Eco-friendly synthesis of high silica zeolite Y with choline as green and innocent structure-directing agent

doi:10.1016/S1872-2067(18)63167-5

Chinese Journal of Catalysis ›› 2019, Vol. 40 ›› Issue (1): 52-59.DOI: 10.1016/S1872-2067(18)63167-5

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Eco-friendly synthesis of high silica zeolite Y with choline as green and innocent structure-directing agent

Dawei He^a,b, Danhua Yuan^a, Zhijia Song^a,b, Yunpeng Xu^a, Zhongmin Liu^a

a National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received:2018-09-12 Revised:2018-09-23 Online:2019-01-18 Published:2018-11-09
Contact: 10.1016/S1872-2067(18)63167-5
Supported by:
The work was supported by the National Natural Science Foundation of China (Grant No.21802136).

Abstract

Abstract:

Zeolite synthesis in contemporary chemical industries is predominantly conducted using organic structure-directing agents (OSDAs), which are chronically hazardous to humans and the environment. It is a growing trend to develop an eco-friendly and nuisanceless OSDA for zeolite synthesis. Herein, choline is employed as a non-toxic and green OSDA to synthesize high silica Y zeolite with SiO₂/Al₂O₃ ratios of 6.5-6.8. The prepared Y zeolite samples exhibited outstanding (hydro)thermal stability at ultrahigh temperature owing to the higher SiO₂/Al₂O₃ ratio. The XRF, SEM, ²⁹Si-NMR and ¹³Na+ results suggested that choline plays a structure-directing role in the synthesis of Y zeolite, while the feed molar fraction of Na⁺ is a crucial determinant for the framework SiO₂/Al₂O₃ ratio and the crystal morphology.

Key words: Zeolite synthesis, FAU zeolite, High silica, Green organic structure-directing agent, (Hydro)thermal stability

Dawei He, Danhua Yuan, Zhijia Song, Yunpeng Xu, Zhongmin Liu. Eco-friendly synthesis of high silica zeolite Y with choline as green and innocent structure-directing agent[J]. Chinese Journal of Catalysis, 2019, 40(1): 52-59.

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Eco-friendly synthesis of high silica zeolite Y with choline as green and innocent structure-directing agent

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