Relationship between oxygen species and activity/stability in heteroatom (Zr, Y)-doped cerium-based catalysts for catalytic decomposition of CH3SH

doi:10.1016/S1872-2067(18)63146-8

Abstract

Abstract:

CeO₂,Ce_1-xZr_xO₂, and Ce_1-xY_xO_2-δ(x=0.25, 0.50, 0.75, and 1.00) have been rapidly synthesized to estimate their catalytic behavior in decomposing CH₃SH. The role of oxygen vacancies, and the relationship between the oxygen species and catalytic properties of CeO₂ andZr-doped and Y-doped ceria-based materials are investigated in detail. Combining the observed catalytic performance with the characterization results, it can be deemed that surface lattice oxygenplays a critical role in methanethiol catalytic conversion over cerium oxides. Ce_0.75Zr_0.25O₂ shows higher catalytic activity for CH₃SH decomposition due to the large amount of surface lattice oxygen,readily available oxygen species, and excellent redox properties. Ce_0.75Y_0.25O_2-δ displays better catalytic stability owing to the greater number of oxygen vacancies that would promote bulk lattice oxygen migration to the surface of the catalyst in order to replenish surface lattice oxygen. In addition, the results show that the difference in chemical valence between Ce and the heteroatoms would strongly influence the amount of surface lattice oxygen as well as the mobility of bulk-phase oxygen in these catalysts, thus affecting their activity and stability.

Key words: Cerium-base catalyst, Heteroatom, Surface lattice oxygen, CH₃SH decomposition, Bulk oxygen migration

Dingkai Chen, Dehua Zhang, Dedong He, Jichang Lu, Liping Zhong, Caiyun Han, Yongming Luo. Relationship between oxygen species and activity/stability in heteroatom (Zr, Y)-doped cerium-based catalysts for catalytic decomposition of CH₃SH[J]. Chinese Journal of Catalysis, 2018, 39(12): 1929-1941.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(18)63146-8

