邻苯三酚红多壁碳纳米管糊电极为传感器分析制药和生物样品中异丙基肾上腺素

doi:10.1016/S1872-2067(15)61036-1

催化学报 ›› 2016, Vol. 37 ›› Issue (4): 579-583.DOI: 10.1016/S1872-2067(15)61036-1

邻苯三酚红多壁碳纳米管糊电极为传感器分析制药和生物样品中异丙基肾上腺素

Mohsen Keyvanfard, Khadijeh Alizad

伊斯兰自由大学马杰斯分校化学系, 伊斯法罕, 伊朗

收稿日期:2015-10-10 修回日期:2016-01-05 出版日期:2016-03-30 发布日期:2016-03-30
通讯作者: Mohsen Keyvanfard

Determination of isoproterenol in pharmaceutical and biological samples using a pyrogallol red multiwalled carbon nanotube paste electrode as a sensor

Mohsen Keyvanfard, Khadijeh Alizad

Department of Chemistry, Majlesi Branch, Islamic Azad University, Isfahan, Iran

Received:2015-10-10 Revised:2016-01-05 Online:2016-03-30 Published:2016-03-30
Contact: Mohsen Keyvanfard

摘要/Abstract

摘要：

异丙基肾上腺素(ISPR)是一种重要的邻苯二酚胺类药物, 广泛用于治疗心脏疾病. 然而, 过量服用该药对人体非常危险. 本文采用邻苯三酚红修饰多壁碳纳米管糊电极(PGRMMWCNTPE)制备了一种新型传感器, 用于高灵敏度检测水溶液中的ISPR. 采用计时电流法、循环伏安法和方波伏安法考察了PGRMMWCNTPE电极电催化氧化ISPR性能. 通过伏安数据计算了ISPR氧化的催化反应速率常数、电子传递系数和扩散系数. 在ISPR浓度0.8-570 μmol/L范围内建立了线性标准曲线, 检测限为0.47 μmol/L ISPR. 将该传感器用于尿液和药物样品中ISPR检测得到满意结果.

关键词: 异丙基肾上腺素, 药物分析, 邻苯三酚红, 伏安法, 多壁碳纳米管

Abstract:

Isoproterenol (ISPR) is an important catecholamine-based drug that is widely used in the treatment of heart disease. However, overdose of this drug is very dangerous to the human body. In this study, a new sensor based on a pyrogallol red modified-multiwalled carbon nanotube paste electrode (PGRMMWCNTPE) was prepared and used for high sensitivity determination of ISPR in aqueous solution. Electrocatalytic oxidation of ISPR at the PGRMMWCNTPE was investigated by chronoamperometry, cyclic voltammetry, and square-wave voltammetry. The values of the catalytic rate constant, electron transfer coefficient, and diffusion coefficient for ISPR oxidation were then calculated using voltammetric data. A linear calibration curve was constructed for ISPR concentration in the range 0.8-570 μmol/L with a detection limit of 0.47 μmol/L ISPR. The sensor was then applied to the determination of ISPR in urine and drug samples with satisfactory results.

Key words: Isoproterenol, Pharmaceutical analysis, Pyrogallol red, Voltammetry, Multiwalled carbon nanotubes

Mohsen Keyvanfard, Khadijeh Alizad. 邻苯三酚红多壁碳纳米管糊电极为传感器分析制药和生物样品中异丙基肾上腺素[J]. 催化学报, 2016, 37(4): 579-583.

Mohsen Keyvanfard, Khadijeh Alizad. Determination of isoproterenol in pharmaceutical and biological samples using a pyrogallol red multiwalled carbon nanotube paste electrode as a sensor[J]. Chinese Journal of Catalysis, 2016, 37(4): 579-583.

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邻苯三酚红多壁碳纳米管糊电极为传感器分析制药和生物样品中异丙基肾上腺素

Determination of isoproterenol in pharmaceutical and biological samples using a pyrogallol red multiwalled carbon nanotube paste electrode as a sensor

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