Application of Amino-Functionalized SBA-15 Type Mesoporous Silica in One-Pot Synthesis of Spirooxindoles

doi:10.1016/S1872-2067(11)60456-7

Abstract

Abstract: Amino-functionalized SBA-15 (SBA-Pr-NH₂) has been used as a new basic nanocatalyst in the one-pot synthesis of spirooxindole derivatives via the three-component condensation reaction of isatins, activated methylene reagents, and dimedone in an aqueous medium. SBA-Pr-NH₂ has been established as an efficient heterogeneous nanoporous solid basic catalyst (pore size of 6 nm) that can be easily handled and removed from the reaction mixture by simple filtration, and also recovered and reused without noticeable loss of reactivity.

Key words: amino-functionalized SBA-15, spirooxindoles, isatin, nano-reactor, green synthesis

Ghodsi MOHAMMADI ZIARANI, Alireza BADIEI, Somayeh MOUSAVI, Negar LASHGARI, Afsaneh SHAHBAZI. Application of Amino-Functionalized SBA-15 Type Mesoporous Silica in One-Pot Synthesis of Spirooxindoles[J]. Chinese Journal of Catalysis, 2012, 33(11): 1832-1839.

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