Environmentally benign and economic synthesis of covalent triazine-based frameworks

doi:10.1016/S1872-2067(17)62771-2

Abstract

Abstract:

Covalent triazine-based frameworks (CTFs) are important microporous materials with a wide range of applications. Here, we demonstrate an environmentally benign and economic synthetic pathway to CTFs. The monomers used for CTFs, aromatic nitriles, were obtained by cyanation using nontoxic potassium hexacyanoferrate(II) in place of commonly used toxic cyanides. Then, the CTFs were synthesized by trimerization of the corresponding cyano monomers in molten zinc chloride. A series of CTFs was synthesized, and the highest Brunauer-Emmett-Teller surface area measured in this series was 2404 m²/g. Among the synthesized CTFs, CTF_DCP exhibited excellent CO₂ adsorption properties, with a CO₂ uptake of 225 mg/g at 0℃.

Key words: Covalent triazine-based framework, Aryl bromide, Cyanation, Potassium hexacyanoferrate(II), Palladium acetate

Ling Zhang, Xue Liu, Rui-Xia Yang, Nian-Yu Huang, Wei-Qiao Deng. Environmentally benign and economic synthesis of covalent triazine-based frameworks[J]. Chinese Journal of Catalysis, 2017, 38(3): 583-588.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62771-2

https://www.cjcatal.com/EN/Y2017/V38/I3/583

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