Chitosan- supported cinchonine as an efficient organocatalyst for direct asymmetric aldol reaction in water

doi:10.1016/S1872-2067(14)60248-5

Abstract

Abstract:

Chitosan-supported succinic anhydride-cinchonine (CTS-SA-CN) was synthesized via a two-step route with succinic anhydride as the linker. The catalyst was used to promote the direct asymmetric aldol reaction between cyclohexanone and a variety of aromatic aldehydes in aqueous medium. Aldol adducts were obtained in excellent yields (up to 99%) and good enantioselectivities (up to 96% ee). The CTS-SA-CN catalyst was successfully recycled simply by filtration after use, and was reused 5 times without any significant loss of activity.

Key words: Chitosan, Cinchonine, Supported catalyst, Direct asymmetric aldol reaction

Wenshan Zhao, Chengke Qu, Lili Yang, Yuanchen Cui. Chitosan- supported cinchonine as an efficient organocatalyst for direct asymmetric aldol reaction in water[J]. Chinese Journal of Catalysis, 2015, 36(3): 367-371.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60248-5

https://www.cjcatal.com/EN/Y2015/V36/I3/367

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