Degradation of methylene blue with H2O2 over a cupric oxide nanosheet catalyst

doi:10.1016/S1872-2067(12)60717-7

Chinese Journal of Catalysis ›› 2013, Vol. 34 ›› Issue (11): 2125-2129.DOI: 10.1016/S1872-2067(12)60717-7

• Articles • Previous Articles Next Articles

Degradation of methylene blue with H₂O₂ over a cupric oxide nanosheet catalyst

Maiyong Zhu^a,b, Dehai Meng^a, Chengjiao Wang^a, Jian Di^a, Guowang Diao^a

a College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, Jiangsu, China;
b School of Materials Science & Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China

Received:2013-06-30 Revised:2013-09-16 Online:2013-10-18 Published:2013-10-18
Contact: Guowang Diao
Supported by:
This work was supported by the National Natural Science Foundation of China (20973151, 21273195) and the Foundation of Jiangsu Provincial Key Program of Physical Chemistry in Yangzhou University.

Abstract

Abstract:

Cupric oxide (CuO) nanosheets were prepared by the hydrothermal method with the use of cetyltrimethylammonium bromide (CTAB) and were used as the catalyst for the oxidation degradation of methylene blue with H₂O₂. The effects of temperature, oxidant concentration, and catalyst dosage were evaluated. The catalytic reaction obeyed first order kinetics, and the activation energy was 54 kJ/mol. Although the CuO nanosheets show high activity, their stability and reusability still need improvement.

Key words: Cupric oxide, Nanosheet, Methylene blue, Oxidation degradation

Maiyong Zhu, Dehai Meng, Chengjiao Wang, Jian Di, Guowang Diao. Degradation of methylene blue with H₂O₂ over a cupric oxide nanosheet catalyst[J]. Chinese Journal of Catalysis, 2013, 34(11): 2125-2129.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60717-7

https://www.cjcatal.com/EN/Y2013/V34/I11/2125

References

[1] Zollinger H. Color Chemistry: Synthesis, Properties and Applications of Organic Dyes and Pigments. VCH Publishers, New York, 1991. 379
[2] Morais L C, Freitas O M, Goncalves E P, Vasconcelos L T, Beca G C. Water Res, 1999, 33: 979
[3] Santhy K, Selvapathy P. Bioresour Technol, 2006, 97: 1329
[4] Zhu M Y, Diao G W. J Phys Chem C, 2011, 115: 18923
[5] Zhou L, Gao C, Xu W J. ACS Appl Mater Interfaces, 2010, 2: 1483
[6] Uddin M T, Islam M A, Mahmud S, Rukanuzzaman M. J Hazard Mater, 2009, 164: 53
[7] Francesca P, Sara M, Luigi T. Water Res, 2008, 42: 2953
[8] Zhang Z L, Chen H, Che H W, Wang Y H, Su F B. Mater Chem Phys, 2013, 138: 593
[9] Zhang Z L, Chen H, She X L, Sun J, Teo J, Su F B. J Power Sources, 2012, 217: 336
[10] Choi C S, Park Y U, Kim H, Kim N R, Kang K, Lee H M. Electrochim Acta, 2012, 70: 98
[11] Dubal D P, Gund G S, Holze R, Lokhande C D. J Power Sources, 2013, 242: 687
[12] Sukhorukov Y P, Gizhevskii B A, Mostovshchikova E V, Yermakov A Y, Tugushev S N, Kozlov E A. Tech Phys Lett, 2006, 32: 132
[13] Zhu M Y, Diao G W. Catal Sci Technol, 2012, 2: 82
[14] Zhang Z L, Che H W, Wang Y L, Gao J J, She X L, Sun J, Zhong Z Y, Su B. RSC Adv, 2012, 2: 2254
[15] Sun S D, Zhang X Z, Sun Y X, Yang S C, Song X P, Yang Z M. ACS Appl Mater Interfaces, 2013, 5: 4429
[16] Sun S D, Zhang X Z, Sun Y X, Yang S C, Song X P, Yang Z M. Phys Chem Chem Phys, 2013, 15: 10904
[17] Hong L, Liu A L, Li G W, Chen W, Lin X H. Biosens Bioelectron, 2013, 43: 1
[18] Zhu J, Qian X F. J Solid State Chem, 2010, 183: 1632
[19] Reddy K J, McDonald K J, King H. J Colloid Interface Sci, 2013, 397: 96
[20] Martinson C A, Reddy K J. J Colloid Interface Sci, 2009, 336: 406
[21] Meshram S P, Adhyapak P V, Mulik U P, Amalnerka, D P. Chem Eng J, 2012, 204-206: 158
[22] Hong J M, Li J, Ni Y H. J. Alloys Compounds, 2009, 481: 610

