Hajar BAHRAMI, Hassan KARIMI-MALEH, Shadpour MALLAKPOUR. Carbon Paste Electrode Prepared from Chemically Modified Multiwall Carbon Nanotubes for the Voltammetric Determination of Isoprenaline in Pharmaceutical and Urine Samples[J]. 催化学报, 2012, 33(12): 1919-1926.
[13]	Jahan Bakhsh RAOOF, Reza OJANI, Mehdi BAGHAYERI. Sensitive Voltammetric Determination of Captopril Using a Carbon Paste Electrode Modified with Nano-TiO2/Ferrocene Carboxylic Acid[J]. 催化学报, 2011, 32(11): 1685-1692.
[14]	M. JAFARIAN;*;F. GOBAL;M. G. MAHJANI;M. HOSSEINI ALIABADI. 碱性溶液中分子氧在多晶银上的多步还原[J]. 催化学报, 2010, 31(5): 541-546.