Liquid-Phase Partial Hydrogenation of Benzene over Ru/MgAl2O4 Catalyst: Effect of Calcination Temperature of MgAl2O4

doi:10.3724/SP.J.1088.2011.10508

Abstract

Abstract: The MgAl₂O₄ material was synthesized by the hydrothermal method. A series of Ru/MgAl₂O₄ catalyst samples were prepared using this MgAl₂O₄ calcined at different temperatures. The catalyst samples were characterized by powder X-ray diffraction, ²⁷Al solid-state nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, temperature-programmed reduction, temperature-programmed desorption, N₂ physisorption, transmission electron microscopy, and X-ray photoelectron spectroscopy. It was found that the spinel phase readily formed at calcination temperature as low as 773 K. The calcination temperature of MgAl₂O₄ strongly influenced the structural properties of the catalyst. In the liquid-phase partial hydrogenation of benzene, the Ru/MgAl₂O₄ catalyst sample calcined at 1023 K exhibited the highest cyclohexene selectivity and yield. The maximum cyclohexene yield was 38.5% and the corresponding selectivity was 52.4%. Based on the characterization results, the effect of the calcination temperature of MgAl₂O₄ on the activity and selectivity of Ru/MgAl₂O₄ catalyst samples was discussed.

Key words: ruthenium, magnesium aluminum spinel, calcination temperature, benzene, partial hydrogenation, cyclohexene

ZHOU Gong-Bing, LIU Jian-Liang, XU Ke, PEI Yan, QIAO Ming-Hua, FAN Kang-Nian. Liquid-Phase Partial Hydrogenation of Benzene over Ru/MgAl₂O₄ Catalyst: Effect of Calcination Temperature of MgAl₂O₄[J]. Chinese Journal of Catalysis, 2011, 32(9): 1537-1544.

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https://www.cjcatal.com/EN/Y2011/V32/I9/1537

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Liquid-Phase Partial Hydrogenation of Benzene over Ru/MgAl₂O₄ Catalyst: Effect of Calcination Temperature of MgAl₂O₄

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