https://www.cjcatal.com/EN/Y2018/V39/I12/1929

References

[1] L. Zhang, Y. X. Peng, J. Zhang, L. Chen, X. J. Meng, F. S. Xiao, Chin. J. Catal., 2016, 37, 800-809.
[2] W. M. Cai, G. H. Lu, J. He, Y. Lan, Ceram. Int., 2012, 38, 3167-3174.
[3] V. Hulea, E. Huguet, C. Cammarano, A. Lacarriere, R. Durand, C. Leroi, R. Cadours, B. Coq, Appl. Catal. B, 2014, 144, 547-553.
[4] S. Z. Zhao, H. H. Yi, X. L. Tang, F. Y. Gao, B. Zhang, Z. X. Wang, Y. R. Zuo, J. Cleaner. Prod., 2015, 87, 856-86.
[5] A. Bagreev, J. A. Menendez, I. Dukhno, Y. Tarasenko, T. J. Bandosz, Carbon, 2005, 43, 208-210.
[6] S. Bashkova, A. Bagreev, T. J. Bandosz, Catal. Today, 2005, 99, 323-328.
[7] I. A. A. C. Esteves, M. S. S. Lopes, P. M. C. Nunes, J. P. B. Mota, Separ. Purif. Technol., 2008, 62, 281-296.
[8] J. C. Lu, H. S. Hao, L. M. Zhang, Z. Z. Xu, L. P. Zhong, Y. T. Zhao, D. D. He, J. P. Liu, D. K. Chen, H. P. Pu, S. F. He, Y. M. Luo, Appl. Catal. B, 2018, 237, 185-197.
[9] E. Huguet, B. Coq, R. Durand, C. Leroi, R. Cadours, V. Hulea, Appl. Catal. B, 2013, 134-135, 344-348.
[10] L. Altas, H. Büyükgüngör, J. Hazard Mater., 2008, 153, 462-469.
[11] A. Ryzhikov, V. Hulea, D. Tichit, C. Leroi, D. Anglerot, B. Coq, P. Trens, Appl. Catal. A, 2011, 397, 218-224.
[12] M. G. Conti-Ramsden, K. Nkrumah-Amoako, N. W. Brown, E. P. L. Roberts, Adsorption, 2013, 19, 989-996.
[13] M. Mirzaeian, A. M. Rashidi, M. Zare, R. Ghabezi, R. Lotfi, J. Nat. Gas Sci. Eng., 2014, 18, 439-445.
[14] J. Y. Liu, M. Zhao, C. H. Xu, S. Y. Liu, X. Q. Zhang, Y. Q. Chen, Chin. J. Catal., 2013, 34, 751-757.
[15] E. Aneggi, V. Cabbai, A. Trovarelli, D. Goi, Int. J. Photoenergy, 2012, 2012, 694721.
[16] Y. N. Zheng, K. Z. Li, H. Wang, X. Zhu, Y. G. Wei, M. Zheng, Y. H. Wang, Energy Fuels, 2016, 30, 638-647.
[17] D. Pakhare, J. Spivey, Chem. Soc. Rev., 2014, 43, 7813-7837.
[18] B. C. H. Steele, A. Heinzel, Nature, 2001, 414, 345-352.
[19] Q. Fu, H. Saltsburg, M. Flytzani-Stephanopoulos, Science, 2003, 301, 935-938.
[20] C. Wen, Y. Zhu, Y. Ye, S. Zhang, F. Cheng, Y. Liu, P. Wang, F. Tao, ACS Nano, 2012, 6, 9305-9313.
[21] X. X. Dai, W. Y. Jiang, W. L. Wang, X. L. Weng, Y. Shang, Y. H. Xue, Z. B. Wu, Chin. J. Catal., 2018, 39, 728-735.
[22] U. Menon, H. Poelman, V. Bliznuk, V. V. Galvita, D. Poelman, G. B. Marine, J. Catal., 2012, 295, 91-103.
[23] B. F. Jin, Y. C. Wei, Z. Zhao, J. Liu, Y. Z. Li, R. J. Li, A. J. Duan, G. Y. Jiang, Chin. J. Catal., 2017, 38, 1629-1641.
[24] D. K. Chen, D. D. He, J. C. Lu, L. P. Zhong, F. Liu, J. P. Liu, J. Yu, G. P. Wan, S. F. He, Y. M. Luo, Appl. Catal. B, 2017, 218, 249-259.
[25] H. D. Xu, Z. T. Fang, Y. Cao, S. Kong, Lin Tao, M. C. Gong, Y. Q. Chen, Chin. J. Catal., 2012, 33, 1927-1937.
[26] N. Laosiripojana, S. Assabumrungrat, Appl. Catal. B, 2011, 102, 267-275.
[27] M. Flytzani-Stephanopoulos, M. Sakbodin, Z. Wang, Science, 2006, 312, 1508-1510.
[28] D. D. He, G. P. Wan, H. S. Hao, D. K. Chen, J. C. Lu, L. Zhang, F. Liu, L. P. Zhong, S. F. He, Y. M. Luo, Chem. Eng. J., 2016, 289, 161-169.
[29] D. D. He, H. S. Hao, D. K. Chen, J. C. Lu, L. P. Zhong, R. Chen, F. Liu, G. P. Wan, S. F. He, Y. M. Luo, J. Environ. Chem. Eng., 2016, 4, 311-318.
[30] D. D. He, H. S. Hao, D. K. Chen, J. P. Liu, J. Yu, J. C. Lu, F. Liu, G. P. Wan, S. F. He, Y. M. Luo, Catal. Today, 2017, 281, 559-565.
[31] D. D. He, D. K. Chen, H. S. Hao, J. Yu, J. P. Liu, J. C. Lu, F. Liu, G. P. Wan, S. F. He, Y. M. Luo, Appl. Surf. Sci., 2016, 390, 959-967.
[32] R. Di Monte, J. Kaspar, J. Mater. Chem., 2005, 15, 633-648.
[33] L. Katta, P. Sudarsanam, G. Thrimurthulu, B. M. Reddye, Appl. Catal. B, 2010, 101, 101-108.
[34] S. Abdollahzadeh-Ghom, C. Zamani, T. Andreu, M. Epifani, J. R. Morante, Appl. Catal. B, 2011, 108-109, 32-38.
[35] M. Fabián, B. Antic, V. Girman, M. Vucinic-Vasic, A. Kremenovic, S. Suzuki, H. Hahn, V. Šepelák, J. Solid State Chem., 2015, 230, 42-48.
[36] S. P. Wang, X. Y. Wang, J. Huang, S. M. Zhang, S. R. Wang, S. H. Wu, Catal. Commun., 2007, 8, 231-236.
[37] I. Dobrosz-Gómez, I. Kocemba, J. M. Rynkowski, Appl. Catal. B, 2008, 83, 240-255.
[38] Y. M. Luo, Z. Y. Hou, J. Gao, D. Jin, X. Zheng, Mater. Sci. Eng. B, 2007, 140, 123-127.
[39] X. L. Sang, L. Y. Zhang, H. Wang, D. D. He, L. Deng, S. Huang, J. Wang, Y. M. Luo, Powder Technol., 2014, 253, 590-595.
[40] D. Yang, L. Wang, Y. Z. Sun, K. Zhou, J. Phys. Chem. C, 2010, 114, 8926-8932.
[41] D. Harshini, D. H. Lee, J. Jeong, Y. M. Kima, S. W. Nama, H. C. Ham, J. H. Han, T. H. Lim, C. W. Yoon, Appl. Catal. B, 2014, 148-149, 415-423.
[42] D. Jampaiah, K. M. Tur, S. J. Ippolito, Y. M. Sabri, J. Tardio, S. K. Bhargava, B. M. Reddy, RSC Adv., 2013, 3, 12963-12974.
[43] W. Lee, S. Y. Chen, Y. S. Chen, C. L. Dong, H. J. Lin, C. T. Chen, A. Gloter, J. Phys. Chem. C, 2014, 118, 26359.
[44] H. P. Zhang, H. C. Liu, J. Energy Chem., 2013, 22, 98-106.
[45] A. Nakajima, A. Yoshihara, M. Ishigame, Phys. Rev. B, 1994, 50, 13297-13307.
[46] T. Taniguchi, T. Watanabe, N. Sugiyama, A. K. Subramani, H. Wagata, N. Matsushita, M. Yoshimura, J. Phys. Chem. C, 2009, 113, 19789-19793.
[47] J. Li, Y. X. Han, Y. H. Zhu, R. X. Zhou, Appl. Catal. B, 2011, 108-109, 72-80.
[48] A. Galtayries, R. Sporken, J. Riga, G. Blanchard, R. Caudano, J. Electron Spectrosc., 1998, 88, 951-956.
[49] A. E. Nelsona, K. H. Schulz, Appl. Surf. Sci., 2003, 210, 206-221.
[50] Z. Wang, Z. P. Qu, X. Quan, Z. Li, H. Wang, R. Fan, Appl. Catal. B, 2013, 134-135, 153-166.
[51] J. Hierso, O. Sel, A. Ringuede, C. Laberty-Robert, L. Bianchi, D. Grosso, C. Sanchez, Chem. Mater., 2009, 21, 2184-2192.
[52] Q. Ye, R. P. Wang, B. Q. Xu, Acta Phys. Chim. Sin., 2006, 22, 33-37.
[53] A. E. C. Palmqvist, M. Wirde, U. Gelius, M. Muhammed, Nanostruct. Mater., 1999, 11, 995-1007.
[54] C. T. Campbell, C. H. F. Peden, Science, 2005, 309, 713-714.
[55] Y. C. Wei, J. Liu, Z. Zhao, A. Duan, G. Jiang, J. Catal., 2012, 287, 13-29.
[56] I. Atribak, A. Buenolopez, A. Garciagarcia, J. Catal., 2008, 259, 123-132.
[57] Y. N. Zheng, K. Z. Li, H. Wang, Y. H. Wang, D. Tian, Y. G. Wei, X. Zhu, C. H. Zeng, Y. M. Luo, J. Catal., 2016, 344, 365-377.
[58] X. W. Liu, K. B. Zhou, L. Wang, B. Y. Wang, Y. D. Li, J. Am. Chem. Soc., 2009, 131, 3140-3141.

