Nano-sized silica supported FeCl3 as an efficient heterogeneous catalyst for the synthesis of 1, 2, 4-triazine derivatives

doi:10.1016/S1872-2067(15)60829-4

Chinese Journal of Catalysis ›› 2015, Vol. 36 ›› Issue (4): 620-625.DOI: 10.1016/S1872-2067(15)60829-4

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Nano-sized silica supported FeCl₃ as an efficient heterogeneous catalyst for the synthesis of 1, 2, 4-triazine derivatives

Davood Habibi, Somayyeh Vakili

Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, 6517838683, Hamedan, Iran

Received:2014-09-21 Revised:2014-12-19 Online:2015-03-23 Published:2015-03-23

Abstract

Abstract:

The one-pot synthesis of a series of 1,2,4-triazines from the reactions of semicarbazide or thiosemicarbazide with various α,β-dicarbonyl compounds under reflux conditions in a EtOH-H₂O (9:1) mixture as solvent and catalyzed by nano-sized silica supported FeCl₃ (FeCl₃@SiO₂) was investigated. The FeCl₃ content of the catalyst was measured by atomic absorption to get the adsorption capacity. The reactions gave high yields of the product and the catalyst was easily separated and reused for successive reaction runs without significant loss of activity.

Key words: Nano-sized silica supported FeCl₃, Multicomponent reactions, 1,2,4-Triazines, α,β-Dicarbonyl compounds, Semicarbazide, Thiosemicarbazide

Davood Habibi, Somayyeh Vakili. Nano-sized silica supported FeCl₃ as an efficient heterogeneous catalyst for the synthesis of 1, 2, 4-triazine derivatives[J]. Chinese Journal of Catalysis, 2015, 36(4): 620-625.

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Nano-sized silica supported FeCl₃ as an efficient heterogeneous catalyst for the synthesis of 1, 2, 4-triazine derivatives

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