Advances in polymer-stabilized Au nano-cluster catalysis: Interplay of theoretical calculations and experiments

doi:10.1016/S1872-2067(16)62463-4

Abstract

Abstract:

Polymer-stabilized Au nano clusters (NCs) with mean diameters of 2-10 nm exhibit unique catalytic properties. Several studies have shown that the key factors affecting the catalytic activity of polymer-stabilized Au NCs are control of the Au NC size, appropriate selection of polymers and optimization of the reaction conditions. This is because polymer-stabilized Au NCs exhibit a clear size effect in several catalytic reactions, and the catalytic activity differs with the type of polymer used and the reaction conditions. In order to elucidate the reason underlying the catalytic activity of the polymer-stabilized Au NCs, much attention is being devoted to the interplay of theoretical calculations and experiments in catalysis by polymer stabilized Au NCs. The present article mainly summarizes our progress in understanding this interplay in polymer-stabilized Au NC catalysis.

Key words: Polymer-stabilized Au nano-cluster, Aerobic oxidation of alcohols, Interplay of theoretical calculations and experiments, Size effect of Au nano-cluster, Role of the polymers

Hiroaki Koga, Kohei Sakata, Yoshinori Ato, Akihide Hayashi, Kohei Tada, Mitsutaka Okumur. Advances in polymer-stabilized Au nano-cluster catalysis: Interplay of theoretical calculations and experiments[J]. Chinese Journal of Catalysis, 2016, 37(10): 1588-1593.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62463-4

