Photocatalytic degradation of 2,4-dichlorophenol with V2O5-TiO2 catalysts: Effect of catalyst support and surfactant additives

doi:10.1016/S1872-2067(15)61035-X

Abstract

Abstract:

Binary oxide catalysts with various weight percentage V₂O₅ loadings were prepared by solid-state dispersion and the nanocomposites were modified with surfactants. The catalysts were analyzed using X-ray diffraction, diffuse-reflectance spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, and N₂ adsorption-desorption. The photocatalytic activities of the catalysts were evaluated in the degradation of 2,4-dichlorophenol under ultraviolet irradiation. The photocatalytic activity of 50 wt% V₂O₅-TiO₂ (50V₂O₅-TiO₂) was higher than those of pure V₂O₅, TiO₂, and P25. Interactions between V₂O₅ and TiO₂ affected the photocatalytic efficiencies of the binary oxide catalysts. Cetyltrimethylammonium bromide (CTAB) and hexadecyltrimethylammonium bromide (HTAB) significantly enhanced the efficiency of the 50V₂O₅-TiO₂ catalyst. The highest percentage of 2,4-dichlorophenol degradation (100%) and highest reaction rate (2.22 mg/(L·min)) were obtained in 30 min with the (50V₂O₅-TiO₂)-CTAB catalyst. It is concluded that the addition of a surfactant to the binary oxide significantly enhanced the photocatalytic activity by modifying the optical and electronic properties of V₂O₅ and TiO₂.

Key words: 2,4-Dichlorophenol, Degradation, Photocatalysis, Surfactant, Binary oxide, Characterization

Eda Sinirtas, Meltem Isleyen, Gulin Selda Pozan Soylu. Photocatalytic degradation of 2,4-dichlorophenol with V₂O₅-TiO₂ catalysts: Effect of catalyst support and surfactant additives[J]. Chinese Journal of Catalysis, 2016, 37(4): 607-615.

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Photocatalytic degradation of 2,4-dichlorophenol with V₂O₅-TiO₂ catalysts: Effect of catalyst support and surfactant additives

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