Bismuth triflate: A highly efficient catalyst for the synthesis of bio-active coumarin compounds via one-pot multi-componentreaction

doi:10.1016/S1872-2067(14)60308-9

Abstract

Abstract:

A series of coumarin-chalcone hybrid compounds and coumarins linked to pyrazoline was synthesized in good yield and short time using a simple and efficient method. This method involved the one-pot reaction of salicylaldehyde, an α-ketoester and an aromatic aldehyde (in the case of the coumarin-chalcone derivatives) in addition to hydrazine hydrate (in the case of the pyrazolyl coumarins) in the presence of a catalytic amount of bismuth triflate [Bi(OTf)₃, 5 mol%]. The synthesized compounds showed scavenging activity towards the free radical 2,2-diphenyl-1-picrylhydrazyl. All compounds were characterized using IR, ¹H NMR and ¹³C NMR spectroscopy.

Key words: Coumarin, Chalcone, Pyrazoline, One-pot multi-component reaction, Salicylaldehyde, α-Ketoester, Bismuth triflate [Bi(OTf)₃]

Mahmoud. Abd, El Aleem. Ali, Ali. El-Remaily. Bismuth triflate: A highly efficient catalyst for the synthesis of bio-active coumarin compounds via one-pot multi-componentreaction[J]. Chinese Journal of Catalysis, 2015, 36(7): 1124-1130.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60308-9

https://www.cjcatal.com/EN/Y2015/V36/I7/1124

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