Relationship between oxygen species and activity/stability in heteroatom (Zr, Y)-doped cerium-based catalysts for catalytic decomposition of CH₃SH

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 6

Recommended Articles

Metrics

[1]	Xue Bai, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi Guan. Improvement of oxygen evolution activity on isolated Mn sites by dual-heteroatom coordination [J]. Chinese Journal of Catalysis, 2023, 54(11): 212-219.
[2]	Chuqiang Huang, Jianqing Zhou, Dingshuo Duan, Qiancheng Zhou, Jieming Wang, Bowen Peng, Luo Yu, Ying Yu. Roles of heteroatoms in electrocatalysts for alkaline water splitting: A review focusing on the reaction mechanism [J]. Chinese Journal of Catalysis, 2022, 43(8): 2091-2110.
[3]	Yu Ding, Bo-Qiang Miao, Yue Zhao, Fu-Min Li, Yu-Cheng Jiang, Shu-Ni Li, Yu Chen. Direct growth of holey Fe₃O₄-coupled Ni(OH)₂ sheets on nickel foam for the oxygen evolution reaction [J]. Chinese Journal of Catalysis, 2021, 42(2): 271-278.
[4]	XU Hao, WU Peng. Recent Progress of Metallosilicate Catalysts in Environment-Friendly Selective Oxidation Reactions [J]. Chinese Journal of Catalysis, 2019, 40(s1): 51-56.
[5]	Pei Tang, Yongjun Gao, Jinghe Yang, Wenjing Li, Huabo Zhao, Ding Ma. Growth mechanism of N-doped graphene materials and their catalytic behavior in the selective oxidation of ethylbenzene [J]. Chinese Journal of Catalysis, 2014, 35(6): 922-928.
[6]	KANG Zi-Hua, LIU Hai-鸥, ZHANG Xiong-Fu. Preparation and Characterization of Sn-β Zeolites by a Two-Step Postsynthesis Method and Their Catalytic Performance for Baeyer-Villiger Oxidation of Cyclohexanone [J]. Chinese Journal of Catalysis, 2012, 33(5): 898-904.