Multiwall carbon nanotube paste electrode with 3,4-dihydroxy-cinnamic acid as mediator for the determination of glutathione in pharmaceutical and urine samples

doi:10.1016/S1872-2067(12)60661-5

Abstract

Abstract:

A sensitive and selective electrochemical sensor for the determination of glutathione (GSH) was developed using a modified multiwall carbon nanotube paste electrode with 3,4-dihydroxy-cinnamic acid as a mediator. This modified electrode showed very high electrocatalytic activity for the anodic oxidation of GSH. Under the optimized conditions, the electrocatalytic peak current showed a linear relationship with GSH concentration in the range of 0.5-400.0 μmol/L with a detection limit of 0.1 μmol/L GSH. The relative standard deviations for seven successive assays of 5.0 and 25.0 μmol/L GSH were 2.2% and 2.7%, respectively. The modified electrode was used for the determination of GSH compounds in real urine samples.

Key words: Glutathione, 3,4-Dihydroxy-cinnamic acid, Carbon paste electrode, Multiwall carbon nanotube, Sensor

Mohsen Keyvanfard, Hassan Karimi-Maleh, Khadijeh Alizad. Multiwall carbon nanotube paste electrode with 3,4-dihydroxy-cinnamic acid as mediator for the determination of glutathione in pharmaceutical and urine samples[J]. Chinese Journal of Catalysis, 2013, 34(10): 1883-1889.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60661-5

https://www.cjcatal.com/EN/Y2013/V34/I10/1883

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