A shaped binderless ZSM-11 zeolite catalyst for direct amination of isobutene to tert-butylamine

doi:10.1016/S1872-2067(17)62756-6

Chinese Journal of Catalysis ›› 2017, Vol. 38 ›› Issue (1): 168-175.DOI: 10.1016/S1872-2067(17)62756-6

A shaped binderless ZSM-11 zeolite catalyst for direct amination of isobutene to tert-butylamine

Wanshuo Zhang^a,b, Shangyao Gao^b,c, Sujuan Xie^b, Hui Liu^b,d, Xiangxue Zhu^b, Yongchen Shang^a, Shenglin Liu^b, Longya Xu^b, Ye Zhang^e

a College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, Heilongjiang, China;
b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
c University of Chinese Academy of Sciences, Beijing 100049, China;
d Research and Development Center, Sinochem Quanzhou Petrochemical Co., Ltd., Quanzhou 362103, Fujian, China;
e PetroChina Fushun Petrochemical Company, Fushun 113008, Liaoning, China

Received:2016-10-20 Revised:2016-11-22 Online:2017-01-18 Published:2017-01-18
Contact: Yongchen Shang,Tel:+86-13936570503;E-mail:yongchenshang@163.com;Shenglin Liu,Tel:+86-411-84379968;E-mail:slliu@dicp.ac.cn
Supported by:
This work was supported by K.C.Wong Education Foundation, Hong Kong (201611), and Youth Innovation Promotion Association, CAS (20120155).

Abstract

Abstract:

A shaped binderless and two binder-containing ZSM-11 zeolite catalysts were prepared and char-acterized by powder X-ray diffraction, N₂ adsorption-desorption, and pyridine adsorption-infrared measurements. The binderless catalyst was synthesized using a dry-gel conversion technique, in which 1,6-hexanediamine and tetrabutylammonium bromide were used as structure-directing agents and no other alkaline materials were added. The catalytic performance of the zeolites in the direct amination of isobutene to tert-butylamine was evaluated in a fixed-bed reactor. By virtue of its high crystallinity as well as its good mechanical strength, the shaped binderless ZSM-11 catalyst showed a higher rate of formation of tert-butylamine than did the binder-containing catalysts.

Key words: Binderless zeolite, ZSM-11, Amination, Isobutene, Tert-butylamine

Wanshuo Zhang, Shangyao Gao, Sujuan Xie, Hui Liu, Xiangxue Zhu, Yongchen Shang, Shenglin Liu, Longya Xu, Ye Zhang. A shaped binderless ZSM-11 zeolite catalyst for direct amination of isobutene to tert-butylamine[J]. Chinese Journal of Catalysis, 2017, 38(1): 168-175.

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A shaped binderless ZSM-11 zeolite catalyst for direct amination of isobutene to tert-butylamine

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