https://www.cjcatal.com/EN/Y2016/V37/I10/1588

References

[1] M. Haruta, T. Kobayashi, H. Sano, N. Yamada, Chem. Lett., 1987, 405-408.
[2] M. Haruta, N. Yamada, T. Kobayashi, S. Iijima, J. Catal., 1989, 115, 301-309.
[3] G. J. Hutchings, J. Catal., 1985, 96, 292-295.
[4] B. Nkosi, J. Coville, G. J. Hutchings, Appl. Catal., 1988, 43, 33-39.
[5] T. Takei, T. Akita, I. Nakamura, T. Fujitani, M. Okumura, K. Okazaki, J. Huang, T. Ishida, M. Hruta, Adv. Catal., 2012, 55, 1-126.
[6] M. Comotti, C. Della Pina, R. Matarrese, M. Rossi, Angew. Chem. Int. Ed. 2004, 43, 5812-5815.
[7] T. Yonezawa, N. Toshima, in:Advanced Functional Molecules and Polymers, H. S. Nalwa Ed., OPA, Amsterdam, 2001, 2, 65-86.
[8] H. Tsunoyama, H. Sakurai, T. Tsukuda, Chem. Phys. Lett., 2006, 429, 528-532.
[9] H. Tsunoyama, N. Ichikuni, H. Sakurai, T. Tsukuda, J. Am. Chem. Soc., 2009, 131, 7086-7093.
[10] N. Toshima, M. Kuriyama, Y. Yamada, H. Hirai, Chem. Lett., 1981, 793-796.
[11] T. Teranishi, M. Hosoe, M. Miyake, Adv. Mater., 1997, 9, 65-67.
[12] T. Teranishi, M. Miyake, Chem. Mater., 1998, 10, 594-600.
[13] N. Toshima, in:Nanoscale Materials, L. M. Liz-Marzän, P. V. Kamat Eds., Kluwer Academic Publishers, Norwell, MA, 2003, 79-96.
[14] R. Narayanan, M. A. El-Sayed, J. Phys. Chem. B, 2005, 109, 12663-12676.
[15] Y. W. Zhang, M. E. Grass, J. N. Kuhn, F. Tao, S. E. Habas, W. Y. Huang, P. D. Yang, G. A. Somorjai, J. Am. Chem. Soc., 2008, 130, 5868-5869.
[16] H. Tsunoyama, H. Sakurai, N. Ichikuni, Y. Negishi, T. Tsukuda, Langmuir, 2004, 20, 11293-11296.
[17] H. Tsunoyama, N. Ichikuni, T. Tsukuda, Langmuir, 2008, 24, 11327-11330.
[18] H. Tsunoyama, H. Sakurai, Y. Negishi, T. Tsukuda, J. Am. Chem. Soc., 2005, 127, 9374-9375.
[19] H. Tsunoyama, N. Ichikuni, H. Sakurai, T. Tsukuda, J. Am. Chem. Soc., 2009, 131, 7086-7093.
[20] S. S. Stahl, Angew. Chem. Int. Ed., 2004, 43, 3400-3420.
[21] T. Mallat, A. Baiker, Chem. Rev., 2004, 104, 3037-3058.
[22] Y. Uozumi, R. Nakao, Angew. Chem. Int. Ed., 2003, 42, 194-197.
[23] Y. M. A. Yamada, T. Arakawa, H. Hocke, Y. Uozumi, Angew. Chem. Int. Ed., 2007, 46, 704-706.
[24] T. Wang, H. Shou, Y. Kou, H. C. Liu, Green Chem., 2009, 11,562-568.
[25] T. Ishida, J. Aimoto, A. Hamasaki, H. Ohashi, T. Honma, T. Yokoyama, K. Sakata, M. Okumura, M. Tokunaga, Chem. Lett., 2014, 43, 1368-1370.
[26] K. Sakata, H. Koga, T. Ishida, J. Aimoto, M. Tokunaga, M. Oku-mura, Gold Bull, 2015, 48, 31-37.
[27] M. Okumura, Y. Kitagawa, T. Kawakami, M. Haruta, Chem. Phys. Lett., 2008, 459, 133-136.
[28] N. K. Chaki, H. Tsunoyama, Y. Negishi, H. Sakurai, T. Tsukuda, J. Phys. Chem. C, 2007, 111, 4885-4888.
[29] M. Okumura, M. Haruta, Y. Kitagawa, K. Yamaguchi, Gold Bull., 2007, 40, 40-44.
[30] K. Sakata, K. Tada, S. Yamada, Y. Kitagawa, T. Kawakami, S. Yama-naka, M. Okumura, Mol. Phys., 2014, 112, 385-392.
[31] S. Karanjit, K. Bobuatong, R. Fukuda, M. Ehara, H. Sakurai, Int. J. Quant. Chem., 2013, 113, 428-436.
[32] K. Bobuatong, S Kranjit, R. Fukuda, M. Ehara, H. Sakurai, Phys. Chem. Chem. Phys., 2012, 14, 3103-3111.
[33] M. Okumura, S. Tsubota, M. Haruta, J. Mol. Catal. A, 2003, 199, 73-84.
[34] M. Okumura, S. Nakamura, S. Tsubota, T. Nakamura, M. Azuma, M. Haruta, Catal. Lett., 1998, 51, 53-58.
[35] K. Sakata, Y. Ato, K. Tada, H. koga, S. Yamanaka, T. Kawakami, T. Saito, M. Okumura, Chem. Lett., 2016, 45, 344-346.
[36] D. Widmann, R. J. Behm, Angew. Chem. Int. Ed., 2011, 50, 10241-10245.
[37] M. Farnesi Camellone, P. M. Kowalski, D. Marx, Phys. Rev. B, 2011, 84, 035413/1-035413/18.
[38] H. J. Zhang, N. Toshima, Catal. Sci. Technol., 2013, 3, 268-278.
[39] H. J. Zhang, M. Okumura, N. Toshima, J. Phys. Chem. C, 2011, 115, 14883-14891.
[40] H. J. Zhang, M. Haba, M. Okumura, T. Akita, S. Hashimoto, N. To-shima, Langmuir, 2013, 29, 10330-10339.
[41] H. J. Zhang, J. Okuni, N. Toshima, J. Colloid Interface Sci., 2011, 354, 131-138.
[42] T. Ishida, N. Kinoshita, H. Okatsu, T. Akita, T. Takei, M. Haruta, Angew. Chem. Int. Ed., 2008, 47, 9265-9268.
[43] H. J. Zhang, N. Toshima, K. Takasaki, M. Okumura, J. Alloy Compd., 2014, 586, 462-468.
[44] H. J. Zhang, T. Watanabe, M. Okumura, M. Haruta, N. Toshima, Nat. Mater., 2012, 11, 49-52.
[45] H. J. Zhang, T. Watanabe, M. Okumura, M. Haruta, N. Toshima, J. Catal., 2013, 305, 7-18.
[46] H. J. Zhang, K. Kawashima, M. Okumura, N. Toshima, J. Mater. Chem. A, 2014, 2, 13498-13508.
[47] H. Tsunoyama, H. Sakurai, N. Ichikuni, Y. Negishi, T. Tsukuda, Langmuir, 2004, 20, 11293-11296.
[48] H. Sakurai, H. Tsunoyama, T. Tsukuda, Trans. Mater. Res. Soc. Jpn., 2006, 31, 521-524.
[49] I. Kamiya, H. Tsunoyama, T. Tsukuda, H. Sakurai, Chem. Lett., 2007, 36, 646-647.
[50] H. Sakurai, I. Kamiya, H. Kitahara, H. Tsunoyama, T. Tsukuda, Synlett., 2009, 245-248.
[51] R. N. Dhital, C. Kamonsatikul, E. Somsook, K. Bobuatong, M. Ehara, S. Karanjit, H. Sakurai, J. Am. Chem. Soc., 2012, 134, 20250-20253.
[52] B. Boekfa, E. Pahl, N. Gaston, H. Sakurai, J. Limtrakul, M. Ehara, J. Phys. Chem. C, 2014, 118, 22188-22196.