Insights into facet-dependent reactivity of CuO-CeO2 nanocubes and nanorods as catalysts for CO oxidation reaction

doi:10.1016/S1872-2067(20)63533-1

Abstract

Abstract: Copper-ceria (CuO-CeO₂) catalysts have been known to be very effective for the oxidation of CO, and their chemical behavior has been extensively studied during the last decades. However, the effect of different CeO₂ crystal surfaces on the catalytic activity of CuO-CeO₂ for the oxidation of CO is still unclear and should be further elucidated. In this study, we deposited 1 wt% Cu on mostly {100}-exposed CeO₂ nanocubes (1CuCe NC) and mostly {110}-exposed CeO₂ nanorods (1CuCe NR), respectively. Both 1CuCe NC and 1CuCe NR have been used as catalysts for the oxidation of CO and achieved 100% and 50% CO conversion at 130℃, respectively. The differences in the catalytic activity of 1CuCe NC and 1CuCe NR were analyzed using temperature-programmed reduction of H₂ and temperature-programmed desorption of CO techniques. The results confirmed the excellent reducibility of the 1CuCe NC catalyst, which was attributed to the weak interactions between Cu and the CeO₂ support. Moreover, in situ diffuse reflectance infrared Fourier-transform spectroscopy studies indicated that the {100} planes of 1CuCe NC facilitated the generation of active Cu(I)sites, which resulted in the formation of highly reactive Cu(I)-CO species during the oxidation of CO. Both the excellent redox properties and effective CO adsorption capacity of the 1CuCe NC catalyst increased its catalytic reactivity.

Key words: Copper-ceria catalyst, Crystal facets, CO oxidation, Redox property, Active site

Yu Aung May, Wei-Wei Wang, Han Yan, Shuai Wei, Chun-Jiang Jia. Insights into facet-dependent reactivity of CuO-CeO₂ nanocubes and nanorods as catalysts for CO oxidation reaction[J]. Chinese Journal of Catalysis, 2020, 41(6): 1017-1027.

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Insights into facet-dependent reactivity of CuO-CeO₂ nanocubes and nanorods as catalysts for CO oxidation reaction

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