Synthesis of SAPO-35 molecular sieve and its catalytic properties in the methanol-to-olefins reaction

doi:10.1016/S1872-2067(12)60557-9

Abstract

Abstract:

SAPO-35 molecular sieve samples with different Si contents were hydrothermally synthesized using hexamethyleneimine as the template and characterized by XRD, XRF, SEM, MAS NMR, XPS and N₂ physisorption. Three SAPO-35 samples were tested as methanol-to-olefins catalysts. After the reaction, the evolution of coke species was investigated over SAPO-35 and SAPO-34 catalysts with similar Si concentrations. A correlation between the cage size of the molecular sieves and the coke species was obtained.

Key words: SAPO-35, Methanol to olefins, SAPO-34, Coke species, Deactivation

LI Bing, TIAN Peng, LI Jinzhe, CHEN Jingrun, YUAN Yangyang, SU Xiong, FAN Dong, WEI Yingxu, QI Yue, LIU Zhongmin. Synthesis of SAPO-35 molecular sieve and its catalytic properties in the methanol-to-olefins reaction[J]. Chinese Journal of Catalysis, 2013, 34(4): 798-807.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60557-9

https://www.cjcatal.com/EN/Y2013/V34/I4/798

References

[1] Lok B M, Messina C A, Patton R L, Gajek R T, Cannan T R, Flanigen E M. US Patent 4 440 871. 1984

[2] Fu Y, Wang L F, Tan Y X, Ji H B. Chem React Eng Technol (付晔, 王乐夫, 谭宇新, 纪红兵. 化学反应工程与工艺), 2000, 16(1): 55

[3] http://www.iza-structure.org/databases/

[4] Zhu Zh D, Hartmann M, Kevan L. Chem Mater, 2000, 12: 2781

[5] Jeon H Y, Shin C H, Jung H J, Hong S B. Appl Catal A, 2006, 305: 70

[6] Djieugoue M A, Prakash A M, Kevan L. J Phys Chem B, 2000, 104: 6452

[7] Venkatathri N, Yoo J W. Appl Catal A, 2008, 340: 265

[8] Cheung O, Liu Q L, Bacsik Z, Hedin N. Microporous Mesoporous Mater, 2012, 156: 90

[9] Falconer J L, Li Sh G, Noble R D. US Patent 20050204916A1. 2005

[10] Liu G Y, Tian P, Liu Zh M. Progr Chem (刘广宇, 田鹏, 刘中民. 化学进展), 2010, 22: 1531

[11] Zhang J Ch, Zhang H B, Yang X Y, Huang Zh, Cao W L. J Nat Gas Chem, 2011, 20: 266

[12] Liu G Y, Tian P, Xia Q H, Liu Zh M. J Nat Gas Chem, 2012, 21: 431

[13] Nawaz S, Kolboe S, Stöcker M. Stud Surf Sci Catal, 1994, 81: 393

[14] Chen J Sh, Wright P A, Thomas J M, Natarajan S, Marchese L, Bradley S M, Sankar G, Catlow C R A, Gai-Boyes P L. J Phys Chem, 1994, 98: 10216

[15] Yuan C Y, Wei Y X, Li J Zh, Xu Sh T, Chen J R, Zhou Y, Wang Q Y, Xu L, Liu Zh M. Chin J Catal (袁翠峪, 魏迎旭, 李金哲, 徐舒涛, 陈景润, 周游, 王全义, 许磊, 刘中民. 催化学报), 2012, 33: 367

[16] Hereijgers B P C, Bleken F, Nilsen M H, Svelle S, Lillerud K P, Bj?rgen M, Weckhuysen B M, Olsbye U. J Catal, 2009, 264: 77

[17] Zhang F M, Kuang X H, Li L Sh, Shu X T, Wang W D, Qin F M (张凤美, 匡晓辉, 李黎声, 舒兴田, 王卫东, 秦凤明), CN Patent 101 397 143. 2009

[18] Guisnet M. J Mol Catal A, 2002, 182-183: 367

[19] Guisnet M, Costa L, Ribeiro F R. J Mol Catal A, 2009, 305: 69

[20] Prakash A M, Hartmann M, Kevan L. Chem Mater, 1998, 10: 932

[21] Zhang D Zh.[PhD Dissertation]. Dalian: Dalian Institute of Chemical Physics, CAS (张大治.[博士学位论文]. 大连: 中国科学院大连化学物理研究所), 2007

[22] Sastre G, Lewis D W, Catlow C R A. J Phys Chem, 1996, 100: 6722

[23] Liu G Y, Tian P, Zhang Y, Li J Zh, Xu L, Meng Sh H, Liu Zh M. Microporous Mesoporous Mater, 2008, 114: 416

[24] Wang J D, Yu X B, Liu Y, Yang Y R. Progr Chem (王靖岱, 虞贤波, 刘烨, 阳永荣. 化学进展), 2009, 21: 1757

[25] Arstad B, Kolboe S. J Am Chem Soc, 2001, 123: 8137

[26] Arstad B, Kolboe S. Catal Lett, 2001, 71: 209

[27] Lesthaeghe D, De Sterck B, Van Speybroeck V, Marin G B, Waroquier M. Angew Chem, Int Ed, 2007, 46: 1311

[28] Wei Y X, Li J Zh, Yuan C Y, Xu Sh T, Zhou Y, Chen J R, Wang Q Y, Zhang Q, Liu Zh M. Chem Commun, 2012, 48: 3082