Palladium supported on an ion exchange resin for the Suzuki-Miyaura reaction

doi:10.1016/S1872-2067(12)60698-6

Abstract

Abstract:

A basic anion exchange resin, Amberlite IRA-900, was loaded with Pd(C₃H₅)(C₅H₅) by an easy metal-organic chemical vapor deposition (MOCVD) approach to give Pd@IRA-900 catalyst after reduction at room temperature. Ultraviolet-Visible spectroscopy results showed a red shift of the absorption peak of Pd²⁺ after the Pd precursor was loaded on the resin, indicating that a chemical reaction occurred between the precursor and the support. Pd nanoparticles with 2.6 nm of average size were well dispersed on the support. The Pd@IRA-900 catalyst showed high activity for different kinds of aryl halides in Suzuki-Miyaura coupling reactions under mild and aerobic conditions. Excellent recyclability of Pd@IRA-900 catalyst was also observed in the Suzuki-Miyaura coupling reaction of iodobenzene and phenylboronic acid. A bifunctional catalyst Pd@IRA-900(OH) was synthesized by pretreating the ion exchange resin support with NaOH before Pd loading, which successfully catalyzed the Suzuki-Miyaura reaction of iodobenzene and phenylboronic acid without base under aerobic conditions.

Key words: Palladium, Anion exchange resin, Metal-organic chemical vapor deposition, Suzuki-Miyaura coupling reaction, Bifunctional catalyst

Mingming Zhang, Manman Jiang, Changhai Liang. Palladium supported on an ion exchange resin for the Suzuki-Miyaura reaction[J]. Chinese Journal of Catalysis, 2013, 34(12): 2161-2166.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60698-6

https://www.cjcatal.com/EN/Y2013/V34/I12/2161

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