Chinese Journal of Catalysis ›› 2018, Vol. 39 ›› Issue (12): 1910-1918.DOI: 10.1016/S1872-2067(18)63140-7

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Fabrication of Bi2WO6 quantum dots/ultrathin nanosheets 0D/2D homojunctions with enhanced photocatalytic activity under visible light irradiation

Jingjing Xua, Junpeng Yuea, Junfeng Niub, Mindong Chena, Fei Tenga   

  1. a Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, School of Environmental Science and Engineering, Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials, Nanjing University of Information Science and Technology, Nanjing 210044, Jiangsu, China;
    b Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan 523808, Guangdong, China
  • Received:2018-05-24 Revised:2018-07-06 Online:2018-12-18 Published:2018-09-26
  • Contact: 10.1016/S1872-2067(18)63140-7
  • Supported by:

    This work was supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Abstract:

A novel visible light-responsive homogeneous catalyst based on Bi2WO6 quantum dots (QDs-BWO)/Bi2WO6 nanosheets (N-BWO) was successfully fabricated through a simple hydrothermal method. A variety of techniques were employed to investigate the morphology, structure, and electronic properties of the samples. The photocatalytic performance of the QDs/N-BWO materials was investigated by monitoring the degradation of 4-chlorophenol and rhodamine B under visible light irradiation. The as-fabricated QDs/N-BWO materials showed higher photocatalytic activity than both QDs-BWO and N-BWO. The results reveal that the incorporation of the QDs improved the separation efficiency of electron-hole pairs, leading to enhanced photocatalytic activity. Moreover, the results of quenching experiments show that·O2- species played a major role in the degradation process. This work provides an important reference for the fabrication of homogeneous catalysts with high performance in the degradation of different types of pollutants.

Key words: Bi2WO6, Quantum dots, Nanosheet, Photocatalysis, Homojunction