Electrocatalytic measurement of H2O2 concentration using bis(N-2-methylphenyl-salicyldenaminato)copper(Ⅱ) spiked in a carbon paste electrode

doi:10.1016/S1872-2067(12)60753-0

Abstract

Abstract:

The electrochemical behavior of a bis(N-2-methylphenyl-salicyldenaminato)copper(Ⅱ) complex spiked in a carbon paste electrode (BMPSCu-CPE) and its electrocatalytic reduction of H₂O₂ were examined using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry. Cyclic voltammetry was used to study the redox properties of BMPSCu-CPE at various potential scan rates. The apparent charge transfer rate constant and the transfer coefficient for the electron transfer between BMPSCu and the carbon paste electrode (CPE) were 1.9±0.1 s^-1 and 0.43, respectively. BMPSCu-CPE had excellent electrocatalytic activity for H₂O₂ reduction in 0.1 mol/L phosphate buffer solution (pH 5.0), and it decreased the overpotential by 300 mV as compared to CPE alone. The diffusion coefficient and kinetic parameters such as the heterogeneous catalytic electron transfer rate constant and electron transfer coefficient for the reduction of H₂O₂ at the BMPSCu-CPE surface were also determined using electrochemical methods. Differential pulse voltammetry showed two linear dynamic ranges of 1.0-10.0 and 10.0-300.0 μmol/L and a detection limit of 0.63 μmol/L H₂O₂. The BMPSCu-CPE has excellent reproducibility and long term stability, and it was successfully applied for the determination of H₂O₂ in two pharmaceutical samples: an antiseptic solution and a hair dying cream.

Key words: Electrochemical behavior, Bis(N-2-methylphenyl-salicyldenaminato)copper(Ⅱ), complex, Hydrogen peroxides, Electrocatalytic reduction

Hossein Khoshro, Hamid R. Zare, Rasoul Vafazadeh. Electrocatalytic measurement of H₂O₂ concentration using bis(N-2-methylphenyl-salicyldenaminato)copper(Ⅱ) spiked in a carbon paste electrode[J]. Chinese Journal of Catalysis, 2014, 35(2): 247-254.

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Electrocatalytic measurement of H₂O₂ concentration using bis(N-2-methylphenyl-salicyldenaminato)copper(Ⅱ) spiked in a carbon paste electrode

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