Degradation of methylene blue with H₂O₂ over a cupric oxide nanosheet catalyst

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Cheng Liu, Mengning Chen, Yingzhang Shi, Zhiwen Wang, Wei Guo, Sen Lin, Jinhong Bi, Ling Wu. Ultrathin ZnTi-LDH nanosheet: A bifunctional Lewis and Brönsted acid photocatalyst for synthesis of N-benzylideneanilline via a tandem reaction [J]. Chinese Journal of Catalysis, 2023, 49(6): 102-112.
[2]	Kehan Zhu, Haifeng Jiang, Gao-Feng Chen, Hao Wu, Liang-Xin Ding, Haihui Wang. Simultaneous electrosynthesis of nitrate and hydrogen by integrating ammonia oxidation and water reduction [J]. Chinese Journal of Catalysis, 2023, 55(12): 216-226.
[3]	Linfeng Xie, Xuan Liu, Fanyang Huang, Jiashun Liang, Jianyun Liu, Tanyuan Wang, Liming Yang, Ruiguo Cao, Qing Li. Regulating Pd-catalysis for electrocatalytic CO₂ reduction to formate via intermetallic PdBi nanosheets [J]. Chinese Journal of Catalysis, 2022, 43(7): 1680-1686.
[4]	Xiu Qian, Yanjiao Wei, Mengjie Sun, Ye Han, Xiaoli Zhang, Jian Tian, Minhua Shao. Heterostructuring 2D TiO₂ nanosheets in situ grown on Ti₃C₂T_x MXene to improve the electrocatalytic nitrogen reduction [J]. Chinese Journal of Catalysis, 2022, 43(7): 1937-1944.
[5]	Zhenlong Zhao, Ji Bian, Lina Zhao, Hongjun Wu, Shuai Xu, Lei Sun, Zhijun Li, Ziqing Zhang, Liqiang Jing. Construction of 2D Zn-MOF/BiVO₄ S-scheme heterojunction for efficient photocatalytic CO₂ conversion under visible light irradiation [J]. Chinese Journal of Catalysis, 2022, 43(5): 1331-1340.
[6]	Wei Xiong, Min Zhou, Hao Li, Zhao Ding, Da Zhang, Yaokang Lv. Electrocatalytic ammonia synthesis catalyzed by mesoporous nickel oxide nanosheets loaded with Pt nanoparticles [J]. Chinese Journal of Catalysis, 2022, 43(5): 1371-1378.
[7]	Shi-Qun Cheng, Xue-Fei Weng, Qing-Nan Wang, Bai-Chuan Zhou, Wen-Cui Li, Ming-Run Li, Lei He, Dong-Qi Wang, An-Hui Lu. Defect-rich BN-supported Cu with superior dispersion for ethanol conversion to aldehyde and hydrogen [J]. Chinese Journal of Catalysis, 2022, 43(4): 1092-1100.
[8]	Jing-Yu Li, Ming-Yu Qi, Yi-Jun Xu. Efficient splitting of alcohols into hydrogen and C-C coupled products over ultrathin Ni-doped ZnIn₂S₄ nanosheet photocatalyst [J]. Chinese Journal of Catalysis, 2022, 43(4): 1084-1091.
[9]	Junxian Bai, Rongchen Shen, Zhimin Jiang, Peng Zhang, Youji Li, Xin Li. Integration of 2D layered CdS/WO₃ S-scheme heterojunctions and metallic Ti₃C₂ MXene-based Ohmic junctions for effective photocatalytic H₂ generation [J]. Chinese Journal of Catalysis, 2022, 43(2): 359-369.
[10]	Sunhong Ruan, Biao Zhang, Jinhan Zou, Wanfu Zhong, Xiaoyang He, Jinhai Lu, Qinghong Zhang, Ye Wang, Shunji Xie. Bismuth nanosheets with rich grain boundaries for efficient electroreduction of CO₂ to formate under high pressures [J]. Chinese Journal of Catalysis, 2022, 43(12): 3161-3169.
[11]	Jiandong Wu, Xiao Zhao, Xiaoqiang Cui, Weitao Zheng. Emerging two-dimensional metallenes: Recent advances in structural regulations and electrocatalytic applications [J]. Chinese Journal of Catalysis, 2022, 43(11): 2802-2814.
[12]	Xueyou Gao, Deqian Zeng, Jingren Yang, Wee-Jun Ong, Toyohisa Fujita, Xianglong He, Jieqian Liu, Yuezhou Wei. Ultrathin Ni(OH)₂ nanosheets decorated with Zn_0.5Cd_0.5S nanoparticles as 2D/0D heterojunctions for highly enhanced visible light-driven photocatalytic hydrogen evolution [J]. Chinese Journal of Catalysis, 2021, 42(7): 1137-1146.
[13]	Jinxiu Zhao, Xiang Ren, Xu Sun, Yong Zhang, Qin Wei, Xuejing Liu, Dan Wu. In situ evolution of surface Co₂CrO₄ to CoOOH/CrOOH by electrochemical method: Toward boosting electrocatalytic water oxidation [J]. Chinese Journal of Catalysis, 2021, 42(7): 1096-1101.
[14]	Chao Wang, Wei Jiang, Hanxiang Chen, Linhua Zhu, Jing Luo, Wenshu Yang, Guangying Chen, Zhigang Chen, Wenshuai Zhu, Huaming Li. Pt nanoparticles encapsulated on V₂O₅ nanosheets carriers as efficient catalysts for promoted aerobic oxidative desulfurization performance [J]. Chinese Journal of Catalysis, 2021, 42(4): 557-562.
[15]	Qian Wu, Qingping Gao, Limei Sun, Huanmei Guo, Xishi Tai, Dan Li, Li Liu, Chongyi Ling, Xuping Sun. Facilitating active species by decorating CeO₂ on Ni₃S₂ nanosheets for efficient water oxidation electrocatalysis [J]. Chinese Journal of Catalysis, 2021, 42(3): 482-489.