Catalytic performance of mesoporous material supported bimetallic carbide Ni-b-Mo2C/SBA-16 catalyst for CH4/CO2 reforming to syngas

doi:10.3724/SP.J.1088.2013.20857

Abstract

Abstract: Mesoporous molecular sieve SBA-16 supported bimetallic carbide catalyst Ni-b-Mo₂C/SBA-16 was prepared using the impregnation and thermal decomposition method. N₂ adsorption-desorption isotherms, powder X-ray diffraction, and transmission electron microscopy measurements show that the active components were uniformly dispersed on the support, and the catalyst still remained ordered mesoporous structure of SBA-16. Catalytic performance measurements show that the catalyst exhibited higher conversion rate of CH₄, CO₂, and selectivity of CO, H₂, and remarkable anti-coke effect.

Key words: methane, carbon dioxide, reforming, molybdenum carbide, nickel, mesoporous molecular sieve SBA-16, syngas, anti-coke

NAO Mo-Han, FU Xiao-Juan, LEI Yan-Qiu, SU Hai-Quan. Catalytic performance of mesoporous material supported bimetallic carbide Ni-b-Mo2C/SBA-16 catalyst for CH₄/CO₂ reforming to syngas[J]. Chinese Journal of Catalysis, 2013, 34(2): 379-384.

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References

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Catalytic performance of mesoporous material supported bimetallic carbide Ni-b-Mo2C/SBA-16 catalyst for CH₄/CO₂ reforming to syngas

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